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Metapramine

Product Name
Metapramine
CAS No.
21730-16-5
Chemical Name
Metapramine
Synonyms
RP 19560;Metapramine;Metapramine USP/EP/BP;10,11-Dihydro-5-Methyl-10-5H-Dibenz[b,f]azepine;5-Methyl-10-MethylaMino-10,11-dihydrodibenzo[b,f]azepine;10,11-Dihydro-N,5-diMethyl-5H-Dibenz[b,f]azepin-10-aMine;5H-Dibenz[b,f]azepin-10-amine, 10,11-dihydro-N,5-dimethyl-;10,11-Dihydro-5-methyl-10-(methylamino)-5H-dibenz[b,f]azepine
CBNumber
CB3875115
Molecular Formula
C16H18N2
Formula Weight
238.33
MOL File
21730-16-5.mol
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Metapramine Property

Melting point:
237-240 °C
Boiling point:
350.8±42.0 °C(Predicted)
Density 
1.12±0.1 g/cm3(Predicted)
storage temp. 
Hygroscopic, -20°C Freezer, Under inert atmosphere
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Oil
pka
9.09±0.20(Predicted)
color 
Colourless to Pale Yellow
Stability:
Hygroscopic
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
M225830
Product name
Metapramine
Packaging
25mg
Price
$85
Updated
2021/12/16
TRC
Product number
M225830
Product name
Metapramine
Packaging
100mg
Price
$150
Updated
2021/12/16
Usbiological
Product number
015997
Product name
Metapramine
Packaging
10mg
Price
$460
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
API0011900
Product name
METAPRAMINE
Purity
95.00%
Packaging
100MG
Price
$1963.5
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
59652
Product name
Metapramine
Packaging
100mg
Price
$2200
Updated
2021/12/16
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Metapramine Chemical Properties,Usage,Production

Description

Metapramine is an antidepressant with a pharmacological profile similar to the tricyclics and an apparent rapid clinical onset of action. Metapramine differs biochemically from the tricyclics in that it markedly enhances norepinephrine turnover with minimal inhibition of reuptake. Like the tricyclics, however, it does down regulate β-receptors.

Originator

Rhone-Poulenc (France)

Uses

Metapramine is a tricyclic antidepressant derived from dibenzoazepine. Metapramine acts as a norepinephrine reuptake inhibitor without affecting the reuptake of serotonin or dopamine.

Definition

ChEBI: Metapramine is a dibenzooxazepine.

Manufacturing Process

5-Methyl-dibenzo[b,f]azepine (4.1 g), N-diethylaminoborane (1.7 g) and freshly distilled toluene (150 cc) are introduced into a 500 cc three-neck flask equipped with a dropping funnel and a condenser, and protected against moisture by a calcium chloride guard tube. The solution is heated under reflux (110°C) for 22 hours under a nitrogen atmosphere and then cooled. A 2 N aqueous sodium hydroxide solution (33 cc) is then run in followed by an 0.316 N aqueous methylchloramine solution (190 cc), the addition of which takes 9 minutes. The mixture is stirred for 1 hour and then decanted. The organic layer is washed with water until it has a pH of 6 and is then extracted with 2 N hydrochloric acid (5 times 50 cc), dried over sodium sulfate, filtered and evaporated. Recrystallization of the residue from petroleum ether yields some unconverted 5-methyl-dibenzo[b,f]azepine (2.17 g).
The aqueous acid solution is rendered alkaline by adding 2 N sodium hydroxide solution. After extracting with diethyl ether (3 times 100 cc), drying the extracts over potassium carbonate, treating them with decolorizing charcoal, filtering and evaporating the ether, a yellowish oil (0.9 g), identified as 5-methyl-10-methylamino-10,11-dihydrodibenzo[b,f]azepine, is obtained in a yield of 37.5%.
Methylchloramine can be prepared by adding an aqueous solution of sodium hypochlorite to an aqueous solution of methylamine in accordance with the process described by W.S. Metcalf, J. Chem. Soc.1942,148.

brand name

TIMAXEL

Therapeutic Function

Antidepressant

Metapramine Preparation Products And Raw materials

Raw materials

Preparation Products

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Metapramine Suppliers

BOC Sciences
Tel
16314854226
Email
info@bocsci.com
Country
United States
ProdList
9923
Advantage
65
TargetMol Chemicals Inc.
Tel
+1-781-999-5354 +1-00000000000
Email
marketing@targetmol.com
Country
United States
ProdList
32161
Advantage
58
United States Biological
Tel
--
Fax
--
Email
chemicals@usbio.net
Country
United States
ProdList
6214
Advantage
80
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
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View Lastest Price from Metapramine manufacturers

Dideu Industries Group Limited
Product
Metapramine 21730-16-5
Price
US $1.10/g
Min. Order
1g
Purity
99.9%
Supply Ability
100 Tons min
Release date
2021-07-26

21730-16-5, MetapramineRelated Search:


  • Metapramine
  • 10,11-Dihydro-5-methyl-10-(methylamino)-5H-dibenz[b,f]azepine
  • 10,11-Dihydro-5-Methyl-10-5H-Dibenz[b,f]azepine
  • 10,11-Dihydro-N,5-diMethyl-5H-Dibenz[b,f]azepin-10-aMine
  • 5-Methyl-10-MethylaMino-10,11-dihydrodibenzo[b,f]azepine
  • RP 19560
  • 5H-Dibenz[b,f]azepin-10-amine, 10,11-dihydro-N,5-dimethyl-
  • Metapramine USP/EP/BP
  • 21730-16-5
  • Aromatics
  • Heterocycles
  • Intermediates & Fine Chemicals
  • Neurochemicals
  • Pharmaceuticals