ChemicalBook > CAS DataBase List > 4-Bromomethylphenyl acetate
4-Bromomethylphenyl acetate
- Product Name
- 4-Bromomethylphenyl acetate
- CAS No.
- 52727-95-4
- Chemical Name
- 4-Bromomethylphenyl acetate
- Synonyms
- p-Acetoxybenzyl Bromide;4-acetoxybenzyl bromide;4-Bromomethylphenyl acetate;4-(Bromomethyl)phenylacetate,tech;Phenol, 4-(broMoMethyl)-, acetate;Phenol, 4-(bromomethyl)-, 1-acetate;4-(Bromomethyl)phenyl acetate, technical
- CBNumber
- CB3947164
- Molecular Formula
- C9H9BrO2
- Formula Weight
- 229.07
- MOL File
- 52727-95-4.mol
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4-Bromomethylphenyl acetate Property
- Melting point:
- 54-55 °C
- Boiling point:
- 118-122 °C(Press: 1.5 Torr)
- Density
- 1.463±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
- form
- crystalline powder
- color
- Light lemon
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Safety
- HS Code
- 2915390090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P405Store locked up.
P501Dispose of contents/container to..…
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N-Bromosuccinimide Price
TRC
- Product number
- B847223
- Product name
- 4-(Bromomethyl)phenylacetate
- Packaging
- 50mg
- Price
- $65
- Updated
- 2021/12/16
AK Scientific
- Product number
- 4300BB
- Product name
- 4-(Bromomethyl)phenylacetate
- Packaging
- 5g
- Price
- $1680
- Updated
- 2021/12/16
Abosyn
- Product number
- 61-10848
- Product name
- 4-(Bromomethyl)phenylacetate
- Purity
- 95-98%
- Packaging
- 1g
- Price
- $225
- Updated
- 2021/12/16
Crysdot
- Product number
- CD12064989
- Product name
- 4-(Bromomethyl)phenylacetate
- Purity
- 97%
- Packaging
- 5g
- Price
- $402
- Updated
- 2021/12/16
Abosyn
- Product number
- 61-10848
- Product name
- 4-(Bromomethyl)phenylacetate
- Purity
- 95-98%
- Packaging
- 5g
- Price
- $675
- Updated
- 2021/12/16
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4-Bromomethylphenyl acetate Chemical Properties,Usage,Production
Synthesis
140-39-6
52727-95-4
P-cresyl acetate (50.0 g) was dissolved in 500 mL of carbon tetrachloride, and 4.0 g of benzoyl peroxide (BPO) was added, heated to 50 °C and stirred. Subsequently, 71.5 g of N-bromosuccinimide (NBS) (molar ratio of p-cresyl acetate, NBS to BPO was 1:1.2:0.05) was added in three batches and the reaction was kept for 3 hours. After completion of the reaction, filtration was carried out and the filtrate was concentrated under reduced pressure. The resulting orange-red oil was slowly added dropwise to petroleum ether and stirred to disperse, and the solid then precipitated. The solid was separated by filtration and the filtrate was washed with water. After drying, the filtrate was concentrated under reduced pressure to give 4-bromomethylphenyl acetate (III) in a yield of 68.3 g and 89.2%.
References
[1] Patent: CN108640834, 2018, A. Location in patent: Paragraph 0020; 0023; 0025
[2] Chemical Communications, 2010, vol. 46, # 20, p. 3526 - 3528
[3] Journal of Organic Chemistry, 1981, vol. 46, # 15, p. 3029 - 3035
[4] Chemical Communications, 2016, vol. 52, # 32, p. 5609 - 5612
[5] ChemMedChem, 2013, vol. 8, # 10, p. 1662 - 1667
4-Bromomethylphenyl acetate Preparation Products And Raw materials
Raw materials
Preparation Products
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