ChemicalBook > CAS DataBase List > Ethyl 6-aminopicolinate

Ethyl 6-aminopicolinate

Product Name
Ethyl 6-aminopicolinate
CAS No.
69142-64-9
Chemical Name
Ethyl 6-aminopicolinate
Synonyms
ethyl 6-aminopicolinate;2-Amino-6-carbethoxypyridine;6-Aminopicolinic Acid Ethyl Ester;ETHYL 6-AMINOPYRIDINE-2-CARBOXYLATE;6-Aminopyridine-2-carboxylic acid ethyl ester;6-Amino-2-pyridinecarboxylic acid ethyl ester;2-Pyridinecarboxylic acid, 6-amino-, ethyl ester;2-Pyridinecarboxylicacid,6-amino-,ethylester(9CI);6-Aminopyridine-2-carboxylic acid ethyl ester ISO 9001:2015 REACH
CBNumber
CB3967539
Molecular Formula
C8H10N2O2
Formula Weight
166.18
MOL File
69142-64-9.mol
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Ethyl 6-aminopicolinate Property

Melting point:
56-58℃
Boiling point:
330℃
Density 
1.192
Flash point:
153℃
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
soluble in Methanol
form 
powder to crystal
pka
1.87±0.10(Predicted)
color 
White to Yellow to Green
λmax
337nm(MeOH)(lit.)
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical
Product number
E1213
Product name
Ethyl 6-Aminopyridine-2-carboxylate
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$103
Updated
2025/07/31
TCI Chemical
Product number
E1213
Product name
Ethyl 6-Aminopyridine-2-carboxylate
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$311
Updated
2025/07/31
TRC
Product number
E900178
Product name
Ethyl6-Aminopicolinate
Packaging
500mg
Price
$130
Updated
2021/12/16
AK Scientific
Product number
W7903
Product name
Ethyl6-amino-2-pyridinecarboxylate
Packaging
10g
Price
$289
Updated
2021/12/16
Apolloscientific
Product number
OR929091
Product name
6-Aminopyridine-2-carboxylicacidethylester
Purity
95%
Packaging
250mg
Price
$203
Updated
2021/12/16
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Ethyl 6-aminopicolinate Chemical Properties,Usage,Production

Chemical Properties

White to Yellow to Green powder to crystal.

Synthesis

23628-31-1

64-17-5

69142-64-9

6-Amino-2-pyridinecarboxylic acid (6.0 g, 43.5 mmol) was dissolved in ethanol (150 mL) at 0 °C and sulfoxide chloride (12.0 g, 101 mmol) was added slowly. The reaction mixture was heated to reflux with continuous stirring for 12 hours. Upon completion of the reaction, it was cooled to room temperature and the reaction mixture was subsequently concentrated under reduced pressure. The pH was adjusted to 9 with saturated aqueous sodium carbonate solution and concentrated again under reduced pressure. Dichloromethane (150 mL) was added to the residue, stirred vigorously for 30 minutes at room temperature and filtered. The filtrate was concentrated under reduced pressure to give ethyl 6-aminopyridine-2-carboxylate (5.5 g, 76% yield).

References

[1] Patent: WO2010/3048, 2010, A1. Location in patent: Page/Page column 107
[2] Patent: WO2010/19606, 2010, A1. Location in patent: Page/Page column 81-82
[3] Patent: WO2010/37127, 2010, A1. Location in patent: Page/Page column 109
[4] Patent: WO2010/88574, 2010, A1. Location in patent: Page/Page column 127-128
[5] Patent: WO2010/101949, 2010, A1. Location in patent: Page/Page column 132; 133

Ethyl 6-aminopicolinate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ethyl 6-aminopicolinate manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
6-Aminopyridine-2-carboxylic acid ethyl ester 69142-64-9
Price
US $1.10/g
Min. Order
1g
Purity
99.0% min
Supply Ability
100 tons min
Release date
2021-05-25
Career Henan Chemical Co
Product
6-Aminopyridine-2-carboxylic acid ethyl ester 69142-64-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-12-24

69142-64-9, Ethyl 6-aminopicolinateRelated Search:


  • ETHYL 6-AMINOPYRIDINE-2-CARBOXYLATE
  • 6-Aminopyridine-2-carboxylic acid ethyl ester
  • 2-Pyridinecarboxylicacid,6-amino-,ethylester(9CI)
  • 2-Amino-6-carbethoxypyridine
  • 6-Amino-2-pyridinecarboxylic acid ethyl ester
  • ethyl 6-aminopicolinate
  • 2-Pyridinecarboxylic acid, 6-amino-, ethyl ester
  • 6-Aminopicolinic Acid Ethyl Ester
  • 6-Aminopyridine-2-carboxylic acid ethyl ester ISO 9001:2015 REACH
  • 69142-64-9
  • Heterocycle-Pyridine series
  • GLYCINESCAFFOLD
  • pharmacetical