Reaction
ChemicalBook > CAS DataBase List > (S,S)-F-BINAPHANE

(S,S)-F-BINAPHANE

Reaction
Product Name
(S,S)-F-BINAPHANE
CAS No.
544461-38-3
Chemical Name
(S,S)-F-BINAPHANE
Synonyms
(S,S)-F-BINAPHANE;1,1'-Bis[(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino]ferrocene;1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene;1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene (S,S)-f-Binaphane;1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, Min. 98% (S,S)-f-Binaphane;1,1μ-Bis[(S)-4,5-dihydro-3H-binaphtho[2,1-c:1μ,2μ-e]phosphepino]ferrocene, 1,1μ-Bis[(11bs)-3,5-dihydro-4H-dinaphtho[2,1-c:1μ,2μ-e]phosphenpin-4yl]ferrocene
CBNumber
CB3972577
Molecular Formula
C54H32FeP2
Formula Weight
798.64
MOL File
544461-38-3.mol
More
Less

(S,S)-F-BINAPHANE Property

form 
Powder
color 
yellow-brown
Sensitive 
air sensitive, light sensitive
More
Less

Hazard and Precautionary Statements (GHS)

More
Less

N-Bromosuccinimide Price

Strem Chemicals
Product number
26-0243
Product name
1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, min. 98% (S,S)-f-Binaphane
Packaging
100mg
Price
$161
Updated
2024/03/01
Strem Chemicals
Product number
26-0243
Product name
1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, min. 98% (S,S)-f-Binaphane
Packaging
500mg
Price
$642
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
OGM0002731
Product name
1,1'-BIS-[(11BS)-3,5-DIHYDRO-4H-DINAPHTHO[2,1-C,1',2'-E]PHOSPHEPIN-4-YL]FERROCENE
Purity
95.00%
Packaging
5MG
Price
$496.32
Updated
2021/12/16
More
Less

(S,S)-F-BINAPHANE Chemical Properties,Usage,Production

Reaction

  1. Ligand for enantioselective Pd-catalyzed hydrogenation of enesulfonamides [5] and cyclic Nsulfonylimines.
  2. Enantioselective, asymmetric organocatalyst for cycloaddition of allenoates to C60 fullerene (conversion >90%, ee up to 90%)
  3. Ligand for Iridium-mediated direct asymmetric reductive amination of acetophenone with phenylhydrazide (conversion >99%; yield >94%; ee >94%)
  4. Ligand used for the palladium-catalyzed, asymmetric, decarboxylative generation and asymmetric allylation of α-imino anions.
  5. Ligand used in iridium-catalyzed, asymmetric hydrogenation of 6-substituted 3-hydroxypyridinium salts to trans 6-substituted piperidin-3-ols with high enantioselectivities(up to 95% ee).

(S,S)-F-BINAPHANE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(S,S)-F-BINAPHANE Suppliers

SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91

544461-38-3, (S,S)-F-BINAPHANERelated Search:


  • (S,S)-F-BINAPHANE
  • 1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, Min. 98% (S,S)-f-Binaphane
  • 1,1μ-Bis[(S)-4,5-dihydro-3H-binaphtho[2,1-c:1μ,2μ-e]phosphepino]ferrocene, 1,1μ-Bis[(11bs)-3,5-dihydro-4H-dinaphtho[2,1-c:1μ,2μ-e]phosphenpin-4yl]ferrocene
  • 1,1'-Bis[(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino]ferrocene
  • 1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene (S,S)-f-Binaphane
  • 1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene
  • 544461-38-3
  • C54H40P2Fe
  • C54H40FeP2