METHYL JASMONATE

Product Name: METHYL JASMONATE
CAS No.: 1211-29-6
Chemical Name: METHYL JASMONATE
Synonyms: Methyl cis-jasmonate;JASMONIC ACID METHYL ESTER;(1R)-3-Oxo-2α-[(Z)-2-pentenyl]-1α-cyclopentaneacetic acid methyl ester;Cmc_7389;Cmc_13964;FEMA 3410;JASMONEIGE;,2beta(z)]]-;METHYL JASMONATE;(-)-methyljasmonate
CBNumber: CB4100148
Molecular Formula: C13H20O3
Formula Weight: 224.3
MOL File: 1211-29-6.mol

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METHYL JASMONATE Property

Boiling point:: 110 °C0.2 mm Hg(lit.)
alpha: D -76.5° (c = 3.4 in CH3OH)
Density: 1.03 g/mL at 25 °C(lit.)
FEMA: 3410 | METHYL JASMONATE
refractive index: n20/D 1.474(lit.)
Flash point:: >230 °F
storage temp.: Sealed in dry,Room Temperature
solubility: Almost insoluble in water, soluble in alcohol and oils.
form: oily liquid
Specific Gravity: 1.02
color: Colorless
Odor: at 100.00 %. floral fresh petal magnolia oily waxy
Odor Type: floral
JECFA Number: 1400
LogP: 2.12
CAS DataBase Reference: 1211-29-6(CAS DataBase Reference)
EPA Substance Registry System: Cyclopentaneacetic acid, 3-oxo-2-(2Z)-2-pentenyl-, methyl ester, (1R,2R)- (1211-29-6)

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Safety

WGK Germany: 3
Hazardous Substances Data: 1211-29-6(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC

Product number: J210535
Product name: (-)-JasmonicAcidMethylEster
Packaging: 5mg
Price: $880
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: API0013577
Product name: 3-OXO-2-(2-PENTENYL)CYCLOPENTANEACETIC ACID METHYL ESTER
Purity: 95.00%
Packaging: 5G
Price: $1163.09
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: API0013577
Product name: 3-OXO-2-(2-PENTENYL)CYCLOPENTANEACETIC ACID METHYL ESTER
Purity: 95.00%
Packaging: 1G
Price: $224.7
Updated: 2021/12/16

Chemenu

Product number: CM202237
Product name: Methyl2-((1R,2R)-3-oxo-2-((Z)-pent-2-en-1-yl)cyclopentyl)acetate
Purity: 95%
Packaging: 100g
Price: $317
Updated: 2021/12/16

Crysdot

Product number: CD13025718
Product name: Methyl2-((1R,2R)-3-oxo-2-((Z)-pent-2-en-1-yl)cyclopentyl)acetate
Purity: 95+%
Packaging: 100g
Price: $339
Updated: 2021/12/16

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METHYL JASMONATE Chemical Properties,Usage,Production

Description

Methyl jasmonate has a powerful, floral-herbaceous, sweet, persistent odor. Can be isolated from jasmine oil; or it may be prepared synthetically (probably in the trans-form) from muconic acid via the methyl-3-oxo-cyclopenthyl acetate.

Chemical Properties

Methyl jasmonate has a powerful, floral–herbaceous, sweet, persistent odor.

Chemical Properties

METHYL JASMONATE is a volatile component of jasmine flower absolute. It is a colorless to pale yellow liquid, bp0.125 kPa 116–118 °C, d20 20 1.022–1.028, n20 D 1.473–1.477, possessing an odor reminiscent of the floral heart of jasmine. Synthesis of the title compound is accomplished by reaction of (2Z)-2-buten-1-yl bromide with Li in the presence of copper-(I) iodide, and the product is treated with a mixture of 2-methylene- and 4-methylene-3-oxocyclopentylacetic acid methyl ester. The aforementioned ester mixture is obtained by reaction of methyl 3-oxocyclopentylacetate with formaldehyde.
An alternative route uses a palladium-catalyzed decarboxylation of the readily available substituted allyl 2-oxocyclopentanecarboxylates, which leads to the corresponding cyclopentenones. Addition of dimethylmalonate, with subsequent saponification/decarboxylation and, if necessary, (Z)-selective hydrogenation, yields methyl jasmonate:
Methyl jasmonate exists in an equilibrium mixture in which the trans-isomer dominates. But of all possible four enantiomeric isomers, chiefly the minor (+)-cis-isomer is responsible for the typical sensory properties of methyl jasmonate. Therefore, several approaches to obtain this material selectively have been developed either by directed syntheses or by enrichment using special isomerization distillation techniques.
Methyl jasmonate is used in fine fragrances where it provides rich, soft effects in jasmine and muguet compositions.

Occurrence

Reportedly identified in jasmine oil (Jasminum grandiflorum L.) and in Tunisian rosemary. Also found in lemon peel oil, peppermint oil and green and fermented tea

Uses

(-)-Jasmonic Acid Methyl Ester can be used in biological study where it can exert concn.-dependent effect on SE1 and upregulated SE1 expression in both young and mature leaves of Gynostemma pentaphyllum, with greater upregulation in young leaves than in mature leaves.

Uses

Methyl ester in perfumes.

Definition

ChEBI: A jasmonate ester that is the methyl ester of jasmonic acid.

Aroma threshold values

Detection: 5.7 ppm

Taste threshold values

Taste characteristics at 15 ppm: floral, fruity, green, waxy, seedy and melon-like

Trade name

Jasmoneige® (Nippon Zeon), Splendione® (Firmenich)

Synthesis

Can be isolated from jasmine oil; synthetically it can be prepared (probably in the trans-form) from muconic acid via the methyl-3-oxo-cyclopentyl acetate

METHYL JASMONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL JASMONATE Suppliers

Canada 1 China 160 Germany 2 India 1 Japan 1 South Korea 1 Switzerland 1 United Kingdom 4 United States 17 USA 1 Global 189

Beijing HwrkChemical Technology Co., Ltd

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Nanjing MeiBo Biological Technology Co., Ltd.

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Hunan Hui Bai Shi Biotechnology Co., Ltd.

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Hangzhou Yuhao Chemical Technology Co., Ltd

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Beijing HuaMeiHuLiBiological Chemical

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Shanghai T&W Pharmaceutical Co., Ltd.

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TargetMol Chemicals Inc.

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Bide Pharmatech Ltd.

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Finetech Industry Limited

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Suzhou yacoo science co.,Ltd

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View Lastest Price from METHYL JASMONATE manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Methyl Jasmonate 1211-29-6
Price: US $60.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-05-16

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Methyl Jasmonate 1211-29-6
Price: US $0.00/ml
Min. Order: 5ml
Purity: ≥95.0%
Supply Ability: 10kg/month
Release date: 2021-09-29

Hebei Weibang Biotechnology Co., Ltd

Product: METHYL JASMONATE 1211-29-6
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-21

1211-29-6, METHYL JASMONATERelated Search:

(±)-JASMONIC ACID (-)-JASMONIC ACID Methyl-(+/-)Jasmonate=JasmonsreMethylester=JasmonicacidMethylester,trans-Methyl jasmonate Methyl JasMonate (Mixture of isoMers) Jasmonic Acid-d5 (Mixture of Diastereomers, (-)-trans major) N-[(-)-JASMONOYL]-(S)-ISOLEUCINE (JaIle) 3-oxo-2-pentylcyclopentaneacetic acid (+)-trans-Jasmonic Acid Methyl isocostate L-Isoleucine, N-[2-[(1R,2S)-3-oxo-2-(2Z)-2-penten-1-ylcyclopentyl]acetyl]- (±)-JASMONIC ACID METHYL ESTER (MeJA) CYCLOPENTYLACETIC ACID Jasmone CIS-2-PENTENE Methyl dihydrojasmonate METHYL JASMONATE 95+% (+/-)-JASMONIC ACID METHYL JASMONATE

(1R)-3-Oxo-2α-[(Z)-2-pentenyl]-1α-cyclopentaneacetic acid methyl ester

(1R)-3-Oxo-2α-[(Z)-2-pentenyl]cyclopentane-1α-acetic acid methyl ester

(1R,2S)-2-[(Z)-2-Pentenyl]-3-oxocyclopentane-1-acetic acid methyl ester

Methyl 3R,7S-jasmonate

(1R)-3-Oxo-2β-[(Z)-2-pentenyl]cyclopentaneacetic acid methyl ester

Methyl cis-jasmonate

Methyl 2-(3-oxo-2-((Z)-pent-2-enyl)-cyclopentyl)-acetate

(3R,7R)-Methyl jasmonate

Cmc_13964

Cmc_7389

Cyclopentaneacetic acid, 3-oxo-2-(2-pentenyl)-, methyl ester, (Z)-trans- (8ci)

(1R,2R)-3-Oxo-2-(2Z)-2-penten-1-ylcyclopentaneacetic acid methyl ester

methyl [1R-[1alpha,2beta(Z)]]-3-oxo-2-(pent-2-enyl)cyclopentaneacetate

TRANS-3-OCTEN-2-ONE 98+%

(-)-JASMONIC ACID METHYL ESTER 98% (HPLC)

(±)-JASMONIC ACID METHYL ESTER 95% (HPLC)

methyljasmonate,(E)-methyljasmonate

Cyclopentaneacetic acid, 3-oxo-2-(2Z)-2-pentenyl-, methyl ester, (1R,2R)-

2-(2-PENTENYL)-3-METHOXYCARBONYLMETHYLCYCLOPENTANONE

3-OXO-2-(2-PENTENYL)CYCLOPENTANEACETIC ACID METHYL ESTER

METHYL 3-OXO-2-(2-PENTENYL)CYCLOPENTANEACETATE

METHYL (+/-)-JASMINATE

METHYL (+/-)-JASMONATE

METHYL JASMONATE

JASMONIC ACID METHYL ESTER

FEMA 3410

,2beta(z)]]-

3-oxo-2-(2-pentenyl)-,methylester,[1R-[1.alpha.,2.beta.(Z)]]-Cyclopentaneaceticacid

Cyclopentaneacetic acid, 3-oxo-2-(2-pentenyl)-, methyl ester, [1R-[1alpha,2beta(Z)]]-

Cyclopentaneacetic acid, 3-oxo-trans-2-(cis-2-pentenyl), methyl ester

Cyclopentaneaceticacid,3-oxo-2-(2-pentenyl)-,methylester,[1R-[1.alpha.,2.beta.(Z)]]-

cyclopentaneaceticacid,3-oxo-2-(2-pentenyl)-,methylester,[1theta-[1alpha

Cyclopentaneaceticacid,3-oxo-trans-2-(cis-2-pentenyl),methylester

Methyl (3-oxo-2-[(2E)-2-pentenyl]cyclopentyl)acetate

methyl(1r-(1a,2b(z)))

methyl(1r-(1a,2b(z)))-3-

methyl(1r-(1a,2b(z)))-3-oxo-2-(pent-2-enyl)cyclopentaneacetate

Methyl 2-((1R,2R)-3-oxo-2-((Z)-pent-2-en-1-yl)cyclopentyl)acetate

(Z)-methyl epi-jasmonate

Anabasine Methyl (2-pent-2-enyl-3-oxo-1-cyclopentyl)acetate

Jasmonic Acid Impurity 6 ((-)-Jasmonic Acid Methyl Ester)

(-)-methyljasmonate

METHYL JASMONATE USP/EP/BP

JASMONEIGE

Methyl Jasmonate CAS No.?1211-29-6?with Best Price

Methyl [1R-[1?,2?(Z)]]-3-oxo-2-(pent-2-enyl)cyclopentaneacetate

2-Nitro-5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalene 102121-55-1

METHYL JASMONATE,Methyl dihydrojasmonate

1211-29-6

39924-52-3

Organic Building Blocks

Esters

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C12 to C63

Carbonyl Compounds

Building Blocks

Aromatic Esters