DIIRON NONACARBONYL Property

Melting point:

100 °C

Boiling point:

209°C (rough estimate)

Density 

2,85 g/cm³

storage temp. 

2-8°C

form 

crystal

Specific Gravity

2.85

color 

yellow to orange

Water Solubility 

Insoluble in water.

Sensitive 

Air Sensitive

Exposure limits

ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3

EPA Substance Registry System

Iron, tri-.mu.-carbonylhexacarbonyldi-, (Fe-Fe) (15321-51-4)

Safety

Hazard Codes 

F,T

Risk Statements 

11-23/25

Safety Statements 

16-28-36/37/39-45

RIDADR 

UN 2930 6.1/PG 2

WGK Germany 

3

F 

4.8-25

TSCA 

Yes

HazardClass 

6.1

PackingGroup 

II

HS Code 

29310099

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

H261In contact with water releases flammable gas

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

DIIRON NONACARBONYL Chemical Properties,Usage,Production

Description

This carbonyl is obtained as dark yellow platelets by exposing solutions of the pentacarbonyl in organic solvents to sunlight or ultraviolet irradiation.

Chemical Properties

yellow to orange platelets

Uses

It is an important reagent in organometallic chemistry and of occasional use in organic synthesis.

Uses

Reacts with phenylsilanes to give triply bridged diiron complexes.

Purification Methods

Wash it with EtOH and Et2O, then dry it in air. It sublimes at 35o at high vacuum. It forms dark yellow plates which are stable for several days when kept in small amounts. Large amounts, especially when placed in a desiccator, spontaneously ignite in a period of one day. It decomposes in moist air. It is insoluble in hydrocarbon solvents but forms complexes with several organic compounds. [Sheline & Pitzer J Am Chem Soc 72 1107 1950, Speyer & Wolf Chem Ber 60 1424 1927.] TOXIC.

Structure and conformation

Iron enneacarbonyl decomposes at 100°, but can be sublimed at 35°C in a high vacuum. It is insoluble in aliphatic hydrocarbons and reacts with many organic solvents to form mainly the pentacarbonyl or its substituted derivatives. These properties have considerably hindered structural studies ; the infrared spectrum, for example, can only be measured in the solid. The X-ray crystal structure determination shows it to have the structure shown in Fig. 8 in which six carbon monoxide molecules are arranged around each iron atom in a slightly distorted octahedral array. The Fe-Fe distance is 2.46A, whilst the Fe-C distances are all around 1.85A. The Mossbauer spectrum also suggests that the iron atoms are in an octahedral environment. However, since the compound is diamagnetic it must contain an Fe-Fe bond as well as the three bridging carbonyl groups.