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ChemicalBook > CAS DataBase List > (1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%

(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%

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Product Name
(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%
CAS No.
546084-25-7
Chemical Name
(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%
Synonyms
(1R,2R)-[1,2-Cyclohexanediamino-N,N''-bis(4-bromobenzyl)allylchlorosilane;(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%;(1R,2R)-[1,2-CYCLOHEXANEDIAMINO-N,N''-BIS(4-BROMOBENZYL) ALLYLCHLOROSILANE,MIN. 98%;(3Ar,7ar)-2-allyl-1,3-bis(4-bromobenzyl)-2-chlorooctahydro-1h-benzo[d][1,3,2]diazasilole;(R,R)-1,3-Bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-allyl-1H-1,3,2-benzodiazasilole 95%;(R,R)-1,3-Bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-allyl-1H-1,3,2-benzodiazasilole ;1H-1,3,2-Benzodiazasilole, 1,3-bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-(2-propen-1-yl)-, (3aR,7aR)-;(3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-chloro-2-prop-2-enyl-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole
CBNumber
CB41180965
Molecular Formula
C23H27Br2ClN2Si
Formula Weight
554.82
MOL File
546084-25-7.mol
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(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98% Property

Boiling point:
561.2±60.0 °C(Predicted)
Density 
1.48±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
form 
solid
pka
6.37±0.20(Predicted)
color 
white
Sensitive 
moisture sensitive, store cold
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Safety

Hazard Codes 
F,C
Risk Statements 
15-34
Safety Statements 
26-36/37/39-43-45
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H261In contact with water releases flammable gas

H314Causes severe skin burns and eye damage

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P321Specific treatment (see … on this label).

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Strem Chemicals
Product number
14-1880
Product name
(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane, min. 98%
Packaging
250mg
Price
$95
Updated
2024/03/01
Strem Chemicals
Product number
14-1880
Product name
(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane, min. 98%
Packaging
1g
Price
$283
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ORS0000801
Product name
(R,R)-1,3-BIS[(4-BROMOPHENYL)METHYL]-2-CHLOROOCTAHYDRO-2-ALLYL-1H-1,3,2-BENZODIAZASILOLE
Purity
95.00%
Packaging
1G
Price
$525
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ORS0000801
Product name
(R,R)-1,3-BIS[(4-BROMOPHENYL)METHYL]-2-CHLOROOCTAHYDRO-2-ALLYL-1H-1,3,2-BENZODIAZASILOLE
Purity
95.00%
Packaging
5G
Price
$1193.96
Updated
2021/12/16
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(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98% Chemical Properties,Usage,Production

Reactions

  1. Reagent used in the enantioselective allylation of aldehydes.
  2. Useful reagent for the enantioselective allylation of sterically hindered and functionalized ketones.

Uses

Leighton′s Strained Silacycles: Powerful Enantioselective Allylation Reagents

  • Enantioselective allylation of aldehydes

(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98% Preparation Products And Raw materials

Raw materials

Preparation Products

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(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98% Suppliers

J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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Sigma-Aldrich
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021-61415566 800-8193336
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orderCN@merckgroup.com
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Aladdin Scientific
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+1-+1(833)-552-7181
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sales@aladdinsci.com
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546084-25-7, (1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%Related Search:


  • (R,R)-1,3-Bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-allyl-1H-1,3,2-benzodiazasilole
  • (R,R)-1,3-Bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-allyl-1H-1,3,2-benzodiazasilole 95%
  • (1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%
  • (1R,2R)-[1,2-CYCLOHEXANEDIAMINO-N,N''-BIS(4-BROMOBENZYL) ALLYLCHLOROSILANE,MIN. 98%
  • (3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-chloro-2-prop-2-enyl-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole
  • 1H-1,3,2-Benzodiazasilole, 1,3-bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-(2-propen-1-yl)-, (3aR,7aR)-
  • (3Ar,7ar)-2-allyl-1,3-bis(4-bromobenzyl)-2-chlorooctahydro-1h-benzo[d][1,3,2]diazasilole
  • (1R,2R)-[1,2-Cyclohexanediamino-N,N''-bis(4-bromobenzyl)allylchlorosilane
  • 546084-25-7
  • C23H27Br2CN2Si
  • C23H27Br2ClN2Si