(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%
Reactions- Product Name
- (1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%
- CAS No.
- 546084-25-7
- Chemical Name
- (1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%
- Synonyms
- (1R,2R)-[1,2-Cyclohexanediamino-N,N''-bis(4-bromobenzyl)allylchlorosilane;(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98%;(1R,2R)-[1,2-CYCLOHEXANEDIAMINO-N,N''-BIS(4-BROMOBENZYL) ALLYLCHLOROSILANE,MIN. 98%;(3Ar,7ar)-2-allyl-1,3-bis(4-bromobenzyl)-2-chlorooctahydro-1h-benzo[d][1,3,2]diazasilole;(R,R)-1,3-Bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-allyl-1H-1,3,2-benzodiazasilole 95%;(R,R)-1,3-Bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-allyl-1H-1,3,2-benzodiazasilole ;1H-1,3,2-Benzodiazasilole, 1,3-bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-(2-propen-1-yl)-, (3aR,7aR)-;(3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-chloro-2-prop-2-enyl-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole
- CBNumber
- CB41180965
- Molecular Formula
- C23H27Br2ClN2Si
- Formula Weight
- 554.82
- MOL File
- 546084-25-7.mol
(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98% Property
- Boiling point:
- 561.2±60.0 °C(Predicted)
- Density
- 1.48±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
- form
- solid
- pka
- 6.37±0.20(Predicted)
- color
- white
- Sensitive
- moisture sensitive, store cold
Safety
- Hazard Codes
- F,C
- Risk Statements
- 15-34
- Safety Statements
- 26-36/37/39-43-45
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H261In contact with water releases flammable gas
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P231+P232Handle under inert gas. Protect from moisture.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P321Specific treatment (see … on this label).
P363Wash contaminated clothing before reuse.
P370+P378In case of fire: Use … for extinction.
P402+P404Store in a dry place. Store in a closed container.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 14-1880
- Product name
- (1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane, min. 98%
- Packaging
- 250mg
- Price
- $95
- Updated
- 2024/03/01
- Product number
- 14-1880
- Product name
- (1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane, min. 98%
- Packaging
- 1g
- Price
- $283
- Updated
- 2024/03/01
- Product number
- ORS0000801
- Product name
- (R,R)-1,3-BIS[(4-BROMOPHENYL)METHYL]-2-CHLOROOCTAHYDRO-2-ALLYL-1H-1,3,2-BENZODIAZASILOLE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $525
- Updated
- 2021/12/16
- Product number
- ORS0000801
- Product name
- (R,R)-1,3-BIS[(4-BROMOPHENYL)METHYL]-2-CHLOROOCTAHYDRO-2-ALLYL-1H-1,3,2-BENZODIAZASILOLE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $1193.96
- Updated
- 2021/12/16
(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98% Chemical Properties,Usage,Production
Reactions
- Reagent used in the enantioselective allylation of aldehydes.
- Useful reagent for the enantioselective allylation of sterically hindered and functionalized ketones.
Uses
Leighton′s Strained Silacycles: Powerful Enantioselective Allylation Reagents
- Enantioselective allylation of aldehydes
(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98% Preparation Products And Raw materials
Raw materials
Preparation Products
(1R,2R)-[1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane,min.98% Suppliers
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