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ChemicalBook > CAS DataBase List > Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

Reaction
Product Name
Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)
CAS No.
106681-15-6
Chemical Name
Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)
Synonyms
(S)-Ru(OAc)2(T-BINAP);Ru(OAc)2[(S)-tolbinap];RU[(S)-T-BINAP](OCOH3)2;Ru[(S)-T-BINAP](OCOCH3)2;RU(OAC)2[(S)-TOLBINAP];Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II);Bis(acetato)[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine]]ruthenium;Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap];Ruthenium, bis(acetato-kO,kO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)phosphine-kP]]-, (OC-6-22)-
CBNumber
CB41181063
Molecular Formula
C48H40P2.C4H6O4Ru
Formula Weight
897.949
MOL File
106681-15-6.mol
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Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Property

Melting point:
>100°C
storage temp. 
2-8°C
form 
Powder
color 
brown
Sensitive 
air sensitive
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2843.90.0000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
693197
Product name
(S)-Ru(OAc)2(T-BINAP)
Packaging
500mg
Price
$121
Updated
2023/06/20
Sigma-Aldrich
Product number
693197
Product name
(S)-Ru(OAc)2(T-BINAP)
Packaging
100mg
Price
$31.5
Updated
2023/01/07
TCI Chemical
Product number
R0169
Product name
Ru(OAc)2[(S)-tolbinap]
Packaging
200mg
Price
$41
Updated
2024/03/01
TCI Chemical
Product number
R0169
Product name
Ru(OAc)2[(S)-tolbinap]
Packaging
1g
Price
$134
Updated
2024/03/01
Strem Chemicals
Product number
44-0163
Product name
Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap]
Packaging
250mg
Price
$53
Updated
2024/03/01
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Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Chemical Properties,Usage,Production

Reaction

Catalyst system that exhibits high catalytic activity and enantioselectivity in the hydrogenation of enamines.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) manufacturers

Career Henan Chemical Co
Product
Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) 106681-15-6
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

106681-15-6, Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)Related Search:


  • Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • (S)-Ru(OAc)2(T-BINAP)
  • Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap]
  • Bis(acetato)[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine]]ruthenium
  • Ruthenium, bis(acetato-kO,kO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)phosphine-kP]]-, (OC-6-22)-
  • RU(OAC)<SUB>2</SUB>[(<I>S</I>)-TOLBINAP]
  • Ru(OAc)2[(S)-tolbinap]
  • RU[(S)-T-BINAP](OCOH3)2
  • Ru[(S)-T-BINAP](OCOCH3)2
  • 106681-15-6
  • C52H46O4P2Ru
  • Ru