Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

Reaction

Product Name: Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
CAS No.: 944450-44-6
Chemical Name: Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
Synonyms: RuCl2[(S)-(DM-SEGPHOS®)][(S)-DAIPEN];RuCl2[(S)-(DM-SEGPHOS)][(S)-DAIPEN];RuCl2[(S)-(DM-SEGPHOS(R))][(S)-DAIPEN];RuCl2[(S)-dm-segphos(regR)][(S)-daipen];RuCl2[(S)-(DM-SEGPHOS®RuCl2[(S)-dm-segphos(regR)][(S)-daipen] RuCl2[(S)-dm-segphos][(S)-daipen];Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II);Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II);Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S)-daipen]
CBNumber: CB41181078
Molecular Formula: C65H70Cl2N2O6P2Ru
Formula Weight: 1209.2
MOL File: 944450-44-6.mol

More

Less

Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Property

storage temp.: 2-8°C
form: Powder
color: yellow
Sensitive: air sensitive
CAS DataBase Reference: 944450-44-6

More

Less

Safety

HS Code: 2843.90.0000

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H360May damage fertility or the unborn child

H371May cause damage to organs

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P309+P311IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

P405Store locked up.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 693219
Product name: RuCl2[(S)-(DM-SEGPHOS?)][(S)-DAIPEN]
Packaging: 100mg
Price: $25.16
Updated: 2024/03/01

Sigma-Aldrich

Product number: 693219
Product name: RuCl2[(S)-(DM-SEGPHOS?)][(S)-DAIPEN]
Packaging: 50mg
Price: $31
Updated: 2023/06/20

TCI Chemical

Product number: R0128
Product name: RuCl2[(S)-dm-segphos[R]][(S)-daipen]
Packaging: 200mg
Price: $68
Updated: 2024/03/01

TCI Chemical

Product number: R0128
Product name: RuCl2[(S)-dm-segphos[R]][(S)-daipen]
Packaging: 1g
Price: $237
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0215
Product name: Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(S)-dm-segphos(R)][(S)-daipen]
Packaging: 250mg
Price: $64
Updated: 2024/03/01

More

Less

Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Chemical Properties,Usage,Production

Reaction

Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Suppliers

Belgium 2 China 15 France 1 Germany 1 India 1 Japan 3 Switzerland 1 United States 9 Global 33

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-400-6206333 18521732826
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51456
Advantage: 80

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.

Tel: 0371-65511006 18625597674
Email: sales@kingorgchem.com
Country: China
ProdList: 953
Advantage: 55

Aikon International Limited

Tel: 025-66113011 13155353615
Fax: (7)02557626880
Email: qzhang@aikonchem.com
Country: China
ProdList: 15394
Advantage: 58

Shanghai SPAR pharmaceutical technology co., LTD

Tel: 021-000000
Email: admin@jingshipharmatech.com
Country: China
ProdList: 9993
Advantage: 58

Changzhou Carman Chemical Co., ltd

Tel: 0519-0519-83534936 18151214939
Email: 1521178147@qq.com
Country: China
ProdList: 508
Advantage: 58

TCI Chemicals

Tel: 021-67121386, 800-988-0390
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 5391
Advantage: 58

944450-44-6, Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)Related Search:

Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl) aMino]rutheniuM(II), Min.98% Ru-MACHO BH Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen]　 Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen] Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen]　 (S)-Daipen

Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

RuCl2[(S)-dm-segphos(regR)][(S)-daipen]

Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(S)-dm-segphos(R)][(S)-daipen]

[4-[5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl]-1,3-benzodioxol-5-yl]-bis(3,5-dimethylphenyl)phosphane:(2S)-1,1-bis(4-methoxyphenyl)-3-methylbutane-1,2-diamine:ruthenium(2+):dichloride

RuCl2[(S)-dm-segphos(regR)][(S)-daipen] RuCl2[(S)-dm-segphos][(S)-daipen]

RuCl2[(S)-(DM-SEGPHOS(R))][(S)-DAIPEN]

Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S)-daipen]

RuCl2[(S)-(DM-SEGPHOS)][(S)-DAIPEN]

RuCl2[(S)-(DM-SEGPHOS&reg

)][(S)-DAIPEN]

RuCl2[(S)-(DM-SEGPHOS&reg

Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

944450-44-6