1,3-Bis(diphenylphosphino)propane

Product Name: 1,3-Bis(diphenylphosphino)propane
CAS No.: 6737-42-4
Chemical Name: 1,3-Bis(diphenylphosphino)propane
Synonyms: DPPP;1,3-bis(diphenyphosphino)propane;Bis(1,3-diphenylphosphino)propane;1,3-BIS(DIPHENYLPHOSPHINE)PROPANE;98% DPPP;1,3-Bis(diphenyL;phosphino)propane;PH2PCH2 CH2CH2PPH2;1,3-BIS(DIPHENYPHOSPHINO);1,3-bis-(diphosphino)propane
CBNumber: CB4132404
Molecular Formula: C27H26P2
Formula Weight: 412.45
MOL File: 6737-42-4.mol

More

Less

1,3-Bis(diphenylphosphino)propane Property

Melting point:: 63-65 °C (lit.)
Boiling point:: 529.7±33.0 °C(Predicted)
Flash point:: 235°C
storage temp.: Inert atmosphere,Room Temperature
form: Granules or Powder
color: White to light yellow-beige
Water Solubility: insoluble
Sensitive: Air Sensitive
BRN: 2821785
InChI: InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChIKey: LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES: P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
CAS DataBase Reference: 6737-42-4(CAS DataBase Reference)
NIST Chemistry Reference: 1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPA Substance Registry System: Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39-36
WGK Germany: 3
F: 10-23
TSCA: Yes
HS Code: 29310095

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 262048
Product name: 1,3-Bis(diphenylphosphino)propane
Purity: 97%
Packaging: 1g
Price: $35.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 262048
Product name: 1,3-Bis(diphenylphosphino)propane
Purity: 97%
Packaging: 5g
Price: $65.3
Updated: 2024/03/01

TCI Chemical

Product number: B1138
Product name: 1,3-Bis(diphenylphosphino)propane
Purity: >98.0%(GC)
Packaging: 5g
Price: $34
Updated: 2024/03/01

TCI Chemical

Product number: B1138
Product name: 1,3-Bis(diphenylphosphino)propane
Purity: >98.0%(GC)
Packaging: 25g
Price: $79
Updated: 2024/03/01

Alfa Aesar

Product number: A12931
Product name: 1,3-Bis(diphenylphosphino)propane, 97%
Packaging: 5g
Price: $76.9
Updated: 2024/03/01

More

Less

1,3-Bis(diphenylphosphino)propane Chemical Properties,Usage,Production

Description

1,3-Bis(diphenylphosphino)propane is a ligand for metal-catalyzed substitution reactions of aryl and vinyl triflates, halides, and carbonates; carbonylation reactions; Grignard coupling; diene alkylation; macrocycle synthesis.

Chemical Properties

white to light yellow crystal powde

Uses

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

reaction suitability

reagent type: ligand
reaction type: C-C Bond Formation
reagent type: ligand
reaction type: Carbonylations
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

1,3-Bis(diphenylphosphino)propane Preparation Products And Raw materials

Raw materials

Diphenylphosphine Ethanol 1,3-Dichloropropane Acetone Sodium 1,3-Dibromopropane Tetrahydrofuran Ethyl acetate Hydrochloric acid Dichloromethane Sodium hydroxide Triphenylphosphine Magnesium sulfate Lithium n-Butyllithium

Preparation Products

3-DODECYLTHIOPHENE [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

More

Less

1,3-Bis(diphenylphosphino)propane Suppliers

Americas 1 Austria 1 Belgium 3 Canada 1 China 389 Europe 3 France 2 Germany 9 India 19 Japan 8 Russia 1 Singapore 1 Switzerland 4 Ukraine 2 United Kingdom 14 United States 51 Global 509

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

Melrob-Chemiplus Limited

Tel: --
Fax: --
Email: info@melrob-chemiplus.com
Country: Japan
ProdList: 208
Advantage: 58

Hokko Chemical Industry Co., Ltd.

Tel: --
Fax: --
Email: info@hokkochem.co.jp
Country: Japan
ProdList: 41
Advantage: 58

Kemprotec Limited (Japan)

Tel: --
Fax: --
Country: Japan
ProdList: 50
Advantage: 58

Fine Corporation

Tel: --
Fax: --
Email: info@fine-c.jp
Country: Japan
ProdList: 1427
Advantage: 58

HOKKO Chemical Industry Co.,Ltd.

Tel: --
Fax: --
Email: toiawase@hokkochem.co.jp
Country: Japan
ProdList: 163
Advantage: 73

Wako Pure Chemical Industries, Ltd.

Tel: --
Fax: --
Email: labchem-tec@wako-chem.co.jp
Country: Japan
ProdList: 6819
Advantage: 80

Kanto Chemical Co., Inc.

Tel: --
Fax: --
Email: reag-info@gms.kanto.co.jp
Country: Japan
ProdList: 6756
Advantage: 74

More

Less

View Lastest Price from 1,3-Bis(diphenylphosphino)propane manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: 1,3-Bis(diphenylphosphino)propane 6737-42-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-10-20

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 1,3-Bis(diphenylphosphino)propane 6737-42-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-06

Shanghai UCHEM Inc.

Product: 1,3-Bis(diphenylphosphino)propane 6737-42-4
Price: US $10.00-178.00/g
Min. Order: 25g
Purity: 0.98
Supply Ability: 100kg
Release date: 2023-10-20

6737-42-4, 1,3-Bis(diphenylphosphino)propaneRelated Search:

BIS-Tris Propane Di(trimethylol propane) Diphenylmethane tert-Butylchlorodiphenylsilane N-(Carboxymethyl)-N-(phosphonomethyl)-glycine Diphenylsilane Chlorodiphenylphosphine Diphenylphosphine 1,1'-Bis(diphenylphosphino)ferrocene 1,2-Bis(diphenylphosphino)ethane 1,4-Bis(diphenylphosphino)butane Propane DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) (2R,4R)-(+)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE (2S,4S)-(-)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE TRIMETHYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE)

1,3-BIS(DIPHENYLPHOSPHINE)PROPANE

1,3-BIS(DIPHENYLPHOSPHINO)PROPANE

DPPP

TRIMETHYLENEBIS(DIPHENYLPHOSPHINE)

[3-(Diphenylphosphino)propyl](diphenyl)phosphine

1,3-Propanediylbis(diphenylphosphine)

Bis(1,3-diphenylphosphino)propane

Phosphine, 1,3-propanediylbis[diphenyl-

Phosphine, trimethylenebis(diphenyl-

Propane-1,3-diylbis(diphenylphosphine)

PROPYLENEBIS(DIPHENYLPHOSPHINE)

1,3-bis(diphenyphosphino)propane

1,3-bis(diphenyphosphino)propane(dppp)

1,3-Bis(Diphenlphosphino)Propane

1,3-Bis(diphenylphosphino)propane,98%DPPP

DPPP/ 1,3-BIS(DIPHENYLPHOSPHINE)PROPANE

DPPP/1,3-BIS- (DIPHENYLPHOSPHINO)PROPANE

PH2PCH2 CH2CH2PPH2

1,3-propanediylbis[diphenyl-phosphin

1, 3 - a double (diphenyl phosphine) propane

1,3-Bis(diphenylphosphino)propane Propane-1,3-diylbis(diphenylphosphine)

1-(phenyl(3-(diphenylphosphino)propyl)phosphino)benzene

,3-Bis(diphenylphosphino)propane

1,3-bis-(diphosphino)propane

1,3-Bis(diphenyL

phosphino)propane

1,3-BIS(DIPHENYPHOSPHINO)

1,3-Bis(diphenylphosphino)propane, C 77.5%, H 6.5%

1,3-Bis(diphenylphosphino)propane,97%

3-Di(phenyl)phosphanylpropyl-di(phenyl)phosphane

1,3-Bis(diphenylphosphino)propane ,98%

1,3-Bis(diphenylphosphino)propane, 97% 5GR

98% DPPP

1,3-Bis(diphenylphosphiNA)propane

1,3-Bis(diphenylphosphino)prop

Bis diphenylphosphino propane

Propane-1,3-diylbis(diphenylphosphane) 98%

Propane-1,3-diylbis(diphenylphosphine), 1,3-Bis(diphenylphosphino)propane

1,3- double(twophenylphosphine groups)propane(DPPP)

1,3-Bis(diphenylphosphino)propane, 95+%

1,3-Bis(diphenylphosphino)propane &gt

1,3-Bis(diphenylphosphino)propane, 97%, for synthesis

Phosphine, 1,1'-(1,3-propanediyl)bis[1,1-diphenyl-

1,3- bis(diphenylphosphaneyI)propane (DPPP)

DPPP (1,3-Bis(Diphenylphosphino)Propane) extrapure, 98%

1,3-Bis(diphenylphosphanyl)propane

6737-42-4

C6H52PCH2CH2CH2PC6H52

C6H52PCH23PC6H52

C27H26P2

Phosphine Ligands

Phosphorus Compounds

Polydentate Phosphine Ligands

Catalysis and Inorganic Chemistry

Phosphine Ligands

Synthetic Organic Chemistry

Ligand

API intermediates