ChemicalBook > CAS DataBase List > L-Threonine Benzyl Ester Hydrochloride

L-Threonine Benzyl Ester Hydrochloride

Product Name
L-Threonine Benzyl Ester Hydrochloride
CAS No.
33645-24-8
Chemical Name
L-Threonine Benzyl Ester Hydrochloride
Synonyms
L-THR;L-THR;L-Thr-OBzl HCl;L-THREONINE BENZYL ESTER HCL;Benzyl L-threoninate hydrochloride;L-THREONINE BENZYL ESTER HYDROCHLORIDE;L-THREONINE BENZYL ESTER HYDROCHLORIDE USP/EP/BP;L-Threonine, phenylmethyl ester, hydrochloride (1:1);L-Threonine Benzyl Ester Hydrochloride;benzyl (2S,3R)-2-amino-3-hydroxybutanoate hydrochloride
CBNumber
CB41505896
Molecular Formula
C11H16ClNO3
Formula Weight
245.70264
MOL File
33645-24-8.mol
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L-Threonine Benzyl Ester Hydrochloride Property

Melting point:
128.0 to 132.0 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
powder to crystal
color 
White to Almost white
InChI
InChI=1/C11H15NO3.ClH/c1-8(13)10(12)11(14)15-7-9-5-3-2-4-6-9;/h2-6,8,10,13H,7,12H2,1H3;1H/t8-,10+;/s3
InChIKey
IDZGTFSDZJVMSD-YFYURQRANA-N
SMILES
C(OCC1=CC=CC=C1)(=O)[C@H]([C@H](O)C)N.[H]Cl |&1:10,11,r|
CAS DataBase Reference
33645-24-8
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Safety

HS Code 
2922500090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T2677
Product name
L-Threonine Benzyl Ester Hydrochloride
Purity
>98.0%(HPLC)(N)
Packaging
1g
Price
$36
Updated
2024/03/01
TCI Chemical
Product number
T2677
Product name
L-Threonine Benzyl Ester Hydrochloride
Purity
>98.0%(HPLC)(N)
Packaging
5g
Price
$111
Updated
2024/03/01
TRC
Product number
B535585
Product name
Benzyl(2S,3R)-2-Amino-3-hydroxybutanoateHydrochloride
Packaging
10mg
Price
$45
Updated
2021/12/16
TRC
Product number
B535585
Product name
Benzyl(2S,3R)-2-Amino-3-hydroxybutanoateHydrochloride
Packaging
50mg
Price
$60
Updated
2021/12/16
Activate Scientific
Product number
AS48599
Product name
(2S,3R)-Benzyl 2-amino-3-hydroxybutanoate hydrochloride
Purity
98%
Packaging
5G
Price
$66
Updated
2021/12/16
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L-Threonine Benzyl Ester Hydrochloride Chemical Properties,Usage,Production

References

[1] Charles M, et al. Serine and Threonine Schiff Base Esters React with β-Anomeric Peracetates in the Presence of BF3·Et2O to Produce β-Glycosides. Journal of Carbohydrate Chemistry, 2010; 29.

Uses

L-threonine benzyl ester hydrochloride salt was reacted with the diaryl ketimine bis-(4-methoxyphenyl)-methenamine in CH3CN at rt to form the more nucleophilic L-threonine Schiff base (Benzyl N-bis (4-methoxyphenyl)methylene-L-threoninate) in excellent yield. In addition, L-threonine Schiff base, acting as glycosyl acceptor, reacted at rt with simple sugar peracetate donor with BF3·OEt2 promotion to provide the corresponding L-threonine O-linked glycosides in excellent yields and purities[1].

Preparation

The benzyl ester hydrochloride salt, L-Threonine Benzyl Ester Hydrochloride, was  prepared from L-threonine and PhCH2OH in the presence of p-toluenesulfonic acid[1]. Specifically, L-Threonine (4.0 g, 34 mmol) and pTsOH acid monohydrate (7.10 g, 38 mmol) were reacted with benzyl alcohol (40 mL) in 50 mL dry benzene using a Dean-Stark apparatus according to the procedure of Petursson and Bald-win. Yield:71.3%

L-Threonine Benzyl Ester Hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from L-Threonine Benzyl Ester Hydrochloride manufacturers

Sichuan HongRi Pharma-Tech Co.,Ltd
Product
L-Thr-Obzl.HCl 33645-24-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1T+
Release date
2024-04-03
Sichuan Jiaying Lai Technology Co.,LTD
Product
L-Thr-Obzl.HCl 33645-24-8
Price
US $1.00/g
Min. Order
1g
Purity
98%
Supply Ability
100KG
Release date
2019-07-29
Career Henan Chemical Co
Product
L-THREONINE BENZYL ESTER HYDROCHLORIDE 33645-24-8
Price
US $1.00-2.00/KG
Min. Order
1KG
Purity
95%-99%
Supply Ability
100KG
Release date
2019-08-29

33645-24-8, L-Threonine Benzyl Ester HydrochlorideRelated Search:


  • L-THREONINE BENZYL ESTER HYDROCHLORIDE
  • L-THREONINE BENZYL ESTER HCL
  • (2S,3R)-Benzyl 2-aMino-3-hydroxybutanoate hydrochloride
  • Benzyl L-threoninate hydrochloride
  • L-Thr-OBzl HCl
  • <small>L</small>-Threonine Benzyl Ester Hydrochloride
  • benzyl (2S,3R)-2-amino-3-hydroxybutanoate hydrochloride
  • L-THREONINE BENZYL ESTER HYDROCHLORIDE USP/EP/BP
  • L-Threonine, phenylmethyl ester, hydrochloride (1:1)
  • L-THR
  • L-THR
  • 33645-24-8