6-CHLORO-N-METHYLPYRIDIN-2-AMINE
- Product Name
- 6-CHLORO-N-METHYLPYRIDIN-2-AMINE
- CAS No.
- 89026-78-8
- Chemical Name
- 6-CHLORO-N-METHYLPYRIDIN-2-AMINE
- Synonyms
- Liranaftatum intermedaite;6-Chloro-2-methylaminopyridine;Pyrimidine,2,4-dichloro-9-iodo-;6-CHLORO-N-METHYLPYRIDIN-2-AMINE;6-Chloro-N-methylpyridine-2-amine;2-PyridinaMine, 6-chloro-N-Methyl-;(6-Chloro-pyridin-2-yl)-Methyl-aMine;Cyclobutanecarboxylicacid,3,8-difluoro-;Benzene,1,3,5-tribromo-2,4,11-trimethyl-;α-D-Glucopyranuronicacid,methylester,2,3,7-triacetate
- CBNumber
- CB41517767
- Molecular Formula
- C6H7ClN2
- Formula Weight
- 142.59
- MOL File
- 89026-78-8.mol
6-CHLORO-N-METHYLPYRIDIN-2-AMINE Property
- Boiling point:
- 253.3±20.0 °C(Predicted)
- Density
- 1.250±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- pka
- 3.20±0.10(Predicted)
- form
- solid
- color
- Off-white
Safety
- HazardClass
- IRRITANT
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- C350005
- Product name
- 6-Chloro-N-methylpyridin-2-amine
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- OR917005
- Product name
- 6-Chloro-N-methylpyridin-2-amine
- Purity
- 98%
- Packaging
- 5g
- Price
- $250
- Updated
- 2021/12/16
- Product number
- OR917005
- Product name
- 6-Chloro-N-methylpyridin-2-amine
- Purity
- 98%
- Packaging
- 1g
- Price
- $100
- Updated
- 2021/12/16
- Product number
- 052705
- Product name
- 6-Chloro-N-methyl-2-pyridinamine
- Packaging
- 2.500g
- Price
- $130
- Updated
- 2021/12/16
- Product number
- 3H31-5-AT
- Product name
- 6-Chloro-N-methylpyridin-2-amine
- Purity
- 98%
- Packaging
- 1g
- Price
- $160
- Updated
- 2021/12/16
6-CHLORO-N-METHYLPYRIDIN-2-AMINE Chemical Properties,Usage,Production
Synthesis
2402-78-0
74-89-5
89026-78-8
GENERAL METHOD: 2,6-dichloropyridine (4.22 mmol), a catalytic amount of cuprous iodide (CuI, 10 mg, 0.052 mmol), and water (100 μL) were placed in a 5 mL microwave reaction vial, and 6 equivalents of monomethylamine were added. For aniline-based reactions, additional tetrakis(triphenylphosphine)palladium (Pd(PPh3)4, 10 mg, 0.008 mmol) was added. After completion of the reaction (refer to Table 1), 2 equivalents of potassium carbonate (K2CO3) solid were added. The reaction mixture was filtered and washed with water to give an analytically pure crystalline solid product. Subsequently, purification was performed by rapid column chromatography (Method A) or ball-to-ball distillation (Method B) to remove all volatiles. When aqueous solutions of methylamine or ethylamine are used as reactants, no additional water is added.
References
[1] Tetrahedron, 2015, vol. 71, # 42, p. 8104 - 8110
[2] Patent: US2006/69110, 2006, A1. Location in patent: Page/Page column 57
[3] Patent: WO2017/141036, 2017, A1. Location in patent: Page/Page column 51; 52
6-CHLORO-N-METHYLPYRIDIN-2-AMINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 6-CHLORO-N-METHYLPYRIDIN-2-AMINE manufacturers
- Product
- 6-chloro-N-methylpyridin-2-amine 89026-78-8
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000 tons
- Release date
- 2019-12-27
- Product
- 6-CHLORO-N-METHYLPYRIDIN-2-AMINE 89026-78-8
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
- Product
- 6-CHLORO-N-METHYLPYRIDIN-2-AMINE 89026-78-8
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09