ChemicalBook > CAS DataBase List > ethyl 4,4,4-trifluorobut-2-enoate

ethyl 4,4,4-trifluorobut-2-enoate

Product Name
ethyl 4,4,4-trifluorobut-2-enoate
CAS No.
406-10-0
Chemical Name
ethyl 4,4,4-trifluorobut-2-enoate
Synonyms
ethyl 4,4,4-trifluorobut-2-enoate;4,4,4-trifluoro-2-Butenoic acid ethyl ester;2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester
CBNumber
CB41551282
Molecular Formula
C6H7F3O2
Formula Weight
168.11
MOL File
406-10-0.mol
More
Less

ethyl 4,4,4-trifluorobut-2-enoate Property

Density 
1.125 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.3601(lit.)
Flash point:
26°C
Boiling point:
114-115°C(lit.)
More
Less

Safety

RIDADR 
UN 3272 3 / PGIII
WGK Germany 
3
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
269697
Product name
Ethyl 4,4,4-trifluorocrotonate
Purity
98%
Packaging
5g
Price
$77.2
Updated
2024/03/01
More
Less

ethyl 4,4,4-trifluorobut-2-enoate Chemical Properties,Usage,Production

Uses

Ethyl 4,4,4-trifluorocrotonate was used in the synthesis of (2S,3S)-3-methyl- and (2S,3S)-3-trifluoromethylpyroglutamic acid. It undergoes diastereoselective Michael addition reaction with ethyl crotonate.

General Description

The Michael reaction between ethyl 4,4,4-trifluorocrotonate and a Ni(II) complex of the Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone was studied.

ethyl 4,4,4-trifluorobut-2-enoate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

ethyl 4,4,4-trifluorobut-2-enoate Suppliers

Anichem Inc.
Tel
0512-69369885
Fax
0512-69369880
Email
sales@anichem.com.cn
Country
China
ProdList
497
Advantage
55
Shanghai Tombiopharma Chemical Co. Ltd.
Tel
13391076197
Email
tombiopharma@163.com
Country
China
ProdList
4992
Advantage
55
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51471
Advantage
80
Zhengzhou Huiju Chemical Co., Ltd.
Tel
0371-55900031 18137872243
Fax
QQ:2853979815
Email
2853979815@qq.com
Country
China
ProdList
10014
Advantage
55
Nanjing Chemedicine BioTech Co., Ltd.
Tel
15722927296
Fax
-
Email
71139532@qq.com
Country
China
ProdList
427
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
0551-65418671
Fax
0551-65418697
Email
sales@tnjchem.com
Country
China
ProdList
34572
Advantage
58
TCI (Shanghai) Chemical Trading Co., Ltd.
Tel
021-61109150
Fax
021-61105897
Email
sales@tcisct.com
Country
China
ProdList
31183
Advantage
58
Bide Pharmatech Ltd.
Tel
400-1647117 15221909166
Email
product02@bidepharm.com
Country
China
ProdList
61720
Advantage
58
Aikon International Limited
Tel
18626450290
Email
yftan@aikonchem.com
Country
China
ProdList
10718
Advantage
58
Hangzhou Mingma Technology Co., LTD
Tel
17621758100
Email
xinming1991@126.com
Country
China
ProdList
97
Advantage
58

406-10-0, ethyl 4,4,4-trifluorobut-2-enoateRelated Search:


  • ethyl 4,4,4-trifluorobut-2-enoate
  • 2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester
  • 4,4,4-trifluoro-2-Butenoic acid ethyl ester
  • 406-10-0