ChemicalBook > CAS DataBase List > ethyl 4,4,4-trifluorobut-2-enoate

ethyl 4,4,4-trifluorobut-2-enoate

Product Name
ethyl 4,4,4-trifluorobut-2-enoate
CAS No.
406-10-0
Chemical Name
ethyl 4,4,4-trifluorobut-2-enoate
Synonyms
ethyl 4,4,4-trifluorobut-2-enoate;4,4,4-trifluoro-2-Butenoic acid ethyl ester;2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester
CBNumber
CB41551282
Molecular Formula
C6H7F3O2
Formula Weight
168.11
MOL File
406-10-0.mol
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ethyl 4,4,4-trifluorobut-2-enoate Property

Density 
1.125 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.3601(lit.)
Flash point:
26°C
form 
liquid
Boiling point:
114-115°C(lit.)
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Safety

RIDADR 
UN 3272 3 / PGIII
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
269697
Product name
Ethyl 4,4,4-trifluorocrotonate
Purity
98%
Packaging
5g
Price
$77.2
Updated
2024/03/01
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ethyl 4,4,4-trifluorobut-2-enoate Chemical Properties,Usage,Production

Uses

Ethyl 4,4,4-trifluorocrotonate was used in the synthesis of (2S,3S)-3-methyl- and (2S,3S)-3-trifluoromethylpyroglutamic acid. It undergoes diastereoselective Michael addition reaction with ethyl crotonate.

General Description

The Michael reaction between ethyl 4,4,4-trifluorocrotonate and a Ni(II) complex of the Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone was studied.

ethyl 4,4,4-trifluorobut-2-enoate Preparation Products And Raw materials

Raw materials

Preparation Products

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ethyl 4,4,4-trifluorobut-2-enoate Suppliers

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406-10-0, ethyl 4,4,4-trifluorobut-2-enoateRelated Search:


  • ethyl 4,4,4-trifluorobut-2-enoate
  • 2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester
  • 4,4,4-trifluoro-2-Butenoic acid ethyl ester
  • 406-10-0