ChemicalBook > CAS DataBase List > Ethyl α-bromophenylacetate

Ethyl α-bromophenylacetate

Product Name
Ethyl α-bromophenylacetate
CAS No.
2882-19-1
Chemical Name
Ethyl α-bromophenylacetate
Synonyms
Ethyl 2-bromo-2-phenylacetate;ETHYL 2-(2-BROMOPHENYL)ACETATE;ETHYL A-BROMOPHENYLACETATE;Einecs 220-735-2;ethyl à-bromophenylacetate;ethyleα-bromophenylacetate;ETHYL 2-BROMOPHENYLACETATE;Ethyl bromo(phenyl)acetate;Ethyl α-bromophenylacetate;ETHYL ALPHA-BROMOPHENYLACETATE
CBNumber
CB4161800
Molecular Formula
C10H11BrO2
Formula Weight
243.1
MOL File
2882-19-1.mol
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Ethyl α-bromophenylacetate Property

Boiling point:
89-92 °C/0.9 mmHg (lit.)
Density 
1.389 g/mL at 25 °C (lit.)
refractive index 
n20/D >1.5390(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Liquid
color 
Clear colorless to yellow
Water Solubility 
Not miscible or difficult to mix in water.
Sensitive 
Moisture Sensitive
InChIKey
BKTKLDMYHTUESO-UHFFFAOYSA-N
CAS DataBase Reference
2882-19-1(CAS DataBase Reference)
EPA Substance Registry System
Ethyl .alpha.-bromophenylacetate (2882-19-1)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
III
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
554065
Product name
Ethyl α-bromophenylacetate
Purity
97%
Packaging
25g
Price
$214
Updated
2024/03/01
Sigma-Aldrich
Product number
554065
Product name
Ethyl α-bromophenylacetate
Purity
97%
Packaging
100g
Price
$824
Updated
2024/03/01
Alfa Aesar
Product number
B21114
Product name
Ethyl alpha-bromophenylacetate, 97%
Packaging
10g
Price
$62.65
Updated
2024/03/01
Alfa Aesar
Product number
B21114
Product name
Ethyl alpha-bromophenylacetate, 97%
Packaging
50g
Price
$244
Updated
2024/03/01
Alfa Aesar
Product number
B21114
Product name
Ethyl alpha-bromophenylacetate, 97%
Packaging
250g
Price
$763.65
Updated
2024/03/01
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Ethyl α-bromophenylacetate Chemical Properties,Usage,Production

Uses

α-Bromobenzeneacetic acid ethyl ester is used as an alkyl halide initiator in controlled/living radical polymerization of styrene and methyl methacrylate.

Uses

ETHYL ALPHA-BROMOPHENYLACETATE is used as an alkyl halide initiator in controlled/living radical polymerization of styrene and methyl methacrylate.

Application

Ethyl α-bromophenylacetate (EBPA) may be used to synthesize α-ethoxycarbonyl-N,α-diphenylnitrone.
EBPA may be used as an initiator for the following:
polymerization of dimethyl(methacryloyloxymethyl) phosphonate
polymerization of methyl methacrylate (MMA)
polymerization of trimethylolpropane triacrylate(TMPTA)

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 4067, 1972 DOI: 10.1016/S0040-4039(01)94239-X

Precautions

Moisture sensitive. Store away from oxidizing agents, air and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Ethyl α-bromophenylacetate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ethyl α-bromophenylacetate manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
Ethyl α-bromophenylacetate 2882-19-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-13
Career Henan Chemical Co
Product
ETHYL ALPHA-BROMOPHENYLACETATE 2882-19-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2020-01-09

2882-19-1, Ethyl α-bromophenylacetateRelated Search:

Isopropyl(4-chlorophenyl)acetyl chloride 2,3'-Dichloroacetophenone PHENYL ACETATE Bromoacetic acid Ethyl phenylacetate Ethyl acetate 2'-BROMO-3,4-DICHLOROPHENYLACETIC ACID METHYL ESTER ETHYL 2-BROMO-(4-BROMOPHENYL)ACETATE ALPHA-BROMO-3-CHLOROBENZENEACETIC ACID ETHYL ESTER Ethyl α-bromophenylacetate ETHYL 2-(3-BROMOPHENYL)ACETATE A-BROMO-2,4-DICHLOROBENZENEACETIC ACID ETHYL ESTER BROMO-(4-FLUORO-PHENYL)-ACETIC ACID ETHYL ESTER ALPHA-BROMO-1-NAPHTHALENEACETIC ACID ETHYL ESTER ISOAMYL ALPHA-BROMOPHENYLACETATE ETHYL 2-BROMO-2-PHENYLPROPANOATE Ethyl α-bromo-p-chlorophenylacetate

  • Phenylbromoacetic acid ethyl ester
  • α-Bromobenzeneacetic acid ethyl ester
  • α-Bromophenylacetic acid ethyl ester
  • Einecs 220-735-2
  • 2-BroMo-2-phenylacetic Acid Ethyl Ester
  • DL-α-BroMophenylacetic Acid Ethyl Ester
  • Benzeneacetic acid,a-bromo-,ethyl ester
  • a-Bromophenylacetic acid ethyl ester
  • ALPHA-BROMOPHENYLACETIC ACID ETHYL ESTER
  • à-bromophenylacetic acid ethyl ester
  • Ethyl ɑ-bromophenylacetate, 97%
  • ethyl à-bromophenylacetate
  • Bromophenylacetic acid ethyl ester
  • Ethyl (±)-α-BroMobenzeneacetate
  • Bromo(phenyl)acetic acid ethyl ester, Ethyl 2-bromo-2-phenylethanoate
  • Ethyl alpha-bromophenylacetate 97%
  • ethyleα-bromophenylacetate
  • ETHYL ALPHA-BROMOPHENYLACETATE
  • ETHYL A-BROMOPHENYLACETATE
  • ETHYL 2-BROMOPHENYLACETATE
  • ETHYL 2-(2-BROMOPHENYL)ACETATE
  • Benzeneacetic acid, alpha-bromo-, ethyl ester
  • benzeneaceticacid,.alpha.-bromo-,ethyl
  • benzeneaceticacid,.alpha.-bromo-,ethylester
  • benzeneaceticacid,.alpha.-bromo-,ethylester(asimpurity)
  • Ethyl bromo(phenyl)acetate
  • Ethyl 2-bromo-2-phenylacetate
  • alpha-Bromobenzeneacetic acid ethyl ester
  • Benzeneacetic acid, α-bromo-, ethyl ester
  • Ethyl α-bromophenylacetate
  • Benzeneacetic acid, α-bromo-, ethyl ester
  • alpha phenyl alpha bromo ethyl acetate
  • 2882-19-1
  • 2178-24-1
  • C6H5CHBrCOOCH2CH3
  • ARYL HALIDE
  • Building Blocks
  • C10 to C11
  • Carbonyl Compounds
  • Esters
  • Organic Building Blocks
  • Esters
  • Phenyls & Phenyl-Het
  • C10 to C11
  • Carbonyl Compounds
  • Pharmaceutical Intermediates