ETHYL CIS-3-BROMOACRYLATE Property

Boiling point:

75 °C (12 mmHg)

Density 

1.48 g/mL at 20 °C

refractive index 

n20/D 1.481

storage temp. 

2-8°C

solubility 

soluble in Methanol

form 

clear liquid

color 

Colorless to Almost colorless

BRN 

1902817

Safety

Hazard Codes 

Xi,Xn

Risk Statements 

36/37/38-52/53-22

Safety Statements 

26-36-61

RIDADR 

UN 3082 9/PG 3

WGK Germany 

3

F 

19

HazardClass 

3

PackingGroup 

III

HS Code 

29161900

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

ETHYL CIS-3-BROMOACRYLATE Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

Ethyl cis-3-Bromoacrylate acts as a reagent in the synthetic preparation of aristeromycin and also in the preparation of lipoxin derivatives as new anti-inflammatory compounds.

Uses

Ethyl cis-3-bromoacrylate was used in the preparation of ethyl 2-amino-9-(2-deoxy-β-D-erythropentofuranosyl)-6,9-dihydro-6-oxo-1H-purine-1-acrylate. It was used in the synthesis of 3-(2-deoxy-β-D-erythro-pentofuranosyl)-3,4-dihydropyrimido[1,2-a]purine-6,10-dione. It was employed as building block for the stereoselective preparation of cis-2-enoates.