5-METHOXY-2-(1H-PYRROL-1-YL)ANILINE

Product Name: 5-METHOXY-2-(1H-PYRROL-1-YL)ANILINE
CAS No.: 59194-26-2
Chemical Name: 5-METHOXY-2-(1H-PYRROL-1-YL)ANILINE
Synonyms: 5-Methoxy-2-(1H-pyrrol-1-yl);5-Mehoxy-2-(1H-pyrrol-1-yl)aniline;5-METHOXY-2-(1H-PYRROL-1-YL)ANILINE;1-(2-Amino-4-methoxyphenyl)-1H-pyrrole;5-Methoxy-2-(1H-pyrrol-1-yl)benzenaMine;5-methoxy-2-(1H-pyrrol-1-yl)aniline (en);Benzenamine, 5-methoxy-2-(1H-pyrrol-1-yl)-;5-methoxy-2-(1H-pyrrol-1-yl)aniline(SALTDATA: 1HCl 0.5H2O)
CBNumber: CB4188683
Molecular Formula: C11H12N2O
Formula Weight: 188.23
MOL File: 59194-26-2.mol

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5-METHOXY-2-(1H-PYRROL-1-YL)ANILINE Property

Melting point:: 41-43°C
Boiling point:: 345.3±32.0 °C(Predicted)
Density: 1.13±0.1 g/cm3(Predicted)
storage temp.: 2-8°C(protect from light)
pka: 2.05±0.11(Predicted)

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
HazardClass: IRRITANT
HS Code: 2933998090

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC

Product number: M269463
Product name: 5-Methoxy-2-(1H-pyrrol-1-yl)aniline
Packaging: 50mg
Price: $45
Updated: 2021/12/16

Matrix Scientific

Product number: 045697
Product name: 5-Methoxy-2-(1H-pyrrol-1-yl)aniline
Purity: >95%
Packaging: 500mg
Price: $80
Updated: 2021/12/16

Matrix Scientific

Product number: 045697
Product name: 5-Methoxy-2-(1H-pyrrol-1-yl)aniline
Purity: >95%
Packaging: 1g
Price: $118
Updated: 2021/12/16

AK Scientific

Product number: W7208
Product name: 5-Methoxy-2-(1H-pyrrol-1-yl)aniline
Packaging: 1g
Price: $150
Updated: 2021/12/16

Apolloscientific

Product number: OR33286
Product name: 5-Methoxy-2-(1H-pyrrol-1-yl)aniline
Purity: 95%
Packaging: 1g
Price: $232
Updated: 2021/12/16

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5-METHOXY-2-(1H-PYRROL-1-YL)ANILINE Chemical Properties,Usage,Production

Synthesis

59194-25-1

59194-26-2

General procedure for the synthesis of 5-methoxy-2-(1H-pyrrol-1-yl)aniline from 1-(4-methoxy-2-nitrophenyl)-1H-pyrrole: a methanolic (10 mL) suspension of 1-(4-methoxy-2-nitrophenyl)-1H-pyrrole (3 mmol) and palladium carbon (10%, 60 mg) was stirred for 5 hours under the atmosphere of hydrogen balloon. Upon completion of the reaction, the black solid was removed by filtration and the filtrate was concentrated to afford the crude product of 5-methoxy-2-(1H-pyrrol-1-yl)aniline. The crude product was purified by fast silica gel column chromatography (eluent: ethyl acetate-hexane, gradient to 1:4) to afford the target product as a light yellow oil (97% yield).1H NMR (400 MHz, CDCl3) δ 7.13-7.09 (m, 1H), 6.83-6.82 (m, 2H), 6.40-6.37 (m, 4H), and 3.84 (s, 3H); 13C NMR (100 MHz, CDCl3) δ 159.9, 143.4, 128.2, 122.1, 121.2, 109.2, 103.6, 101.1, 55.4.

References

[1] Journal of Medicinal Chemistry, 2016, vol. 59, # 10, p. 4511 - 4525
[2] Patent: WO2017/149493, 2017, A1. Location in patent: Page/Page column 0150; 0151
[3] Journal of Medicinal Chemistry, 2004, vol. 47, # 8, p. 1997 - 2009
[4] Angewandte Chemie - International Edition, 2014, vol. 53, # 52, p. 14451 - 14455
[5] Angew. Chem., 2014, vol. 126, # 52, p. 14679 - 14683,5

5-METHOXY-2-(1H-PYRROL-1-YL)ANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-METHOXY-2-(1H-PYRROL-1-YL)ANILINE Suppliers

China 29 France 1 Germany 1 India 2 United Kingdom 2 United States 6 Global 41

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59194-26-2, 5-METHOXY-2-(1H-PYRROL-1-YL)ANILINERelated Search:

5-METHOXY-BENZO[B]THIOPHENE-2-CARBOXYLIC ACID 5-Methoxyisoindoline hydrochloride 5-METHOXY-2-METHYLBENZALDEHYDE 5-METHOXYPYRAZINE-2-CARBOXYLIC ACID 5-METHOXY-2,3-DIHYDRO-ISOINDOL-1-ONE 5-Methoxybenzofuran-2-carboxylic acid 3-Methoxy-6-Amino-2-Picoline 5-Methoxybenzofuran 5-METHOXY-PYRIDIN-3-OL 5-methoxy-1-benzothiophene IMidazo[1,2-a]pyridine,5-Methoxy- 5-METHOXY-1,3-BENZOTHIAZOL-2-AMINE Ethyl 5-methoxypyrazine-2-carboxylate 5-METHOXY-2-(1H-PYRROL-1-YL)ANILINE ASISCHEM R37792 1-(4-METHOXY-2-NITROPHENYL)-1H-PYRROLE-2-CARBALDEHYDE METHYL 3-NITRO-4-(1H-PYRROL-1-YL)PHENYL ETHER 2-(2,5-DIMETHYL-1H-PYRROL-1-YL)-5-METHOXYPHENYLAMINE

5-Mehoxy-2-(1H-pyrrol-1-yl)aniline

1-(2-Amino-4-methoxyphenyl)-1H-pyrrole

5-methoxy-2-(1H-pyrrol-1-yl)aniline (en)

5-methoxy-2-(1H-pyrrol-1-yl)aniline(SALTDATA: 1HCl 0.5H2O)

5-Methoxy-2-(1H-pyrrol-1-yl)benzenaMine

5-Methoxy-2-(1H-pyrrol-1-yl)

5-METHOXY-2-(1H-PYRROL-1-YL)ANILINE

Benzenamine, 5-methoxy-2-(1H-pyrrol-1-yl)-

59194-26-2