ChemicalBook > CAS DataBase List > BRUCINE
BRUCINE
- Product Name
- BRUCINE
- CAS No.
- 5892-11-5
- Chemical Name
- BRUCINE
- Synonyms
- BRUCINE ALKALOID;BURCINETETRAHYDRATE;BRUCINE TETRAHYDRATE;BRUCINE HYDRATE, TECH.;2,3-DIMETHOXYSTRYCHNIDIN-10-ONE;STRYCHNIDIN-10-ONE,2,3-DIMETHOXY;Paper Chemicals Wet Strength Agent 12.5%;Strychnidin-10-one, 2,3-dimethoxy-, tetrahydrate;Wet Strength Agent - Polyamide Epichlorohydrin Resin/Pae 12.5%
- CBNumber
- CB4208446
- Molecular Formula
- C23H26N2O4
- Formula Weight
- 394.46
- MOL File
- 5892-11-5.mol
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BRUCINE Property
- Melting point:
- 175-178 °C (dec.)(lit.)
- optical activity
- [α]20/D 67°, c = 1.3 in ethanol
- Water Solubility
- Soluble in methanol. Partially soluble Miscible with water.
- CAS DataBase Reference
- 5892-11-5(CAS DataBase Reference)
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Safety
- Hazard Codes
- T+
- Risk Statements
- 26/28-52/53-36/37/38-26/27/28
- Safety Statements
- 13-45-61-36/37-28
- RIDADR
- UN 1570 6.1/PG 1
- WGK Germany
- 3
- RTECS
- EH8925000
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- I
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 367869
- Product name
- Brucine hydrate
- Purity
- technical grade
- Packaging
- 100g
- Price
- $316.2
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A16251
- Product name
- Brucine dihydrate, 98%
- Packaging
- 10g
- Price
- $37.65
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A16251
- Product name
- Brucine dihydrate, 98%
- Packaging
- 50g
- Price
- $103.65
- Updated
- 2024/03/01
Biosynth Carbosynth
- Product number
- FB31436
- Product name
- Brucine dihydrate
- Packaging
- 100g
- Price
- $800
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB31436
- Product name
- Brucine dihydrate
- Packaging
- 250g
- Price
- $1000
- Updated
- 2021/12/16
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BRUCINE Chemical Properties,Usage,Production
Uses
Resolving agentBrucine dihydrate is used as a resolving agent for chiral acids.
Purification Methods
Crystallise brucine once from water or aqueous Me2CO (as the tetrahydrate), then suspend it in CHCl3 and shake with anhydrous Na2SO4 (to dehydrate the brucine, which then dissolves). Precipitate it by pouring the solution into a large bulk of dry pet ether (b 40-60o), filter and heat to 120o in a high vacuum [Turner J Chem Soc 842 1951]. The tetrahydrate crystallises from a mixture of EtOH and H2O as colourless elongated needles [Eeles Acta Cryst 6 809 1953, Beilstein 27 III/IV 7875.] VERY POISONOUS
BRUCINE Preparation Products And Raw materials
Raw materials
Preparation Products
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