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Acetylthiomethyl-diphenylphosphine borane complex

Product Name
Acetylthiomethyl-diphenylphosphine borane complex
CAS No.
446822-71-5
Chemical Name
Acetylthiomethyl-diphenylphosphine borane complex
Synonyms
Acetylthiomethyl-diphenylphosphine borane complex;Acetylthiomethyl-diphenylphosphine borane complex >=98.0%
CBNumber
CB42090207
Molecular Formula
C15H18BOPS
Formula Weight
288.157
MOL File
446822-71-5.mol
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Acetylthiomethyl-diphenylphosphine borane complex Property

Melting point:
52-55 °C
storage temp. 
2-8°C
form 
solid
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
670359
Product name
Acetylthiomethyl-diphenylphosphine borane complex
Purity
≥98.0%
Packaging
250mg
Price
$180
Updated
2022/05/15
Sigma-Aldrich
Product number
670359
Product name
Acetylthiomethyl-diphenylphosphine borane complex
Purity
≥98.0%
Packaging
1g
Price
$716
Updated
2022/05/15
American Custom Chemicals Corporation
Product number
BOR0003689
Product name
ACETYLTHIOMETHYL-DIPHENYLPHOSPHINE BORANE COMPLEX
Purity
95.00%
Packaging
5MG
Price
$496.09
Updated
2021/12/16
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Acetylthiomethyl-diphenylphosphine borane complex Chemical Properties,Usage,Production

Uses

  • Traceless Staudinger ligation reagent with borane protecting group.
  • The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine.
  • After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond.
  • Used in the synthesis of cyclic peptides.

Uses

Traceless Staudinger ligation reagent with borane protecting group. The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine. After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond. Used in the synthesis of cyclic peptides.

reaction suitability

reaction type: click chemistry
reagent type: ligand
reaction type: Staudinger Reaction

Acetylthiomethyl-diphenylphosphine borane complex Preparation Products And Raw materials

Raw materials

Preparation Products

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Acetylthiomethyl-diphenylphosphine borane complex Suppliers

Riedel-de Haen AG
Tel
--
Fax
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Country
United States
ProdList
6773
Advantage
87

446822-71-5, Acetylthiomethyl-diphenylphosphine borane complexRelated Search:


  • Acetylthiomethyl-diphenylphosphine borane complex
  • Acetylthiomethyl-diphenylphosphine borane complex >=98.0%
  • 446822-71-5
  • C15H18BOPS
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Chemical Ligation
  • Other LigandsSpecialty Synthesis
  • Staudinger Ligation