(3S)-3β-Methyl-4α-[(E)-2-[(2S)-6β-methyl-2α-piperidinyl]vinyl]-1,3,3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-dodecahydronaphtho[2,3-c]furan-1-one

Product Name
(3S)-3β-Methyl-4α-[(E)-2-[(2S)-6β-methyl-2α-piperidinyl]vinyl]-1,3,3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-dodecahydronaphtho[2,3-c]furan-1-one
CAS No.
518-99-0
Chemical Name
(3S)-3β-Methyl-4α-[(E)-2-[(2S)-6β-methyl-2α-piperidinyl]vinyl]-1,3,3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-dodecahydronaphtho[2,3-c]furan-1-one
Synonyms
Himbeline;(+)-Himbeline;Naphtho[2,3-c]furan-1(3H)-one, decahydro-3-methyl-4-[(1E)-2-[(2R,6S)-6-methyl-2-piperidinyl]ethenyl]-, (3S,3aR,4R,4aS,8aR,9aS)-;(3S)-4α-[(E)-2-[(2S,6R)-6-Methyl-2-piperidinyl]vinyl]-3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-decahydro-3-methylnaphtho[2,3-c]furan-1(3H)-one;(3S)-3β-Methyl-4α-[(E)-2-[(2S)-6β-methyl-2α-piperidinyl]vinyl]-1,3,3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-dodecahydronaphtho[2,3-c]furan-1-one
CBNumber
CB42152844
Molecular Formula
C21H33NO2
Formula Weight
331.49
MOL File
518-99-0.mol
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
H456353
Product name
Himbeline
Packaging
0.5mg
Price
$165
Updated
2021/12/16
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(3S)-3β-Methyl-4α-[(E)-2-[(2S)-6β-methyl-2α-piperidinyl]vinyl]-1,3,3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-dodecahydronaphtho[2,3-c]furan-1-one Chemical Properties,Usage,Production

Uses

Himbeline is used in the enantioselective total synthesis of (+)-himbacine and (+)-himbeline from (S)-2-methylpiperidine L-tartrate.

(3S)-3β-Methyl-4α-[(E)-2-[(2S)-6β-methyl-2α-piperidinyl]vinyl]-1,3,3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-dodecahydronaphtho[2,3-c]furan-1-one Preparation Products And Raw materials

Raw materials

Preparation Products

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(3S)-3β-Methyl-4α-[(E)-2-[(2S)-6β-methyl-2α-piperidinyl]vinyl]-1,3,3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-dodecahydronaphtho[2,3-c]furan-1-one Suppliers

518-99-0, (3S)-3β-Methyl-4α-[(E)-2-[(2S)-6β-methyl-2α-piperidinyl]vinyl]-1,3,3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-dodecahydronaphtho[2,3-c]furan-1-oneRelated Search:


  • (+)-Himbeline
  • (3S)-3β-Methyl-4α-[(E)-2-[(2S)-6β-methyl-2α-piperidinyl]vinyl]-1,3,3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-dodecahydronaphtho[2,3-c]furan-1-one
  • (3S)-4α-[(E)-2-[(2S,6R)-6-Methyl-2-piperidinyl]vinyl]-3aβ,4,4aα,5,6,7,8,8aβ,9,9aβ-decahydro-3-methylnaphtho[2,3-c]furan-1(3H)-one
  • Himbeline
  • Naphtho[2,3-c]furan-1(3H)-one, decahydro-3-methyl-4-[(1E)-2-[(2R,6S)-6-methyl-2-piperidinyl]ethenyl]-, (3S,3aR,4R,4aS,8aR,9aS)-
  • 518-99-0