ChemicalBook > CAS DataBase List > SALCOMINE

SALCOMINE

Product Name
SALCOMINE
CAS No.
14167-18-1
Chemical Name
SALCOMINE
Synonyms
o’)-o;SALEN-CO;Salcomin;Nsc32965;(sp-4-2)-;SALCOMINE;N,N&priMe;Co(salen);CO(SALEN)2;salcomin[qr]
CBNumber
CB4223164
Molecular Formula
C16H14CoN2O2
Formula Weight
325.23
MOL File
14167-18-1.mol
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SALCOMINE Property

Melting point:
>300 °C
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
Orange to Amber to Dark red
Water Solubility 
Insoluble in water. Soluble in benzene, chloroform, and pyridine.
Stability:
Stable. Incompatible with strong acids, strong oxidizing agents.
EPA Substance Registry System
Salcomine (14167-18-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
GG0590000
F 
10
TSCA 
Yes
HS Code 
29349990
Hazardous Substances Data
14167-18-1(Hazardous Substances Data)
Toxicity
mouse,LCLo,inhalation,390mg/m3/5.5H (390mg/m3),LUNGS, THORAX, OR RESPIRATION: STRUCTURAL OR FUNCTIONAL CHANGE IN TRACHEA OR BRONCHILUNGS, THORAX, OR RESPIRATION: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA,Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974,
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
274712
Product name
N,N′-Bis(salicylidene)ethylenediaminocobalt(II)
Purity
99%
Packaging
1g
Price
$117
Updated
2024/03/01
Sigma-Aldrich
Product number
274712
Product name
N,N′-Bis(salicylidene)ethylenediaminocobalt(II)
Purity
99%
Packaging
5g
Price
$404
Updated
2024/03/01
TCI Chemical
Product number
S0318
Product name
Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)]
Purity
>95.0%(T)
Packaging
25g
Price
$99
Updated
2024/03/01
TCI Chemical
Product number
S0318
Product name
Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)]
Purity
>95.0%(T)
Packaging
100g
Price
$250
Updated
2024/03/01
Alfa Aesar
Product number
043174
Product name
N,N'-Bis(salicylidene)ethylenediaminecobalt(II), 96%
Packaging
1g
Price
$17.65
Updated
2024/03/01
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SALCOMINE Chemical Properties,Usage,Production

Chemical Properties

black crystalline powder

Uses

Salcomine catalyzes the oxidation of 2,6-disubstituted phenols by dioxygen. Experimental inhibitor of human cytμloviris proteinase activity. Metal complex dyes used as redox catalysts.

General Description

A solid complex between the cobalt(II) ion and the condensation product of salicylaldehyde and ethylenediamine. Such condensation products are called "Schiff's bases." Complexation with cobalt nullifies their basic properties. Used as a catalyst for various oxidation reactions in which SALCOMINE behaves as an oxygen carrier.

Reactivity Profile

SALCOMINE may increase the rate of oxidation reactions such as the conversion of amines to nitro compounds by peroxides or hydroperoxides.

Purification Methods

The powder should have an oxygen capacity of 4.7-4.8% as measured by the increase in weight under O2 at 100 pounds pressure at ca 20o. The O2 is expelled on heating the material to 65o. It crystallises from pyridine, CHCl3 or *C6H6, and the solvent may be removed by heating at 120o in a vacuum. However, this heating may mean reduced O2 capacity. In the dry state it absorbs O2, turning from a maroon colour to black. [Diehl & Hack Inorg Synth III 196 1950.]

SALCOMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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SALCOMINE Suppliers

China 95 Europe 3 France 1 Germany 5 India 3 Japan 2 South Korea 1 Switzerland 1 United Kingdom 3 United States 16 Global 130
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View Lastest Price from SALCOMINE manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
SALCOMINE 14167-18-1
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500000kg
Release date
2024-10-29
Career Henan Chemical Co
Product
SALCOMINE 14167-18-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-07-03

14167-18-1, SALCOMINERelated Search:

Ethylenediamine Salicylaldehyde SALCOMINE SALCOMINE HYDRATE

  • N,N'-DISALICYLALETHYLENEDIAMINE COBALT(II)
  • N,N'-ETHYLENEBIS(SALICYLIDENEIMINATO)COBALT(II)
  • SALCOMINE
  • SALEN-CO
  • ((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n-cobal
  • ((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-cobal
  • (N,N'-Ethylenebis(salicylaldehyde iminato))cobalt(II)
  • (N,N'-Ethylenebis(salicylideniminato))cobalt
  • (sp-4-2)-
  • a13-30876[qr]
  • Bis(salicylaldehyde)ethylenediimine cobalt(ii)
  • bis(salicylaldehyde)ethylenediiminecobalt(ii)
  • Cobalt, ((2,2'-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-N,N',O,O')-
  • Cobalt, ((alpha,alpha'-(ethylenedinitrilo)di-o-cresolato)(2-))-
  • Cobalt, [[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-, (SP-4-2)-
  • Cobalt, N,N'-ethylenebis(salicylideneiminato)-
  • cobalt,((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n
  • cobalt,((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-[qr]
  • cobalt,[[2,2’-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-n,n’,
  • n,n’-bis(salicylidene)ethylenediaminecobalt(ii)salthyd.
  • n,n’-bis(salicylidene)ethylenediamino
  • n,n’-ethylenebis(salicylideneiminato)-cobal
  • N,N'-Ethylenebis(salicylideneiminato)cobalt
  • n,n-ethylenebis(salicylideneiminato)cobaltii[qr]
  • N,N'-Ethylenebis(salicylideniminato)cobalt(II)
  • o,o’)-(sp-4-2)-[qr]
  • o’)-o
  • Salcomin
  • CO(SALEN)2
  • Salcomine: (bis(Salicylaldehyde)ethylenediimine cobalt(II))
  • N,N'-Bis(salicylidene)ethylenediamine cobalt salt
  • Co(SALEN)2, Ethylenebis(salicylimine) cobalt(II) salt, Salcomine, N,Nμ-Disalicylidene-ethylenediamine cobalt(II) salt
  • [2,2'-[Ethane-1,2-diylbis(nitrilomethylidene)]diphenolato]cobalt(II)
  • [Bis(salicylidene)ethylenediaminato]cobalt
  • [Bis(salicylidene)ethylenediamine]cobalt
  • [N,N'-Bis(salicylidene)ethane-1,2-diaminato]cobalt(II)
  • [N,N'-Bis(salicylidene)ethylenediaminato]cobalt
  • [N,N'-Disalicylideneethylenediamine]cobalt
  • N,N-BIS(SALICYLIDENE)ETHYLENE-DIIMINOCOBALT (II)
  • N,N'-BIS(SALICYLIDENE)ETHYLENEDIIMINOCOBALT(II)
  • N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINOCOBALT(II)
  • Ethylenebis(salicylimine) cobalt(II) salt
  • N,N'-Bis(salicylidene)ethylenediaminecobalt(Ⅱ)
  • Salcomine, N,N'-Disalicylidene-ethylenediamine cobalt(II) salt
  • N,N'-Bis(salicyliden)ethylenediaminocobalt (ii)
  • Nsc32965
  • N,N'-Bis(salicylidene)ethylenediiminocobalt(II) N,N'-Disalicylalethylenediamine Cobalt(II) N,N'-Ethylenebis(salicylideneiminato)cobalt(II)
  • SalcoMine&nbsp
  • -Bis(salicylidene)ethylenediaMinocobalt(II)
  • N,N&priMe
  • The twosalicylaldehydeethylenediaMinecobalt
  • Co(salen)
  • <i>N,N'</i>-Bis(salicylidene)ethylenediaminocobalt(II)
  • 2,2'-((1Z,3Z)-2,3-Diaminobuta-1,3-diene-1,4-diyl)diphenol, cobalt salt
  • -Bis(3-aminopropyl)-1,3-propanediamine-d24
  • -Disuccinimidyl Carbonate (Technical Grade)
  • -Bis(3-aminopropyl)-1,3-propanediamine
  • salcomin[qr]