Tri-O-acetyl-D-glucal

Product Name: Tri-O-acetyl-D-glucal
CAS No.: 2873-29-2
Chemical Name: Tri-O-acetyl-D-glucal
Synonyms: (2R,3S,4R)-2-(AcetoxyMethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate;3,4,6-TRI-O-ACETYL-D-GLUCAL;TRIACETYLGLUCAL;ucaL;Tri-O-acetyL;Triacetoglucene;peracetyl-D-gluca;D-GlucalTriacetate;Triacetyl-D-glucal;Triacetyl gluconene
CBNumber: CB4228659
Molecular Formula: C12H16O7
Formula Weight: 272.25
MOL File: 2873-29-2.mol

More

Less

Tri-O-acetyl-D-glucal Property

Melting point:: 53-55 °C(lit.)
Boiling point:: 335.31°C (rough estimate)
Density: 1.2602 (rough estimate)
refractive index: 1.4455 (estimate)
Flash point:: >230 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), Ethanol (Slightly), Methanol (Slightly)
form: Crystalline Powder
color: White to off-white
optical activity: [α]25/D 12°, c = 2 in ethanol
Water Solubility: Soluble in chloroform and ethanol. Insoluble in water.
BRN: 90781
InChI: InChI=1/C12H16O7/c1-7(13)17-6-11-12(19-9(3)15)10(4-5-16-11)18-8(2)14/h4-5,10-12H,6H2,1-3H3/t10-,11-,12+/s3
InChIKey: LLPWGHLVUPBSLP-FHMMHVPQNA-N
SMILES: [C@@H]1(OC(=O)C)[C@@H](COC(=O)C)OC=C[C@H]1OC(=O)C |&1:0,5,14,r|
CAS DataBase Reference: 2873-29-2(CAS DataBase Reference)

More

Less

Safety

Safety Statements: 24/25
WGK Germany: 3
HS Code: 29329995
Storage Class: 11 - Combustible Solids

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: T44407
Product name: Tri-O-acetyl-D-glucal
Purity: 98%
Packaging: 5g
Price: $37.8
Updated: 2025/07/31

Sigma-Aldrich

Product number: T44407
Product name: Tri-O-acetyl-D-glucal
Purity: 98%
Packaging: 25g
Price: $96.2
Updated: 2025/07/31

TCI Chemical

Product number: T1596
Product name: Tri-O-acetyl-D-glucal
Purity: >96.0%(GC)
Packaging: 5g
Price: $38
Updated: 2025/07/31

TCI Chemical

Product number: T1596
Product name: Tri-O-acetyl-D-glucal
Purity: >96.0%(GC)
Packaging: 25g
Price: $112
Updated: 2025/07/31

Sigma-Aldrich

Product number: T44407
Product name: Tri-O-acetyl-D-glucal
Purity: 98%
Packaging: 100g
Price: $283
Updated: 2025/07/31

More

Less

Tri-O-acetyl-D-glucal Chemical Properties,Usage,Production

Chemical Properties

white to off-white crystalline powder

Uses

A D-glucal derivative.

Uses

3,4,6-Tri-O-acetyl-D-glucal acts as a building block for the synthesis of oligosaccharides in both solution and solid-phase. Further, it is used in the preparation of D-arabino-1,5-anhydro-2-deoxy-hex-1-enitol.

Synthesis

In a 500 mL round bottom flask add 10 g glucose, acetic acid 100 mL, acetic anhydride 32.5 mL, p-toluenesulfonic acid 0.5 g, ultrasonic reaction for 10 minutes, the above reaction solution add acetyl bromide 12.5 mL, methanol 9.0 mL, ultrasonic vibration, power 420W (model DST20500) reaction for 1 hour, TLC detection of the reaction is complete, add Dichloromethane was diluted, washed with water and recrystallized with ethanol to obtain 21.9 g of bromoglucose crystals with 96% yield.

In the above bromodextrose add ??-cyclodextrin 44 g, 220 mL of water and 11 g of zinc powder, ultrasonic power 480W, (model DST20500) oscillation reaction for 10 minutes, add ethyl acetate dilution, filtration, filtrate extracted with ethyl acetate for 3 times, combined with the organic phase, add anhydrous sodium sulfate drying, filtration, concentration under reduced pressure, the crude acetylated glucosinolates, and then recrystallized with ethyl acetate and petroleum ether to get acetylated glucose, and then recrystallized with ethanol and petroleum ether to get acetylated glucosinolates. And then recrystallized with ethyl acetate and petroleum ether to get acetylated glucosinolates pure product 13.8 g, the yield is 95%.

Tri-O-acetyl-D-glucal Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

Tri-O-acetyl-D-glucal Suppliers

Austria 1 Belgium 4 Canada 2 China 300 Europe 1 France 1 Germany 10 India 21 Japan 3 Poland 1 Slovakia 1 Sweden 1 Switzerland 7 The Netherlands 1 Ukraine 1 United Kingdom 19 United States 61 Global 435

Nanjing Baifuli Technology Co., Ltd.

Tel: 25-25-58740604 15951658055
Fax: +86-25-58356858
Email: sales@unisyn.cn
Country: China
ProdList: 591
Advantage: 58

Shanghai Boyle Chemical Co., Ltd.

Tel: 021-50182298 021-50180596
Fax: +86-21-57758967
Email: sales@boylechem.com
Country: China
ProdList: 2208
Advantage: 55

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3572
Advantage: 66

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Ark Pharm, Inc.

Tel: 847-367-3680
Fax: 847-367-3681
Email: sales@arkpharminc.com
Country: United States
ProdList: 1670
Advantage: 56

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

More

Less

View Lastest Price from Tri-O-acetyl-D-glucal manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Tri-O-acetyl-D-glucal 2873-29-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 1000kg/month
Release date: 2021-12-16

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Product: Tri-O-acetyl-D-glucal 2873-29-2
Price: US $990.00-800.00/ton
Min. Order: 1ton
Purity: 99%
Supply Ability: 5000
Release date: 2024-08-19

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Tri-O-acetyl-D-glucal 2873-29-2
Price: US $65.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000kg/week
Release date: 2024-06-05

2873-29-2, Tri-O-acetyl-D-glucalRelated Search:

N-ACETYL-L-TYROSINE ETHYL ESTER Acetylacetone Acetylferrocene Acetyl chloride Acetamide HEXA-O-ACETYL-CELLOBIAL Acetyl bromide / 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL 3,4,6-Tri-O-acetyl-D-galactal 3,4,6-Tri-O-benzyl-D-glucal Calcium gluconate Gluconic acid D-Glucal tributyl acetocitrate TRI-O-ACETYL-D-[6-13C]GLUCAL TRI-O-ACETYL-D-[2-13C]GLUCAL 3,4-6TRI-O-ACETYL-L-GLUCAL,TRI-O-ACETYL-L-GLUCAL

1,2-DIDEOXY-3,4,6-TRI-O-ACETYL-D-ARABINO-1-HEXENOPYRANOSE

1,2-DIDEOXY-3,4,6-TRI-O-ACETYL-D-ARABINO-1-HEXENOPYRANOSIDE

1,5-ANHYDRO-2-DEOXY-D-ARABINO-HEX-1-ENITOL 3,4,6-TRI-O-ACETYL ETHER

3,4,6-TRI-O-ACETYL-1,5-ANHYDRO-D-ARABINO-HEX-1-ENITOL

3,4,6-TRI-O-ACETYL-1,5-ANHYDRO-2-DEOXY-D-ARABINO-HEX-1-ENITOL

3,4,6-TRI-O-ACETYL-D-GLUCAL

(-)-TRI-O-ACETYL-D-GLUCAL

TRI-O-ACETYL-D-GLUCAL

TRIACETYLGLUCAL

Tri-O-acetyl-D-glucal,1,2-Dideoxy-3,4,6-tri-O-acetyl-D-arabino-1-hexenopyranose, 3,4,6-Tri-O-acetyl-1,5-anhydro-2-deoxy-D-arabino-hex-1-enitol

Tri-O-acetyl-D-gluca

1,5-anhydro-2-deoxy-d-arabino-hex-1-enitotriacetate

Tri-O-acetyl-D-glucal, 99% 25GR

3,4,6-triacetyl-D-galactal

(-)-TRI-O-ACETYL-D-GLUCAL FOR SYNTHESIS

(2R,3S,4R)-2-(AcetoxyMethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate

3,4,6-tri-O-acetyl-D-gluca

Tri-O-acetyl-D-glucal, 97+%

3,4,6-Tri-O-acetyl-D-glucal, alternatively Triacetylglucal

[(2R,3S,4R)-3,4-diacetyloxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate

(-)-Tri-O-acetyl-D-glucal≥ 99% (Assay)

3,4,6-Tri-O-acetyl-1,2-dideoxy-D-arabino-hex-1-enopyranose

[(2R,3S,4R)-3,4-bis(acetyloxy)-3,4-dihydro-2H-pyran-2-yl]methyl acetate

1,5-anhydro-2-deoxy-D-arabino-hex-1-enitol triacetate

3,4,6-tri-0-Acetyl-D-Glucal

1,5-ANHYDRO-2-DEOXY-D-ARABINO-1-HEXENOL TRIACETATE

D-GlucalTriacetate

D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, triacetate

3,4,6-tri-O-acetylglucal

Triacetyl-D-glucal

3,4,6-Tris-O-acetyl-D-glucal

3,4,6-Triacetyl-D-glucal, 97%

1,2-Dideoxy-D-arabino-1-hexenopyranose triacetate

3-O,4-O,6-O-Triacetyl-1,2-dideoxy-1,2-didehydro-D-arabino-hexopyranose

Tri-O-acetyl-D-glucal,99%

Gastrodin Impurity 8

1,2-Dideoxy-3,4,6-tri-O-acetyl-D-arabino-1-hexenopyranose, 3,4,6-Tri-O-acetyl-1,5-anhydro-2-deoxy-D-arabino-hex-1-enitol

(3,4-Diacetyloxy-3,4-dihydro-2H-pyran-2-yl)methyl acetate

[(2R,3S,4R)-4-Acetyloxy-2-(acetyloxymethyl)-3,4-dihydro-2H-pyran-3-yl] acetate

[3,4-BIS(ACETYLOXY)-3,4-DIHYDRO-2H-PYRAN-2-YL]METHYL ACETATE

1,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol3,4,6-Tri-O-acetyl

Tri-O-acetyL

ucaL

acetic acid [(2R,3S,4R)-3,4-diacetyloxy-3,4-dihydro-2H-pyran-2-yl]methyl ester

3,4,6-o-triacetyl-d-glucone

D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, 3,4,6-triacetate

Tri-O-acetyl-D-glucal USP/EP/BP

Triacetoglucene

3,4,6-Triacetylglucal

peracetyl-D-gluca

Triacetyl gluconene

Acetylated Glucosene

Tri-<i>O</i>-acetyl-<sc>D</sc>-glucal

2873-29-2

C12H16O7

Monosaccharides

Specialty Synthesis

O-Substituted Sugars