ChemicalBook > CAS DataBase List > PROPENYL GUAETHOL

PROPENYL GUAETHOL

Product Name
PROPENYL GUAETHOL
CAS No.
94-86-0
Chemical Name
PROPENYL GUAETHOL
Synonyms
VANITROPE;6-ETHOXY-M-ANOL;2-ETHOXY-5-PROP-1-ENYLPHENOL;1-ethoxy-2-hydroxy-4-propenylbenzene;VANIBON;FEMA 2922;Rich vanillin;isosafroeugenol;PROPENYL GUAETHOL;5-PROPENYLGUAETHOL
CBNumber
CB4239477
Molecular Formula
C11H14O2
Formula Weight
178.23
MOL File
94-86-0.mol
More
Less

PROPENYL GUAETHOL Property

Melting point:
86-88 °C(lit.)
Boiling point:
116°C/2mmHg(lit.)
Density 
1.0196 (rough estimate)
refractive index 
1.5670 (estimate)
FEMA 
2922 | PROPENYLGUAETHOL
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
solubility 
10% soluble in alcohol, 4 % soluble in Propylene glycol, 4 % soluble in Polysorbate 80, 20% soluble in Benzylalcohol, soluble in most perfume and flavor oils.
form 
powder to crystal
pka
10.02±0.10(Predicted)
color 
White to Almost white
Odor
at 10.00 % in dipropylene glycol. sweet vanilla woody tobacco spicy phenolic powdery
Odor Type
vanilla
JECFA Number
1264
InChIKey
RADIRXJQODWKGQ-HWKANZROSA-N
LogP
2.90
CAS DataBase Reference
94-86-0(CAS DataBase Reference)
EPA Substance Registry System
Phenol, 2-ethoxy-5-(1-propenyl)- (94-86-0)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
2
RTECS 
SL3850000
HS Code 
2909500090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W292206
Product name
Propenyl guaethol
Purity
≥99%, FCC, FG
Packaging
sample-k
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W292206
Product name
Propenyl guaethol
Purity
≥99%, FCC, FG
Packaging
100g
Price
$85.3
Updated
2024/03/01
Sigma-Aldrich
Product number
W292206
Product name
Propenyl guaethol
Purity
≥99%, FCC, FG
Packaging
1kg
Price
$310
Updated
2024/03/01
Sigma-Aldrich
Product number
W292206
Product name
Propenyl guaethol
Purity
≥99%, FCC, FG
Packaging
5kg
Price
$1270
Updated
2024/03/01
Sigma-Aldrich
Product number
227544
Product name
trans-2-Ethoxy-5-(1-propenyl)phenol
Purity
97%
Packaging
50g
Price
$101.6
Updated
2024/03/01
More
Less

PROPENYL GUAETHOL Chemical Properties,Usage,Production

Chemical Properties

Free-flowing, white powder; odor and taste similar to vanilla, but much more powerful.Very soluble in fats, edible solvents, and essential oils; very slightly soluble in water.

Chemical Properties

PROPENYL GUAETHOL exists in (Z)- (mp 35–36°C), [876306-58-0], and in (E)- (mp 86°C), [63477-41-8] forms. The (E)-isomer has a sweet vanilla-like odor. Propenylguethol can be prepared from isosafrole by reaction with methylmagnesium chloride or by ethylation of isoeugenol followed by selective demethylation with alkali .

Chemical Properties

Propenylguaethol has a vanilla-like odor and flavor.

Uses

trans-2-Ethoxy-5-(1-propenyl)phenol was used in the synthesis of 2S-((E)-2-ethoxy-5-propenyl-phenoxy)-1-(3,4,5-trimethoxy-phenyl)-propane-1-one.

Uses

Artificial vanilla flavoring, flavor enhancer.

Definition

ChEBI: 2-Ethoxy-5-(1-propenyl)phenol is an aromatic ether.

Preparation

By alkaline hydrolysis of 1-ethoxy-2-methoxy-4-propenyl benzene in ethanol or methanol solution at 150 to 190°C under pressure; or in ethylene glycol solution at the same temperature under atmospheric pressure; by saponification and contemporary transposition of the double bond starting from 1-ethoxy-2-methoxy-4-allyl benzene.

Aroma threshold values

Detection: 400 ppb. Aroma characteristics at 1.0%: vanilla, sweet, spicy, slightly phenolic with a heliotropine- like creaminess.

Taste threshold values

Taste characteristics at 25 ppm: vanilla, spicy, sweet nutty, anisic with a biting creaminess.

Synthesis Reference(s)

Synthetic Communications, 21, p. 379, 1991 DOI: 10.1080/00397919108016759

Biochem/physiol Actions

Taste at 25 ppm

PROPENYL GUAETHOL Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

PROPENYL GUAETHOL Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
Midori Kagaku
Tel
--
Fax
--
Country
Japan
ProdList
104
Advantage
58
Midori Kagaku co.,ltd.
Tel
--
Fax
--
Email
midori@midori-kagaku.com
Country
Japan
ProdList
236
Advantage
64
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
More
Less

View Lastest Price from PROPENYL GUAETHOL manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
PROPENYL GUAETHOL 94-86-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-06
Henan Bao Enluo International TradeCo.,LTD
Product
PROPENYL GUAETHOL 94-86-0
Price
US $50.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
10000MT
Release date
2023-08-08
Shaanxi Dideu Medichem Co. Ltd
Product
2-Ethoxy-5-(1-propenyl)phenol 94-86-0
Price
US $0.00-0.00/Kg
Min. Order
100G
Purity
99.0%+
Supply Ability
100 tons
Release date
2020-01-17

94-86-0, PROPENYL GUAETHOLRelated Search:


  • VANITROPE
  • TRANS-2-ETHOXY-5-(1-PROPENYL)PHENOL
  • PROPENYL GUAETHOL
  • 2-ETHOXY-5-(1-PROPENYL)PHENOL
  • 2-ETHOXY-5-PROP-1-ENYLPHENOL
  • 2-ETHOXY-5-PROPENYLPHENOL
  • 5-PROPENYLGUAETHOL
  • 6-ETHOXY-M-ANOL
  • FEMA 2922
  • 1-ethoxy-2-hydroxy-4-propenylbenzene
  • 2-ethoxy-5-(1-propenyl)-pheno
  • 2-ethoxy-5-propenyl-pheno
  • hydroxymethylanethol
  • isosafroeugenol
  • PROPENYL GUAETHOL 99+% FCC
  • 5-Propenyl-2-ethoxyphenol
  • Phenol, 2-ethoxy-5-(1-propenyl)-
  • VANIBON
  • 1-ETHOXY-2-HYDROXY-4-PROP-1-ENYLBENZENE
  • 1-Ethoxy-2-Hydroxy-4-(1-Propenyl)Benzene
  • trans-2-Ethoxy-5-(1-
  • Propenylguaethol 1-Ethoxy-2-hydroxy-4-(1-propenyl)benzene
  • Vanitrope Propenyl guaethol
  • trans-2-Ethoxy-5-(1-prope
  • 2-Ethoxy-5-(prop-1-en-1-yl)phenol
  • (E)-2-Ethoxy-5-(prop-1-en-1-yl)phenol
  • 2-Ethoxy-5-(1-propenyl)phenol&gt
  • Phenol, 2-ethoxy-5-(1-propen-1-yl)-
  • 2-Ethoxy-5-(1-propenyl)phenol USP/EP/BP
  • Rich vanillin
  • PROPENYL GUAETHOL 929
  • 2-Ethoxy-5-[(1E)-1-propen-1-yl]phenol
  • 94-86-0
  • 94-84-0
  • C2H5OC6H3CHCHCH3OH
  • Building Blocks
  • Alkenes
  • Acyclic
  • Organic Building Blocks
  • Alphabetical Listings
  • Flavors and Fragrances
  • O-P