ChemicalBook > CAS DataBase List > MN(TMHD)3
MN(TMHD)3
- Product Name
- MN(TMHD)3
- CAS No.
- 14324-99-3
- Chemical Name
- MN(TMHD)3
- Synonyms
- Mn(dpm)3;Tris(dipivaloylmethanato)manganese;Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese;MN(TMHD)3;anese(III);-3,5-heptanedionato)mang;Tris(2,2,6,6-tetramethyL;Shenvi Hydrogenation Catalyst;-3,5-heptanedionato)manganese(III);Tris(tetramethylheptanedionato)manganese
- CBNumber
- CB4241944
- Molecular Formula
- C33H57MnO6
- Formula Weight
- 604.74
- MOL File
- 14324-99-3.mol
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MN(TMHD)3 Property
- Melting point:
- 165°C
- Boiling point:
- 255°C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- crystal
- color
- black
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- InChIKey
- ORZPLLPBZHORSD-LWTKGLMZSA-K
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39-36/37
- WGK Germany
- 3
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 700223
- Product name
- Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)
- Purity
- 97%
- Packaging
- 1g
- Price
- $58.1
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 25-5000
- Product name
- Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3]
- Packaging
- 1g
- Price
- $55
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 25-5000
- Product name
- Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3]
- Packaging
- 5g
- Price
- $218
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 25-5000
- Product name
- Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3]
- Packaging
- 25g
- Price
- $869
- Updated
- 2024/03/01
TRC
- Product number
- T897683
- Product name
- Tris(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Manganese(Iii)
- Packaging
- 100mg
- Price
- $175
- Updated
- 2021/12/16
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MN(TMHD)3 Chemical Properties,Usage,Production
Uses
Catalyst for:
- Intramolecular Diels-Alder reactions
- Single electron donor for excess electron transfer studies in DNA
- Enantioselective synthesis
- Borylation reactions
- Hydrohydrazination and hydroazidation
- Oxidative carbonylation of phenol
reaction suitability
core: manganese
reagent type: catalyst
MN(TMHD)3 Preparation Products And Raw materials
Raw materials
Preparation Products
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MN(TMHD)3 Suppliers
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ND(TMHD)3
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MN(TMHD)3
MANGANESE(II) ACETYLACETONATE
Manganic acetylacetonate