METHYL 2-FORMYL-3-OXO-PROPIONATE

Product Name: METHYL 2-FORMYL-3-OXO-PROPIONATE
CAS No.: 50427-65-1
Chemical Name: METHYL 2-FORMYL-3-OXO-PROPIONATE
Synonyms: Methyl Diformylacetate;Regadenoson Impurity 30;Methyl 2-formyl-3-oxo-propiote;Methyl 2-forMyl-3-oxopropanoate;METHYL 2-FORMYL-3-OXO-PROPIONATE;Propanoic acid, 2-formyl-3-oxo-, methyl ester;2-formyl-3-oxo-Propanoic acid methyl ester (9CI ACI);Propanoic acid, 2-formyl-3-oxo-, methyl ester (9CI, ACI)
CBNumber: CB42458959
Molecular Formula: C5H6O4
Formula Weight: 130.1
MOL File: 50427-65-1.mol

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METHYL 2-FORMYL-3-OXO-PROPIONATE Property

Boiling point:: 167.0±35.0 °C(Predicted)
Density: 1.187±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
solubility: slightly sol water; sol aqueous alkali and diethyl ether
pka: 0.54±0.10(Predicted)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M328320
Product name: methyl2-formyl-3-oxopropanoate
Packaging: 10mg
Price: $45
Updated: 2021/12/16

TRC

Product number: M328320
Product name: methyl2-formyl-3-oxopropanoate
Packaging: 50mg
Price: $155
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0310266
Product name: METHYL DIFORMYLACETATE
Purity: 95.00%
Packaging: 5MG
Price: $503.54
Updated: 2021/12/16

J&W Pharmlab

Product number: 05R0326
Product name: Methyl2-formyl-3-oxo-propionate
Purity: 96%
Packaging: 500mg
Price: $199
Updated: 2021/12/16

Crysdot

Product number: CD13012173
Product name: Methyl2-formyl-3-oxopropanoate
Purity: 95+%
Packaging: 1g
Price: $402
Updated: 2021/12/16

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METHYL 2-FORMYL-3-OXO-PROPIONATE Chemical Properties,Usage,Production

Uses

Methyl 2-formyl-3-oxo-propanoate is used for [2 + 2] cycloaddition (de Mayo reaction); [4 + 2]cycloaddition (hetero-Diels-Alder reaction with inverse electron demand); transformation to enamino aldehydes and their photochemical and thermal cycloadditions; Wittig reaction.

Preparation

Methyl 2-formyl-3-oxo-propanoate is prepared by Panizzi's formylation procedure of commercially available methyl 3,3- dimethoxypropanoate with methyl formate, by diformylation of potassium monomethyl malonate with dimethyl formamide and phosphorus oxychloride followed by decarboxylation, and by ozonolysis of dimethyl 2,5-cyclohexadiene-1,4-dicarboxylate.

storage

Methyl 2-formyl-3-oxo-propanoate is stable for at least 6 months if stored at -20 °C; it is a highly acidic compound. Use in a fume hood.

Purification Methods

Fractional vacuum distillation.

METHYL 2-FORMYL-3-OXO-PROPIONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 2-FORMYL-3-OXO-PROPIONATE Suppliers

China 20 India 1 Global 21

Nanjing Chemlin Chemical Co., Ltd

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S.Z. PhyStandard Bio-Tech. Co., Ltd.

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JW & Y Pharmlab Co., Ltd.

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Shanghai zhigan biotechnology co., LTD

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Career Henan Chemica Co

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50427-65-1, METHYL 2-FORMYL-3-OXO-PROPIONATERelated Search:

Triethyl methanetricarboxylate Dehydroacetic acid BENZOYLMALONIC ACID DIETHYL ESTER Ethyl diacetoacetate Methyl diacetoacetate Diethyl acetylmalonate RK-682 TRIETHYL METHANETRICARBOXYLATE, SODIUM DERIVATIVE 2-BENZOYLACETOACETIC ACID ETHYL ESTER METHYL 2-FORMYL-3-OXO-PROPIONATE 3-METHOXYCARBONYL-2,4-DIOXOPIPERIDINE-NA-SALT 2-(2,4-DICHLORO-5-FLUORO-BENZOYL)-MALONIC ACID DIETHYL ESTER 3-OXO-2-(THIOPHENE-2-CARBONYL)-BUTYRIC ACID ETHYL ESTER DIETHYL ISOBUTYROYLMALONATE diethyl (3,4,5-trimethoxybenzoyl)malonate ETHYL 2-[2-(ACETYLAMINO)BENZOYL]-3-OXOBUTANOATE AURORA KA-824 AKOS MSC-0278

Methyl 2-forMyl-3-oxopropanoate

METHYL 2-FORMYL-3-OXO-PROPIONATE

Methyl 2-formyl-3-oxo-propiote

Methyl Diformylacetate

Propanoic acid, 2-formyl-3-oxo-, methyl ester

Propanoic acid, 2-formyl-3-oxo-, methyl ester (9CI, ACI)

2-formyl-3-oxo-Propanoic acid methyl ester (9CI ACI)

Regadenoson Impurity 30

50427-65-1