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ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE

Product Name
ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE
CAS No.
21190-89-6
Chemical Name
ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE
Synonyms
ethyl 6-chloropyridine-2-carboxylate;6-Chloropyridin-2-carboxylic acid ethyl ester;6-Chloropyridine-2-carboxylic acid ethyl ester;6-chloro-2-Pyridinecarboxylic acid ethyl ester;2-Pyridinecarboxylic acid, 6-chloro-, ethyl ester;6-chloro-2-Pyridinecarboxylic acid ethyl ester (9CI ACI);2-Pyridinecarboxylic acid, 6-chloro-, ethyl ester (9CI, ACI)
CBNumber
CB42460981
Molecular Formula
C8H8ClNO2
Formula Weight
185.61
MOL File
21190-89-6.mol
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ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE Property

Boiling point:
289℃
Density 
1.245
Flash point:
129℃
storage temp. 
Store at room temperature
form 
Crystalline
pka
-0.89±0.10(Predicted)
color 
Pale yellow
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
E903765
Product name
Ethyl6-Chloropicolinate
Packaging
100mg
Price
$75
Updated
2021/12/16
Apolloscientific
Product number
OR901965
Product name
Ethyl6-chloropicolinate
Purity
97%
Packaging
25g
Price
$399
Updated
2021/12/16
Matrix Scientific
Product number
119585
Product name
Ethyl 6-chloropicolinate
Purity
95+%
Packaging
25g
Price
$472
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0360259
Product name
ETHYL-6-CHLOROPICOLINATE
Purity
95.00%
Packaging
5MG
Price
$502.67
Updated
2021/12/16
AK Scientific
Product number
W4418
Product name
Ethyl6-chloropicolinate
Packaging
100g
Price
$711
Updated
2021/12/16
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ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE Chemical Properties,Usage,Production

Synthesis

4684-94-0

64-17-5

21190-89-6

Step D: Preparation of ethyl 6-chloro-2-pyridinecarboxylate: 6-chloro-2-pyridinecarboxylic acid (23.5 g, 149 mmol), anhydrous ethanol (100 mL), and toluene (400 mL) were added to a round-bottomed flask equipped with a condenser. Concentrated sulfuric acid (4 mL) was slowly added to the reaction system, followed by heating the mixture to reflux and maintaining the reaction for 3 hours. Upon completion of the reaction, the mixture was cooled to room temperature. The solvent was removed by distillation under reduced pressure and the resulting oily product was dissolved in ethyl acetate (200 mL), washed with 10% aqueous potassium carbonate and dried over anhydrous sodium sulfate. Finally, the dried organic phase was concentrated under reduced pressure to afford ethyl 6-chloro-2-pyridinecarboxylate (26 g, 94% yield).

References

[1] Patent: WO2012/82689, 2012, A1. Location in patent: Page/Page column 56
[2] European Journal of Organic Chemistry, 2014, vol. 2014, # 28, p. 6295 - 6302
[3] Organic Letters, 2014, vol. 16, # 15, p. 3860 - 3863

ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE Suppliers

China 94 India 2 United States 8 Global 104
A.J Chemicals
Tel
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Fax
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Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
CHEMSWORTH
Tel
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Fax
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Email
info@chemsworth.com
Country
India
ProdList
6700
Advantage
30
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View Lastest Price from ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE 21190-89-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-05-29
Henan Fengda Chemical Co., Ltd
Product
ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE 21190-89-6
Price
US $5.00-0.10/KG
Min. Order
1KG
Purity
98%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08
Career Henan Chemical Co
Product
ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE 21190-89-6
Price
US $2.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
ask
Release date
2020-01-08

21190-89-6, ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATERelated Search:

Ethyl 6-chloro-4-methylpyridine-2-carboxylate RARECHEM AL BI 1211 ETHYL 6-CHLORO-2-PYRIDINECARBOXYLATE ETHYL 3,5,6-TRICHLORO-4-[(4-FLUOROPHENYL)AMINO]PYRIDINE-2-CARBOXYLATE PENTYL 4-AMINO-3,5,6-TRICHLOROPYRIDINE-2-CARBOXYLATE Ethyl 3-bromo-6-chloropyridine-2-carboxylate ISOBUTYL 4-AMINO-3,5,6-TRICHLOROPYRIDINE-2-CARBOXYLATE ETHYL 3,4,5,6-TETRACHLOROPYRIDINE-2-CARBOXYLATE 2-Pyridinecarboxylic acid, 4-amino-3,5,6-trichloro-, isooctyl ester

  • 6-Chloropyridine-2-carboxylic acid ethyl ester
  • ethyl 6-chloropyridine-2-carboxylate
  • 2-Pyridinecarboxylic acid, 6-chloro-, ethyl ester
  • 2-Pyridinecarboxylic acid, 6-chloro-, ethyl ester (9CI, ACI)
  • 6-chloro-2-Pyridinecarboxylic acid ethyl ester (9CI ACI)
  • 6-Chloropyridin-2-carboxylic acid ethyl ester
  • 6-chloro-2-Pyridinecarboxylic acid ethyl ester
  • 21190-89-6