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4-(Morpholinomethyl)phenylboronic acid

Product Name
4-(Morpholinomethyl)phenylboronic acid
CAS No.
279262-23-6
Chemical Name
4-(Morpholinomethyl)phenylboronic acid
Synonyms
inomethyL;4-(MorphoL;4-(Morpholinomethyl)phenylboronic acid;4-(Morpholinylmethyl)phenylboronic acid;4-(Morpholinomethyl)benzeneboronic Acid;3)4-(MORPHOLINOMETHYL)PHENYLBORONIC ACID;4-(morpholin-4-ylmethyl)phenyl]boronicaci;[4-(morpholin-4-ylmethyl)phenyl]boronic acid;[4-(Morpholinomethyl)phenyl]boronic acid 98%;B-[4-(4-morpholinylmethyl)phenyl]Boronic acid
CBNumber
CB42470843
Molecular Formula
C11H16BNO3
Formula Weight
221.06
MOL File
279262-23-6.mol
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4-(Morpholinomethyl)phenylboronic acid Property

Melting point:
85 °C
Boiling point:
382.3±52.0 °C(Predicted)
Density 
1.20
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
powder to crystal
pka
8.60±0.16(Predicted)
color 
White to Light yellow to Light orange
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Safety

HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CDS012386
Product name
[4-(morpholinomethyl)phenyl]boronic acid
Purity
AldrichCPR
Packaging
100MG
Price
$259
Updated
2025/07/31
TCI Chemical
Product number
M3128
Product name
4-(Morpholinomethyl)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$188
Updated
2025/07/31
TCI Chemical
Product number
M3128
Product name
4-(Morpholinomethyl)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$578
Updated
2025/07/31
TRC
Product number
M733163
Product name
4-(Morpholinylmethyl)phenylboronicAcid
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
J94870
Product name
4-(Morpholinylmethyl)phenylboronicacid
Packaging
1g
Price
$75
Updated
2021/12/16
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4-(Morpholinomethyl)phenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

4-(Morpholinomethyl)phenylboronic acid is a solid, it is extremely flammable in the presence of oxidizing materials.

Uses

4-(Morpholinomethyl)phenylboronic acid is commonly used in synthetic/analytical chemistry.

Synthesis

110-91-8

68162-47-0

279262-23-6

A) General procedure for the synthesis of 4-morpholinomethylphenylboronic acid: morpholine (0.304 mL) was added to a solution of acetonitrile (10 mL) containing 4-(bromomethyl)phenylboronic acid (500 mg) and potassium carbonate (643 mg). The reaction mixture was stirred at room temperature for 60 hours. Upon completion of the reaction, water was added to the mixture and extracted with ethyl acetate. The organic layer was washed with saturated brine and subsequently dried over anhydrous magnesium sulfate and concentrated under reduced pressure. The resulting solid was washed with diisopropyl ether and ethyl acetate to give the final 4-morpholinomethylphenylboronic acid (449 mg). Mass spectrometry analysis (ESI+): [M + H]+ calculated value 222.1, measured value 222.2.

References

[1] Journal of Organic Chemistry, 2002, vol. 67, # 1, p. 3 - 15
[2] Patent: WO2004/81008, 2004, A1. Location in patent: Page 101-102
[3] Patent: EP2857400, 2015, A1. Location in patent: Paragraph 0843
[4] Patent: WO2017/137535, 2017, A1. Location in patent: Page/Page column 129
[5] Dyes and Pigments, 2018, vol. 149, p. 356 - 362

4-(Morpholinomethyl)phenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(Morpholinomethyl)phenylboronic acid Suppliers

Americas 1 China 101 Europe 1 Germany 2 India 3 Japan 1 United Kingdom 3 United States 14 Global 126
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
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View Lastest Price from 4-(Morpholinomethyl)phenylboronic acid manufacturers

Career Henan Chemical Co
Product
4-(Morpholinomethyl)phenylboronic acid 279262-23-6
Price
US $500.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2018-08-04

279262-23-6, 4-(Morpholinomethyl)phenylboronic acidRelated Search:

3-AMINOMETHYLPHENYLBORONIC ACID, PINACOL ESTER, HCL 4-(Bromomethyl)phenylboronic acid

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