ChemicalBook > CAS DataBase List > 5-bromo-1,7-dimethyl-1H-indazole

5-bromo-1,7-dimethyl-1H-indazole

Product Name
5-bromo-1,7-dimethyl-1H-indazole
CAS No.
1092352-34-5
Chemical Name
5-bromo-1,7-dimethyl-1H-indazole
Synonyms
5-bromo-1,7-dimethyl-1H-indazole;1H-Indazole, 5-bromo-1,7-dimethyl-
CBNumber
CB42500351
Molecular Formula
C9H9BrN2
Formula Weight
225.09
MOL File
1092352-34-5.mol
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5-bromo-1,7-dimethyl-1H-indazole Property

Boiling point:
311.9±22.0 °C(Predicted)
Density 
1.53±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
0.59±0.30(Predicted)
Appearance
Off-white to light yellow Solid
InChI
InChI=1S/C9H9BrN2/c1-6-3-8(10)4-7-5-11-12(2)9(6)7/h3-5H,1-2H3
InChIKey
LKDVGRQGTBBLIS-UHFFFAOYSA-N
SMILES
N1(C)C2=C(C=C(Br)C=C2C)C=N1
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Safety

HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
B691633
Product name
5-Bromo-1,7-dimethyl-1H-indazole
Packaging
100mg
Price
$65
Updated
2021/12/16
Apolloscientific
Product number
OR43557
Product name
5-Bromo-1,7-dimethyl-1H-indazole
Packaging
250mg
Price
$61
Updated
2021/12/16
Apolloscientific
Product number
OR43557
Product name
5-Bromo-1,7-dimethyl-1H-indazole
Packaging
1g
Price
$173
Updated
2021/12/16
SynQuest Laboratories
Product number
3H32-9-J0
Product name
5-Bromo-1,7-dimethyl-1H-indazole
Packaging
1g
Price
$205
Updated
2021/12/16
Matrix Scientific
Product number
070080
Product name
5-Bromo-1,7-dimethyl-1H-indazole
Purity
95%
Packaging
1g
Price
$416
Updated
2021/12/16
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5-bromo-1,7-dimethyl-1H-indazole Chemical Properties,Usage,Production

Synthesis

156454-43-2

74-88-4

1092352-34-5

Step 1: 5-Bromo-7H-methyl-1H-indazole (2.11 g, 10.0 mmol) and potassium tert-butoxide (1.20 g, 10.7 mmol) were dissolved in 50 mL of tetrahydrofuran (THF) and stirred at room temperature. To this solution, iodomethane (0.700 mL, 11.2 mmol) was slowly added and the reaction mixture continued to be stirred overnight. After completion of the reaction, the precipitate was removed by filtration and the filtrate was concentrated under reduced pressure. The resulting residue was purified by fast column chromatography to afford the target product 5-bromo-1,7-dimethyl-1H-indazole in 1.92 g (43% yield). The product was analyzed by ESI-MS and showed m/z = 225/227 ([M+H]+).

References

[1] Patent: US2011/59954, 2011, A1. Location in patent: Page/Page column 97

5-bromo-1,7-dimethyl-1H-indazole Preparation Products And Raw materials

Raw materials

Preparation Products

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5-bromo-1,7-dimethyl-1H-indazole Suppliers

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1092352-34-5, 5-bromo-1,7-dimethyl-1H-indazoleRelated Search:


  • 5-bromo-1,7-dimethyl-1H-indazole
  • 1H-Indazole, 5-bromo-1,7-dimethyl-
  • 1092352-34-5