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ChemicalBook > CAS DataBase List > (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP

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Product Name
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
CAS No.
828927-95-3
Chemical Name
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
Synonyms
(R,R)-O-PINAP;Phthalazine, 1-[2-(diphenylphosphino)-1-naphthalenyl]-4-[(1R)-1-phenylethoxy]-, (1R)-;(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
CBNumber
CB42527987
Molecular Formula
C38H29N2OP
Formula Weight
560.62
MOL File
828927-95-3.mol
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(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Property

Melting point:
64-65°C
alpha 
+78.5° (c 0.25, CHCl3)
Boiling point:
726.4±60.0 °C(Predicted)
pka
3.45±0.30(Predicted)
form 
crystal
color 
colorless
Sensitive 
air sensitive
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-1782
Product name
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
Packaging
250mg
Price
$114
Updated
2021/12/16
Strem Chemicals
Product number
15-1782
Product name
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
Packaging
1g
Price
$342
Updated
2021/12/16
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(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Chemical Properties,Usage,Production

Reaction

  1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777,15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)
  2. With rhodium, enantioselective hydroboration of alkenes as a route to chiral alcohols.
  3. With silver, catalytic, enantioselective, azomethine cycloaddition with acrylates.

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Suppliers

J & K SCIENTIFIC LTD.
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View Lastest Price from (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97 (R,R)-O-PINAP 828927-95-3
Price
US $2.00-6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-08-05

828927-95-3, (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAPRelated Search:


  • (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
  • (R,R)-O-PINAP
  • Phthalazine, 1-[2-(diphenylphosphino)-1-naphthalenyl]-4-[(1R)-1-phenylethoxy]-, (1R)-
  • 828927-95-3
  • C38H29N2OP
  • PINAP Series
  • Chiral Phosphine