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N-Hydroxy-4-methylbenzenesulfonamide

Product Name
N-Hydroxy-4-methylbenzenesulfonamide
CAS No.
1593-60-8
Chemical Name
N-Hydroxy-4-methylbenzenesulfonamide
Synonyms
p-Toluenesulfonylhydroxylamine;N-Hydroxy-4-toluenesulfonamide;N-(p-Tolylsulfonyl)hydroxylamine;N-Hydroxy-4-methylbenzenesulfonamide;Benzenesulfonamide, N-hydroxy-4-methyl-
CBNumber
CB42565288
Molecular Formula
C7H9NO3S
Formula Weight
187.22
MOL File
1593-60-8.mol
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N-Hydroxy-4-methylbenzenesulfonamide Property

Melting point:
126-128℃ (DEC.)
Boiling point:
355.6±35.0 °C(Predicted)
Density 
1.363
pka
6.90±0.69(Predicted)
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Safety

HS Code 
2935909099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TRC
Product number
H543460
Product name
N-Hydroxy-4-methylbenzenesulfonamide
Packaging
100mg
Price
$75
Updated
2021/12/16
Apolloscientific
Product number
OR900172
Product name
N-Hydroxy-4-methylbenzenesulfonamide
Purity
97%
Packaging
5g
Price
$327
Updated
2021/12/16
Apolloscientific
Product number
OR900172
Product name
N-Hydroxy-4-methylbenzenesulfonamide
Purity
97%
Packaging
1g
Price
$145
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0393612
Product name
N-HYDROXY-4-METHYLBENZENESULFONAMIDE
Purity
95.00%
Packaging
5MG
Price
$502.14
Updated
2021/12/16
Ambeed
Product number
A143700
Product name
N-Hydroxy-4-methylbenzenesulfonamide
Purity
98%
Packaging
25g
Price
$1111
Updated
2021/12/16
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N-Hydroxy-4-methylbenzenesulfonamide Chemical Properties,Usage,Production

Synthesis

98-59-9

1593-60-8

General procedure for the synthesis of N-hydroxy-4-methylbenzenesulfonamide from p-toluenesulfonyl chloride: Hydroxylamine hydrochloride (7.2 g, 86 mmol) was dissolved in a solvent mixture of methanol (30 mL) and water (20 mL), followed by the addition of magnesium oxide (5.1 g, 129 mmol), and the reaction was stirred for 10 minutes. Next, a solution of tetrahydrofuran (300 mL) of p-toluenesulfonyl chloride (8 g, 43 mmol) was added to the above mixture and the reaction was vigorously stirred at room temperature. The progress of the reaction was monitored by thin layer chromatography (TLC) until the raw material was completely consumed. Upon completion of the reaction, the reaction mixture was filtered through diatomaceous earth and the filtrate was dried with anhydrous magnesium sulfate and subsequently concentrated under reduced pressure to afford N-hydroxy-4-methylbenzenesulfonamide (7 g, white solid) in 87.5% yield.

References

[1] Patent: CN105418632, 2016, A. Location in patent: Paragraph 0175; 0176; 0177
[2] Synlett, 2009, # 13, p. 2149 - 2153
[3] Journal of Inorganic Biochemistry, 2013, vol. 118, p. 134 - 139
[4] Journal fuer Praktische Chemie (Leipzig), 1901, vol. <2>63, p. 176
[5] Chem. Zentralbl., 1901, vol. 72, # I, p. 455

N-Hydroxy-4-methylbenzenesulfonamide Preparation Products And Raw materials

Raw materials

Preparation Products

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N-Hydroxy-4-methylbenzenesulfonamide Suppliers

Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19913
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
Shanghai Raise Chemical Technology Co.,Ltd
Tel
15026594951
Fax
0556-5030632
Email
rs@raise-chem.com
Country
China
ProdList
4454
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Zhengzhou Guancheng Laboratory equipment Sales
Tel
0371-88888888 272369594
Fax
QQ:272369594
Email
2723695949@qq.com
Country
China
ProdList
4958
Advantage
50
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
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QQ:3008007432
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3008007409@qq.com
Country
China
ProdList
71826
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60
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
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58
Nanjing NingFan Pharm-Tech CO. LTD.
Tel
17368696818
Country
China
ProdList
1984
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58
Jinan Liheng Biotechnology Co., Ltd.
Tel
0531-18763987518 18763987518
Email
levi@lihengpharm.com
Country
China
ProdList
1797
Advantage
58
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View Lastest Price from N-Hydroxy-4-methylbenzenesulfonamide manufacturers

Career Henan Chemical Co
Product
N-Hydroxy-4-methylbenzenesulfonamide 1593-60-8
Price
US $1.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
100kg
Release date
2020-01-14

1593-60-8, N-Hydroxy-4-methylbenzenesulfonamideRelated Search:


  • N-Hydroxy-4-methylbenzenesulfonamide
  • N-(p-Tolylsulfonyl)hydroxylamine
  • N-Hydroxy-4-toluenesulfonamide
  • p-Toluenesulfonylhydroxylamine
  • Benzenesulfonamide, N-hydroxy-4-methyl-
  • 1593-60-8