ChemicalBook > CAS DataBase List > 9,9-diphenyl-9H-fluoreN-2-ylboronicacid

9,9-diphenyl-9H-fluoreN-2-ylboronicacid

Product Name
9,9-diphenyl-9H-fluoreN-2-ylboronicacid
CAS No.
400607-31-0
Chemical Name
9,9-diphenyl-9H-fluoreN-2-ylboronicacid
Synonyms
9,9-Diphenylfluoren-2-boronic acid;9,9-Diphenylfluorene-2-boronic acid;9,9-Diphenylfluoren-2-ylboronic acid;9,9-Diphenylfluorene-2-boronic Acid (c;9,9-diphenyl-9h-fluoren-2-boronic acid;9,9-diphenyl-9H-fluoreN-2-ylboronicacid;9,9-Diphenyl-9H-(fluorene-2-yl)-boronic acid;B-(9,9-Diphenyl-9H-fluoren-2-yl)-boronic Acid;Boronic acid, (9,9-diphenyl-9H-fluoren-2-yl)-;Boronic acid,B-(9,9-diphenyl-9H-fluoren-2-yl)-
CBNumber
CB42631912
Molecular Formula
C25H19BO2
Formula Weight
362.23
MOL File
400607-31-0.mol
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9,9-diphenyl-9H-fluoreN-2-ylboronicacid Property

Boiling point:
546.3±60.0 °C(Predicted)
Density 
1.28±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
pka
8.55±0.40(Predicted)
Appearance
White to off-white Solid
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Safety

HS Code 
2931.90.6000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D5084
Product name
9,9-Diphenylfluorene-2-boronic Acid (contains varying amounts of Anhydride)
Packaging
200mg
Price
$103
Updated
2025/07/31
TCI Chemical
Product number
D5084
Product name
9,9-Diphenylfluorene-2-boronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$342
Updated
2021/12/16
TRC
Product number
D491605
Product name
B-(9,9-Diphenyl-9H-fluoren-2-yl)-boronicAcid
Packaging
500mg
Price
$1320
Updated
2021/12/16
TRC
Product number
D491605
Product name
B-(9,9-Diphenyl-9H-fluoren-2-yl)-boronicAcid
Packaging
50mg
Price
$165
Updated
2021/12/16
AK Scientific
Product number
9601AL
Product name
9,9-Diphenylfluorene-2-boronicAcid
Packaging
250mg
Price
$157
Updated
2021/12/16
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9,9-diphenyl-9H-fluoreN-2-ylboronicacid Chemical Properties,Usage,Production

Uses

B-(9,9-Diphenyl-9H-fluoren-2-yl)-boronic Acid can be used to synthesize pyrrole/polycyclic aromatic units. It is a potential electroluminescent material.

Synthesis

121-43-7

474918-32-6

400607-31-0

General procedure for the synthesis of (9,9-diphenyl-9H-fluoren-2-yl)boronic acid from trimethyl borate and 2-bromo-9,9-diphenylfluorene: 10 g of 2-bromo-9,9-diphenylfluorene and 100 ml of anhydrous tetrahydrofuran were added to a 1-liter flask, and the mixture was cooled to -78 °C (using a bath of liquid nitrogen). Subsequently, 25.2 mL of n-butyllithium solution was added slowly and dropwise, followed by trimethyl borate. The reaction mixture was stirred at -78 °C and then allowed to warm naturally to room temperature. Then, an appropriate amount of dilute hydrochloric acid was added to carry out the hydrolysis reaction. Upon completion of the reaction, the mixture was extracted with ethyl acetate, the organic layer was separated and dried with anhydrous sodium sulfate. Finally, the solvent was removed by distillation under reduced pressure and the residue was eluted with hexane to afford 4 g of the target product (9,9-diphenyl-9H-fluoren-2-yl)boronic acid.

References

[1] Patent: CN106957272, 2017, A. Location in patent: Paragraph 0090; 0091

9,9-diphenyl-9H-fluoreN-2-ylboronicacid Preparation Products And Raw materials

Raw materials

Preparation Products

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9,9-diphenyl-9H-fluoreN-2-ylboronicacid Suppliers

Americas 1 China 94 Europe 1 India 2 Japan 1 United States 6 Global 105
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
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View Lastest Price from 9,9-diphenyl-9H-fluoreN-2-ylboronicacid manufacturers

LY Global chemicals co.,ltd .
Product
9,9-diphenyl-9H-fluoreN-2-ylboronicacid 400607-31-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%Min
Supply Ability
1000kg
Release date
2023-03-12
Career Henan Chemical Co
Product
9,9-diphenyl-9H-fluoreN-2-ylboronicacid 400607-31-0
Price
US $2.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
ask
Release date
2018-12-20

400607-31-0, 9,9-diphenyl-9H-fluoreN-2-ylboronicacidRelated Search:

4''-PENTYL-3-FLUOROBIPHENYL-4-BORONIC ACID 2-boronic acid-9-phenylcarbazole 9,9-diphenyl-9H-fluoreN-4-ylboronicacid (9-phenyl-9H-carbazol-2-yl)boronic acid 9-(biphenyl-4-yl)-3-boric acid-9H-carbazole

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  • B-(9,9-Diphenyl-9H-fluoren-2-yl)-boronic Acid
  • 9,9-Diphenylfluorene-2-boronic Acid (contains varying amounts of Anhydride)
  • 9,9-Diphenylfluorene-2-boronic acid
  • Boronic acid,B-(9,9-diphenyl-9H-fluoren-2-yl)-
  • 9,9-diphenyl-9H-fluoreN-2-ylboronicacid
  • 9,9-Diphenyl-9H-(fluorene-2-yl)-boronic acid
  • 9,9-Diphenylfluoren-2-ylboronic acid
  • 9,9-diphenyl-9h-fluoren-2-boronic acid
  • 9,9-Diphenylfluorene-2-boronic Acid (c
  • 9,9-Diphenylfluoren-2-boronic acid
  • 2,8-dibromo-6,6,12,12-tetramethyl-6H,12H-indeno[1,2-b]fluorene
  • 9,9-Diphenylfluorene-2-boronic(containsvaryingamountsofAnhydride)
  • (9,9-Diphenyl-9H-fluoren-2-yl)boronic acid - [D90312]
  • 400607-31-0
  • 400604-31-0
  • C25H19BO2