[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride

Product Name
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
CAS No.
191654-69-0
Chemical Name
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
Synonyms
[PdCl2{(R)-4-tolylbinap}];[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
CBNumber
CB42637848
Molecular Formula
C48H42Cl2P2Pd
Formula Weight
858.13
MOL File
191654-69-0.mol
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[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Property

Melting point:
>300°C
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
708461
Product name
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride
Packaging
100mg
Price
$50.9
Updated
2023/06/20
Sigma-Aldrich
Product number
708461
Product name
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride
Packaging
500mg
Price
$137
Updated
2022/05/15
American Custom Chemicals Corporation
Product number
ING0013493
Product name
[(R)-(+)-2,2'-BIS-(DI-PARA-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE
Purity
95.00%
Packaging
5MG
Price
$496.53
Updated
2021/12/16
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[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Chemical Properties,Usage,Production

Uses

Catalyst for:

  • Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetal
  • Stereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactants
  • Stereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzinc

Reactant for:
  • Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Suppliers

Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Baoji Didu Pharmaceutical and Chemical Co., Ltd
Tel
02961856358 15829046862
Email
1035@dideu.com
Country
China
ProdList
10011
Advantage
58

191654-69-0, [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chlorideRelated Search:


  • [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
  • [PdCl2{(R)-4-tolylbinap}]
  • 191654-69-0