fluoroMethyl 4-Methylbenzenesulfonate

Product Name: fluoroMethyl 4-Methylbenzenesulfonate
CAS No.: 114435-86-8
Chemical Name: fluoroMethyl 4-Methylbenzenesulfonate
Synonyms: FMTS;Fluoromethyl p-Toluenesulfonate;luoroMethyl 4-Methylbenzenesulfonate;fluoroMethyl 4-Methylbenzenesulfonate;Fluoromethyl 4-methylbenzenesulphonage;Fluoromethyl 4-methylbenzenesulfonate 97+%;fluoromethanol,4-methylbenzenesulfonic acid;Methanol, fluoro-, 4-methylbenzenesulfonate;Methanol, 1-fluoro-, 1-(4-methylbenzenesulfonate)
CBNumber: CB42642765
Molecular Formula: C8H9FO3S
Formula Weight: 204.22
MOL File: 114435-86-8.mol

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fluoroMethyl 4-Methylbenzenesulfonate Property

Boiling point:: 302.1±22.0 °C(Predicted)
Density: 1.282±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: liquid
color: Colourless
InChI: InChI=1S/C8H9FO3S/c1-7-2-4-8(5-3-7)13(10,11)12-6-9/h2-5H,6H2,1H3
InChIKey: RFCGZPLGJZELOK-UHFFFAOYSA-N
SMILES: C(OS(C1=CC=C(C)C=C1)(=O)=O)F

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Safety

RIDADR: 3265
HazardClass: 8
PackingGroup: Ⅱ
HS Code: 2904100090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC

Product number: F598295
Product name: Fluoromethyl4-Methylbenzenesulfonate
Packaging: 2.5mg
Price: $45
Updated: 2021/12/16

Apolloscientific

Product number: PC250002
Product name: Fluoromethyl4-methylbenzenesulfonate
Purity: 97+%
Packaging: 100mg
Price: $393
Updated: 2021/12/16

SynQuest Laboratories

Product number: 6764-3-00
Product name: Fluoromethyl 4-methylbenzenesulfonate
Packaging: 100mg
Price: $434
Updated: 2021/12/16

Apolloscientific

Product number: PC250002
Product name: Fluoromethyl4-methylbenzenesulfonate
Purity: 97+%
Packaging: 250mg
Price: $625
Updated: 2021/12/16

SynQuest Laboratories

Product number: 6764-3-00
Product name: Fluoromethyl 4-methylbenzenesulfonate
Packaging: 250mg
Price: $690
Updated: 2021/12/16

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fluoroMethyl 4-Methylbenzenesulfonate Chemical Properties,Usage,Production

Synthesis

Methylene ditosylate (100 mg, 0.28 mmol) and caesium fluoride (213 mg, 1.4 mmol) were dissolved in tert-amyl alcohol (5 mL) and irradiated in a microwave for 15 minutes at 90 °C. The reaction was allowed to cool and the tert-amyl alcohol was removed under reduced pressure, ice-cold diethyl ether was added and the suspension filtered, and then washed with plenty of ice-cold diethyl ether. The filtrate was concentrated under reduced pressure to yield Fluoromethyl 4-Methylbenzenesulfonate as a colourless oil (49 mg, 88% yield).

References

[1] Tetrahedron Letters, 2018, vol. 59, # 17, p. 1635 - 1637
[2] Bioorganic and Medicinal Chemistry Letters, 2015, vol. 25, # 18, p. 3956 - 3960
[3] Journal of Labelled Compounds and Radiopharmaceuticals, 2003, vol. 46, # 6, p. 555 - 566
[4] ChemMedChem, 2016, vol. 11, # 1, p. 108 - 118
[5] Patent: WO2012/40133, 2012, A2. Location in patent: Page/Page column 36-37

fluoroMethyl 4-Methylbenzenesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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fluoroMethyl 4-Methylbenzenesulfonate Suppliers

China 57 United Kingdom 1 United States 5 Global 63

Jiaxing Fubo Biotechnology Co., Ltd.

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View Lastest Price from fluoroMethyl 4-Methylbenzenesulfonate manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: fluoroMethyl 4-Methylbenzenesulfonate 114435-86-8
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-09

Henan Fengda Chemical Co., Ltd

Product: fluoroMethyl 4-Methylbenzenesulfonate 114435-86-8
Price: US $101.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-28

Career Henan Chemical Co

Product: fluoroMethyl 4-Methylbenzenesulfonate 114435-86-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-09

114435-86-8, fluoroMethyl 4-MethylbenzenesulfonateRelated Search:

fluoroMethyl 4-Methylbenzenesulfonate

Fluoromethyl 4-methylbenzenesulfonate 97+%

luoroMethyl 4-Methylbenzenesulfonate

Methanol, 1-fluoro-, 1-(4-methylbenzenesulfonate)

Fluoromethyl p-Toluenesulfonate

Methanol, fluoro-, 4-methylbenzenesulfonate

FMTS

fluoromethanol,4-methylbenzenesulfonic acid

Fluoromethyl 4-methylbenzenesulphonage

114435-86-8

C8H9O3FS