Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4

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Product Name: Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4
CAS No.: 1345974-62-0
Chemical Name: Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4
Synonyms: Rh₂(R-BTPCP)₄;Tetrakis[(R)-(-)-[(1R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II);Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4
CBNumber: CB42709266
Molecular Formula: C88H64Br4O8Rh2
Formula Weight: 1774.9
MOL File: 1345974-62-0.mol

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Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4 Property

Melting point:: >300°C
form: solid
color: green

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 45-2080
Product name: Tetrakis[(R)-(-)-[(1R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II) Rh2(R-BTPCP)4
Packaging: 50mg
Price: $121
Updated: 2024/03/01

Strem Chemicals

Product number: 45-2080
Product name: Tetrakis[(R)-(-)-[(1R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II) Rh2(R-BTPCP)4
Packaging: 250mg
Price: $485
Updated: 2024/03/01

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Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4 Chemical Properties,Usage,Production

Reaction

Chiral catalyst used for the enantioselective formation of cyclopropanes from the reaction of aryls with styryl diazoacetates.
Chiral catalyst used for the asymmetric synthesis of bicyclo[1.1.0]butane rings via the rhodium-catalyzed decomposition of 2-diazo-5-arylpent-4-enoates.
Rhodium-Catalyzed [4+3] Cycloaddition between Vinyldiazoacetates and Dienes.

Uses

Rh catalyst developed by the Davies lab used for enantioselective cyclopropanations and C-H funcionalization under low catalyst loadings.

Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4 Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4 Suppliers

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1345974-62-0, Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4Related Search:

Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4

Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4

Tetrakis[(R)-(-)-[(1R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II)

Rh2(R-BTPCP)4

1345974-62-0

C88H64Br4O8Rh2