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Iprobenfos

Product Name
Iprobenfos
CAS No.
26087-47-8
Chemical Name
Iprobenfos
Synonyms
epb;EBP;IBP;ricidp;C15230;ricidii;KITAZIN;kitazinl;KITAZINE;Kitazin L
CBNumber
CB4298968
Molecular Formula
C13H21O3PS
Formula Weight
288.34
MOL File
26087-47-8.mol
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Iprobenfos Property

Melting point:
25°C
Boiling point:
126°C
Density 
1.1001 g/cm3
vapor pressure 
2.5 x 10-4 Pa (20 °C)
refractive index 
approximate 1.51
Flash point:
11 °C
storage temp. 
APPROX 4°C
Water Solubility 
430 mg l-1(20 °C)
form 
liquid
BRN 
1974687
CAS DataBase Reference
26087-47-8(CAS DataBase Reference)
NIST Chemistry Reference
Kitazin p(26087-47-8)
EPA Substance Registry System
Phosphorothioic acid, O,O-bis(1-methylethyl) S-(phenylmethyl) ester (26087-47-8)
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Safety

Hazard Codes 
Xn;N,N,Xn,T,F
Risk Statements 
22-51/53-39/23/24/25-23/24/25-11
Safety Statements 
61-45-36/37-16-7
RIDADR 
UN 3082
WGK Germany 
2
RTECS 
TE6550000
HazardClass 
6.1(a)
PackingGroup 
II
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
45814
Product name
Iprobenfos
Purity
PESTANAL
Packaging
100mg
Price
$166
Updated
2024/03/01
TRC
Product number
I745100
Product name
Iprobenfos
Packaging
5g
Price
$1050
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
70941
Product name
Iprobenfos
Packaging
5G
Price
$2000
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AGR0000177
Product name
IPROBENFOS
Purity
98.00%
Packaging
50ML
Price
$2728
Updated
2021/12/16
Biorbyt Ltd
Product number
orb599350
Product name
EBP
Packaging
10μg
Price
$290.7
Updated
2021/12/16
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Iprobenfos Chemical Properties,Usage,Production

Uses

Iprobenfos is a systemic fungicide which provides effective protective and curative control of leaf and ear blast (Pyricularia oryzae), stem rot (Helminthosporium spp.) and sheath blight (Rhizoctonia solani) in rice.

Definition

ChEBI: An organic thiophosphate that is the S-benzyl O,O-diisopropyl ester of phosphorothioic acid. Used as a rice fungicide to control leaf and ear blast, stem rot and sheath blight.

Metabolic pathway

Iprobenfos undergoes extensive degradation and metabolism. Primary metabolic pathways include isomerisation to the thionate (P=S) ester, cleavage of the P-S-benzyl and P-O-isopropyl moieties, and transesterification. Benzyl mercaptan, upon cleavage, undergoes additional oxidation reactions to yield the alcohol, carboxylic acid, disulfide and sulfonic acid. The formation of the oxon from the isomerisation product (P=S ester) was minor and was observed only under UV light irradiation. The primary metabolic pathways of iprobenfos are presented in Scheme 1.

Degradation

Iprobenfos (1) is stable to hydrolytic degradation (<50 °C). The DTN value of iprobenfos in aqueous solution was approximately 301-324 days(PM).
Iprobenfos degraded rapidly when deposited as a thin film and exposed to UV light (DT50 ca. 10 min). Two major degradation reactions were observed during the initial phase of the irradiation. The first reaction involved the isomerisation of iprobenfos to O,O-diisopropyl O- benzyl phosphorothioate (2) followed by the oxidative desulfuration of compound 2 to yield the corresponding oxon analogue 3 (O,O-diisopropyl O-benzyl phosphate). The second reaction involved the hydrolytic cleavage of the S-C linkage of iprobenfos to yield O,O-diisopropyl hydrogen phosphorothioate (4) and the cleavage of the P-O-benzyl linkage of compound 3 to yield O,O-diisopropyl hydrogen phosphate (5). Other major photolytic degradation reactions include the cleavage of the parent P-S linkage to O,O-diisopropyl phosphonate (6). Benzyl alcohol (7) and benzyl mercaptan (8) were also detected. Further oxidation of compound 7 yielded benzoic acid (9) and the oxidation of compound 8 yielded benzylsulfonic acid (10), dibenzyl disulfide (11) and sulfuric acid as terminal products. Other minor products detected included transesterification products [O,O,S-triisopropyl phosphorothioate (12), O,O,O-triisopropyl phosphate (13)] and benzyl isopropyl sulfide (14).

Iprobenfos Preparation Products And Raw materials

Raw materials

Sodium thiophosphate Petroleum crude oil Sulfur MERCAPTANS Benzyl chloride Phosphite Rice net AMMONIUM O,O-DIISOPROPYLTHIOPHOSPHATE Vacuum pump Combinatorial chemistry Toluene Chlorine Diisopropyl phosphite Phosphorus trichloride Diethyl phosphite Sulphur White phosphorus Isopropyl alcohol 1,1'-Thiobisethane Ammonium bicarbonate Ammonia

Preparation Products

AMMONIUM O,O-DIISOPROPYLTHIOPHOSPHATE Tricyclazole+Iprobenfos,W.P.(20%)
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Iprobenfos Suppliers

China 102 Europe 1 France 2 Germany 2 India 7 Japan 4 South Korea 1 Switzerland 1 United Kingdom 3 United States 16 Global 139
Zhejiang Jiahua Chemical Corporation
Tel
+86-573-2807222
Fax
+86-573-2807111
Email
kieserite@hotmail.com
Country
China
ProdList
51
Advantage
64
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12335
Advantage
58
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
The future of Shanghai Industrial Co., Ltd.
Tel
021-61552785
Fax
021-55660885
Email
sales@shshiji.com
Country
China
ProdList
9545
Advantage
55
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9978
Advantage
55
Hubei Jusheng Technology Co.,Ltd
Tel
027-59599241 18871490274
Fax
027-59599241
Email
1400878000@qq.com
Country
China
ProdList
9958
Advantage
58
Alta Scientific Co., Ltd.
Tel
022-6537-8550 15522853686
Fax
022-2532-9655
Email
sales@altasci.com.cn
Country
China
ProdList
4511
Advantage
55
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View Lastest Price from Iprobenfos manufacturers

Career Henan Chemical Co
Product
Iprobenfos 26087-47-8
Price
US $3.00/KG
Min. Order
1KG
Purity
99
Supply Ability
1000kg
Release date
2019-07-30

26087-47-8, IprobenfosRelated Search:

Cumene PROMETHAZINE Promethazine hydrochloride Diisopropylamine (-)-ISOPROTERENOL HYDROCHLORIDE N,N-Diisopropylethylamine Propofol Isoproturon Diisopropyl ether Azamethiphos 3-Methyl-2-butanone Isoprocarb Ritonavir Impurity 4 O,O,S-triethyl phosphorothioate Thiophosphoric acid O,O-diethyl S-benzyl ester Desbenzyl IBP O,O,S-trimethyl phosphorothioate Iprobenfos

  • o，o-Diethyl-s-benzylthiophosphate
  • S-BENZYL O,O-DI-ISOPROPYL-PHOSPHOROTHIOATE
  • iprofenfos
  • Kitazin L
  • kitazinl
  • O,O-bis(1-Methylethyl)-S-(phenylmethyl)phosphorothiolate
  • O,O-Diisopropyl S-Benzyl phosphorothioate
  • O,O-Diisopropyl S-benzyl thiophosphate
  • o,o-diisopropyl-s-benzylesterkyselinythiofosforecne
  • o,o-diisopropyls-benzylphosphorothiolate
  • o,o-diisopropyls-benzylthiophosphate
  • Prednicarbate EP Impurity B
  • Phosphorothioic acid, O,O-bis(1-methylethyl) S-(phenylmethyl) ester
  • Phosphorothioic acid, S-benzyl O,O-diisopropyl ester
  • Phosphorothioicacid,O,O-bis(1-methylethyl)-S-(phenylmethyl)ester
  • phosphorothioicacid,s-benzylo,o-diisopropylester
  • ricidii
  • ricidp
  • S-Benzyl O,O-diisopropyl thiophosphate
  • s-benzyldiisopropylphosphorothioate
  • probenfos
  • Di(propan-2-yloxy)phosphorylsulfanylmethylbenzene
  • Kitajin P
  • Phosphorothioic acid O,O-bis(1-methylethyl) S-phenylmethyl
  • Phosphorothioic acid S-benzyl O,O-diisopropyl
  • C15230
  • Iprobenfos 500mg [26087-47-8]
  • Iprobenfos standard solution
  • Iprobenfos E.C.
  • O，O-diethy-S-benzylphosphorothioate
  • Iprobenfos solutio
  • 3-beta-hydroxysteroid-Delta(8),Delta(7)-isomerase
  • ANTI-EBP(N-TERMINAL) antibody produced in rabbit
  • Cholestenol Delta-isomerase
  • Iprobenfos 0.1
  • Iprobenfos Solution, 100ppm
  • Iprobenfos (IBP)
  • IPROBENFOS, 500MG, NEAT
  • IPROBENPHOS SOLUTION 100 NG/MYL, IN METH ANOL, PESTANAL
  • IPROBENPHOS PESTANAL, (S-BENZYL DIISOPRO
  • iprobenfos (bsi, draft e-iso, draft f-iso)
  • iprobenfos solution
  • Iprobenfos(KitazinP/IBP)
  • benzyl ethyl phosphorothioate
  • epb
  • Phosphorothioic acid, esters, O,O-diethyl-S-(phenylmethyl) ester
  • phosphorothioic acid, s-benzyl o,o-diethyl ester
  • EBP
  • Phosphorothioic acid, O,O-bis(1-methylethyl)-S-(phenylmethyl) ester IBP
  • O,O-Bis(1-methylethyl) S-(phenylmethyl) phosphorothioate
  • BENZYLETHYLTHIOPOSPHATE
  • KITAZIN
  • KITAZINE
  • KITAZIN P
  • KITAZIN(R)
  • IPROBENFOS
  • IPROBENPHOS
  • IBP