ChemicalBook > CAS DataBase List > 5-Acetyloxindole

5-Acetyloxindole

Product Name
5-Acetyloxindole
CAS No.
64483-69-8
Chemical Name
5-Acetyloxindole
Synonyms
5-ACETYLOXINDOLE;1H-indol-5-yl acetate;5-acetyl-2-indolinone;5-acetylindolin-2-one;5-Acetyl-1H-indolin-2-one;5-Acetyl-1,3-dihydro-indol-2-one;2H-Indol-2-one,5-acetyl-1,3-dihydro-
CBNumber
CB4325127
Molecular Formula
C10H9NO2
Formula Weight
175.18
MOL File
64483-69-8.mol
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5-Acetyloxindole Property

Melting point:
225-227 °C
Boiling point:
418.4±45.0 °C(Predicted)
Density 
1.228±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
13.46±0.20(Predicted)
Appearance
White to off-white Solid
CAS DataBase Reference
64483-69-8(CAS DataBase Reference)
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Safety

HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
A165425
Product name
5-Acetyloxindole
Packaging
50mg
Price
$60
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA149735
Product name
5-Acetyloxindole
Packaging
1g
Price
$73
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA149735
Product name
5-Acetyloxindole
Packaging
2g
Price
$127
Updated
2021/12/16
Apolloscientific
Product number
OR913281
Product name
5-Acetyloxindole
Purity
95%
Packaging
1g
Price
$130
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA149735
Product name
5-Acetyloxindole
Packaging
5G
Price
$254
Updated
2021/12/16
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5-Acetyloxindole Chemical Properties,Usage,Production

Synthesis

59-48-3

75-36-5

64483-69-8

Example I Synthesis of 5-acetyl-2-indolomanone: 171 g (1.28 mol) of anhydrous aluminum chloride was suspended in 500 mL of 1,2-dichloroethane and cooled to 0-5°C under ice bath conditions. Subsequently, 78 g (1.1 mol) of acetyl chloride was slowly added dropwise, and the reaction temperature was controlled to not exceed 10 °C. After the dropwise addition, the reaction was continued with stirring for 1 hour. Then, 71.3 g (0.53 mol) of 2-indolone (1,3-dihydroindol-2-one) was added in four batches, ensuring that the reaction temperature was maintained between 10-12 °C after each batch. After the addition was completed, the reaction mixture was allowed to warm slowly to room temperature and stirred overnight. At the end of the reaction, the reaction solution was quenched by slowly pouring it into 1 kg of ice water under vigorous stirring. Subsequently, the slurry was diluted with 1 L of water and stirring was continued for 30 min. The precipitate was collected by diafiltration and dried to give the crude product. After purification, 80.9 g of the target compound 5-acetyl-2-indolomanone was obtained in 86.3% yield of the theoretical value. Thin layer chromatography (TLC) analysis showed Rf = 0.36 (silica gel plate, unfolding agent was ethyl acetate/cyclohexane/methanol = 9:9:2). The molecular formula of the product was C10H9NO2 (molecular weight = 175.19 g/mol) and mass spectrometry analysis showed m/z = 174 ([M-H]-).

References

[1] Patent: US2005/203104, 2005, A1. Location in patent: Page/Page column 8
[2] Patent: WO2005/87726, 2005, A1. Location in patent: Page/Page column 22
[3] Patent: US2005/234120, 2005, A1. Location in patent: Page/Page column 7
[4] Patent: US2009/42876, 2009, A1. Location in patent: Page/Page column 25
[5] Patent: US6395734, 2002, B1

5-Acetyloxindole Preparation Products And Raw materials

Raw materials

Preparation Products

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5-Acetyloxindole Suppliers

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