3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE

Product Name: 3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE
CAS No.: 87743-10-0
Chemical Name: 3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE
Synonyms: 3-((diMethylaMino)Methyl)-4-hydroxy-5-Methoxybenzaldehyde;Benzaldehyde, 3-[(dimethylamino)methyl]-4-hydroxy-5-methoxy-;3-[(Dimethylamino)methyl]-4-hydroxy-5-methoxybenzaldehyde95%;3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE;3-[(Dimethylamino)methyl]-4-hydroxy-5-methoxybenzenecarboxaldehyde;3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE ISO 9001：2015 REACH;2-[(Dimethylamino)methyl]-4-formyl-6-methoxyphenol, N,N-Dimethyl-5-formyl-2-hydroxy-3-methoxybenzylamine
CBNumber: CB4355601
Molecular Formula: C11H15NO3
Formula Weight: 209.24
MOL File: Mol file

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3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE Property

Melting point:: 140-141
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: Light yellow to yellow Solid

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Safety

Hazard Codes: Xi
HazardClass: IRRITANT
HS Code: 2922500090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: D462480
Product name: 3-[(Dimethylamino)methyl]-4-hydroxy-5-methoxybenzenecarbaldehyde
Packaging: 1g
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 042793
Product name: 3-[(Dimethylamino)methyl]-4-hydroxy-5-methoxybenzenecarbaldehyde
Purity: >95%
Packaging: 500mg
Price: $118
Updated: 2021/12/16

Apolloscientific

Product number: OR9894
Product name: 3-[(Dimethylamino)methyl]-4-hydroxy-5-methoxybenzaldehyde
Purity: 95%
Packaging: 1g
Price: $61
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4656-1-Z4
Product name: 3-[(Dimethylamino)methyl]-4-hydroxy-5-methoxybenzaldehyde
Purity: 95%
Packaging: 1g
Price: $68
Updated: 2021/12/16

Matrix Scientific

Product number: 042793
Product name: 3-[(Dimethylamino)methyl]-4-hydroxy-5-methoxybenzenecarbaldehyde
Purity: >95%
Packaging: 1g
Price: $151
Updated: 2021/12/16

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3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE Chemical Properties,Usage,Production

Synthesis

50-00-0

121-33-5

124-40-3

87743-10-0

To a stirred solution of aqueous formaldehyde (37% w/w, 37.5 mmol, 2.8 mL) and aqueous dimethylamine (40% w/w, 37.5 mmol, 4.8 mL) in ethanol (25 mL) was added 4-hydroxy-3-methoxybenzaldehyde (vanillin, 25 mmol, 3.883 g). The reaction mixture was stirred and heated to reflux for 45 minutes, followed by continued stirring at room temperature overnight. Upon completion of the reaction, the precipitated milky white solid was separated by filtration under reduced pressure, washed with ice-cold acetone and dried under vacuum at room temperature to afford 3-((dimethylamino)methyl)-4-hydroxy-5-methoxybenzaldehyde as an off-white solid. Yield: 75% (3.910 g); Melting point: 140-142°C (literature value: 139-141°C, see reference [43j]); 1H NMR (400 MHz, CDCl3) δ (ppm): 10.6 (1H, broad single peak, OH), 9.77 (1H, single peak, CHO), 7.34 (1H, single peak, ArH). 7.15 (1H, single peak, ArH), 3.94 (3H, single peak, OCH3), 3.76 (2H, single peak, CH2), 2.38 (6H, single peak, 2×CH3); 13C NMR (100 MHz, CDCl3) δ (ppm): 190.7, 154.5, 148.6, 128.1, 125.3, 121.4. 109.8, 62.2, 56.0, 44.3.

References

[1] Tetrahedron Letters, 2010, vol. 51, # 15, p. 1979 - 1981
[2] Synthetic Communications, 1983, vol. 13, # 8, p. 677 - 684
[3] Patent: WO2016/80853, 2016, A1. Location in patent: Paragraph 00310; 00311
[4] Patent: CN105418601, 2016, A. Location in patent: Paragraph 0271; 0272, 0273
[5] Bulletin of the Chemical Society of Japan, 1956, vol. 29, p. 265,269

3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE Suppliers

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87743-10-0, 3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDERelated Search:

3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE

3-[(Dimethylamino)methyl]-4-hydroxy-5-methoxybenzenecarboxaldehyde

2-[(Dimethylamino)methyl]-4-formyl-6-methoxyphenol, N,N-Dimethyl-5-formyl-2-hydroxy-3-methoxybenzylamine

3-((diMethylaMino)Methyl)-4-hydroxy-5-Methoxybenzaldehyde

3-[(Dimethylamino)methyl]-4-hydroxy-5-methoxybenzaldehyde95%

Benzaldehyde, 3-[(dimethylamino)methyl]-4-hydroxy-5-methoxy-

3-[(DIMETHYLAMINO)METHYL]-4-HYDROXY-5-METHOXYBENZENECARBALDEHYDE ISO 9001：2015 REACH

87743-10-0