MANGANESE(III) FLUORIDE

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MANGANESE(III) FLUORIDE

Product Name: MANGANESE(III) FLUORIDE
CAS No.: 7783-53-1
Chemical Name: MANGANESE(III) FLUORIDE
Synonyms: MnF3;Manganic fluoride;MANGANESE TRIFLUORIDE;Manganese(Ⅲ) Fluoride;MANGANESE(III) FLUORIDE;manganesefluoride(mnf3);Manganese fluoride (III);Manganese fluoride (MnF3);Manganese(III)fluoride99%;Manganese(III)fluoride,98%
CBNumber: CB4356370
Molecular Formula: F3Mn
Formula Weight: 111.93
MOL File: 7783-53-1.mol

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MANGANESE(III) FLUORIDE Property

Melting point:

decomposes at >600℃ [KIR81]

Density

3.54 g/mL at 25 °C(lit.)

solubility

reacts with H2O

form

Powder

color

red

Specific Gravity

3.54

Water Solubility

Insoluble in organic solvents. Hydrolyzed by water.

Sensitive

Hygroscopic

Merck

14,5741

crystal system

Monoclinic

Space group

C2/c

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.892	0.505	1.348	90	92.6	90	0.606

Exposure limits

ACGIH: TWA 2.5 mg/m3; TWA 0.02 mg/m3; TWA 0.1 mg/m3
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; IDLH 250 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3

Stability:

Stable. Incompatible with strong oxidizing agents. Protect from moisture. Contact with combustible material may lead to fire.

CAS DataBase Reference

7783-53-1(CAS DataBase Reference)

EPA Substance Registry System

Manganese fluoride (MnF3) (7783-53-1)

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Safety

Hazard Codes: O,Xn
Risk Statements: 8-20/21/22-36/37/38
Safety Statements: 17-26-36/37/39
RIDADR: UN 3087 5.1/PG 2
WGK Germany: 3
RTECS: OP0882600
Hazard Note: Harmful/Oxidising Agent/Hygroscopic
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 2826199090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H272May intensify fire; oxidizer

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 339296
Product name: Manganese(III) fluoride
Purity: 99.9% trace metals basis
Packaging: 10g
Price: $61.8
Updated: 2024/03/01

Alfa Aesar

Product number: 013069
Product name: Manganese(III) fluoride, 98% (metals basis)
Packaging: 10g
Price: $44.65
Updated: 2024/03/01

Alfa Aesar

Product number: 013069
Product name: Manganese(III) fluoride, 98% (metals basis)
Packaging: 50g
Price: $193
Updated: 2023/06/20

Strem Chemicals

Product number: 93-2542
Product name: Manganese(III) fluoride, 98%
Packaging: 5g
Price: $30
Updated: 2024/03/01

Strem Chemicals

Product number: 93-2542
Product name: Manganese(III) fluoride, 98%
Packaging: 25g
Price: $120
Updated: 2024/03/01

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MANGANESE(III) FLUORIDE Chemical Properties,Usage,Production

Description

The manganese fluoride, MnF3, is preferably formed by fluorination of manganese(III) iodide. It is a solid, and although its decomposition pressure is lower than 10.1325kPa (0.1 atmosphere) at 600°C, fluorine is still released when heated. It is a strong fluorinating agent, which acts with sulfur, boron, silicon, carbon, phosphorus trichloride and carbon tetrachloride when heated. It is used to fluoride gaseous hydrocarbons.

Chemical Properties

purple powder or crystals

Uses

It is used as a fluorinating agent, useful for conversion of hydrocarbons into fluorocarbons. It is used in organic synthesis as Lewis acid to prepare a number of organic compounds.

Uses

Fluorinating agent in organic chemistry.

Preparation

Manganese(III) fluoride can also be formed via the reaction of elemental fluorine with a manganese(II) halide at around 250°C.

General Description

Manganese(III) fluoride (also known as manganese trifluoride), MnF3, is a red/purplish solid useful for converting hydrocarbons into fluorocarbons, that is, it is a fluorination agent. It forms a hydrate and numerous derivatives. MnF3 can be produced by reacting a solution of MnF2 in hydrogen fluoride with fluorine.

Hazard

Toxic material.

Synthesis

Dissolve Mn2O3 in hydrofluoric acid and concentrate the solution for crystallization, or reduce potassium permanganate in hydrofluoric acid with low manganese salt to obtain hydrated manganese fluoride MnF3·3H2O. This compound is soluble in cold water and does not decompose, and is stable in hot water in the presence of hydrofluoric acid. Anhydrous manganese trifluoride is slowly decomposed into manganese difluoride, hydrated manganese dioxide and hydrogen fluoride in water.

MANGANESE(III) FLUORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from MANGANESE(III) FLUORIDE manufacturers

Wuhan Monad Medicine Tech Co.,LTD

Product: Manganese fluoride(MnF3) 7783-53-1
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99.99%
Supply Ability: 20 tons/month
Release date: 2021-04-19

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