CHLOZOLINATE

ChemicalBook > CAS DataBase List > CHLOZOLINATE

Product Name: CHLOZOLINATE
CAS No.: 84332-86-5
Chemical Name: CHLOZOLINATE
Synonyms: SERINAL;Manderol;SDS 65311;Clozolinate;CHLOZOLINATE;Chlozolinate 1;Einecs 282-714-4;Chlozolinate [iso];Chlozolinate Standard;chlozolinate (bsi,iso)
CBNumber: CB4358743
Molecular Formula: C13H11Cl2NO5
Formula Weight: 332.14
MOL File: 84332-86-5.mol

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CHLOZOLINATE Property

Melting point:: 110-114 °C
Boiling point:: 420.8±55.0 °C(Predicted)
Density: 1.479
vapor pressure: 1.3 x 10^-5 Pa (25 °C)
Flash point:: 100 °C
storage temp.: 0-6°C
pka: -4.24±0.40(Predicted)
Water Solubility: 2 mg l^-1 (25 °C)

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Safety

Hazard Codes: Xn,N,F
Risk Statements: 40-51/53-67-65-50/53-38-11-20
Safety Statements: 36/37-61-62-60-33-25-16-9
RIDADR: UN3077 9/PG 3
WGK Germany: 2
HS Code: 29251900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H336May cause drowsiness or dizziness

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331Do NOT induce vomiting.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 33743
Product name: Chlozolinate solution
Purity: 100μg/mL in cyclohexane, PESTANAL
Packaging: 2ml
Price: $74.5
Updated: 2022/05/15

TRC

Product number: C989138
Product name: Chlozolinate
Packaging: 25mg
Price: $880
Updated: 2021/12/16

TRC

Product number: C989138
Product name: Chlozolinate
Packaging: 50mg
Price: $1680
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: PST0000442
Product name: CHLOZOLINATE
Purity: 98.00%
Packaging: 10MG
Price: $924
Updated: 2021/12/16

Crysdot

Product number: CD11048026
Product name: Ethyl3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxooxazolidine-5-carboxylate
Purity: 95+%
Packaging: 1g
Price: $972
Updated: 2021/12/16

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CHLOZOLINATE Chemical Properties,Usage,Production

Uses

Chlozolinate controls fruit rot, downy mildew and brown rot in pome and stone fruits, vines, vegetables, strawberries and ornamentals caused by Botrytis, Monilia and Sclerotinia, efc.

Uses

Chlozolinate is a dicarboximide fungicide which is used primarily on grapes.

Definition

ChEBI: Ethyl 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylate is the ethyl ester of 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylic acid. It is a dichlorobenzene, an oxazolidinone, a dicarboximide and an ethyl ester.

General Description

Chlozolinate is a systemic fungicide, used for the control of downy mildew, brown rot, and fruit rot in agricultural commodities.

Metabolic pathway

The fungicides, chlozolinate, vinclozolin, and procymidone, are added to wine after fermentation and the degradation products are isolated and identified. Chlozolinate undergoes a rapid hydrolytic loss of the ethoxycarbonyl substituent to give an oxazolidine that further undergoes hydrolytic cleavage to give 3' ,5' -dichloro-2-hydroxypropanilide. The oxazolidine ring of vinclozolin undergoes a similar hydrolysis reaction to give the corresponding anilide, 3' ,5'-dichloro-2-hydroxy-2-methylbut-3-eneanilide. Both of these anilides are stable in wine for 150 days. A different degradation behavior is observed with procymidone and leads to the formation of 3,5- dichloroaniline, which, in turn, breaks down in wine.

Degradation

Chlozolinate (1) hydrolysed rapidly at 25 °C in alkaline solution with DTm values of 6 hours (pH 6.8) and 16 min (pH 8.3). Three hydrolytic degradation reactions were observed. The first reaction involved the cleavage of the ethyl ester to yield the corresponding carboxylic acid (2). Compound 2 underwent decarboxylation to yield 3-(3,5-dichlorophenyl)-5-methyloxazolidine- 2,4-dione (3). The third reaction involved the opening of the oxazolidinedione ring to yield 3',5'-dichloro-2-hydroxypropanilide(4) (Villedieu et al., 1994,1995).
Chlozolinate degraded rapidly in wine during the vinification process (DT₅₀ 0.35 and 0.14 day at pH 3 and 4, respectively). Decarboxylation resulted in the formation of compound 3 as the major product (Cabras et al., 1984; Pirisi et al., 1986; Gennari et al., 1992).

CHLOZOLINATE Preparation Products And Raw materials

Raw materials

Preparation Products

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84332-86-5, CHLOZOLINATERelated Search:

Trifloxystrobin Chlorothalonil (R)-Chlozolinate

CHLOZOLINATE

SERINAL

ethyl (RS)-3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxooxazolidine-5-carboxylate

chlozolinate (bsi,iso)

ethyl 3-(3,5-dichlorophenyl)-5- methyl-2,4-dioxo-5-oxazolidinecarboxyate

chlozolinate (ISO) ethyl (RS)-3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-oxazolidine-5-carboxylate

Chlozolinate solution

5-Oxazolidinecarboxylic acid, 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-, ethyl ester, (+-)-

Chlozolinate [iso]

Einecs 282-714-4

Clozolinate

3-(3,5-Dichlorophenyl)-5-methyl-2,4-dioxo-5-oxazolidinecarboxylic acid ethyl ester

SDS 65311

ethyl(±) 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylate

Manderol

CHLORPICRIN PESTANAL (TRICHLORO- NITROME

CHLOZOLINATE PESTANAL.

(±)ethyl 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-5-oxazolidinecarboxylate

Chlozolinate 1

Chlozolinate solution,100ppm

Chlozolinate Standard

Chlozolinate@1000 μg/mL in Acetonitrile

Chlozolinate@100 μg/mL in Acetonitrile

ClozolinateSolution,10mg/L,1ml

Chlozolinate in Cyclohexane

C11665000 Chlozolinate

Chlozolinate 10.0 μg/ml Cyclohexane

XA11665000CY ChlozolinatE100μg/mLin Cyclohexa

84332-86-5

C13H11Cl2NO5