ChemicalBook > CAS DataBase List > Trimethyl(phenoxy)silane

Trimethyl(phenoxy)silane

Product Name
Trimethyl(phenoxy)silane
CAS No.
1529-17-5
Chemical Name
Trimethyl(phenoxy)silane
Synonyms
DK553;DKSI224;Phenol, TMS ether;PHENOXYTRIMETHYLSILANE;Trimethylphenoxysilane;trimethylphenoxy-silan;TRIMETHYLSILYLPHENOXIDE;trimethylphenoxy-Silane;trimethyl-phenoxy-silane;(Trimethylsiloxy)benzene
CBNumber
CB4402745
Molecular Formula
C9H14OSi
Formula Weight
166.29
MOL File
1529-17-5.mol
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Trimethyl(phenoxy)silane Property

Melting point:
-55 °C
Boiling point:
81 °C23 mm Hg(lit.)
Density 
0.92 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.478
Flash point:
127 °F
storage temp. 
Sealed in dry,Room Temperature
form 
liquid
Specific Gravity
0.92
color 
Colorless to Light orange to Yellow
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
λmax
274nm(Heptane)(lit.)
BRN 
1905943
InChIKey
OJAJJFGMKAZGRZ-UHFFFAOYSA-N
EPA Substance Registry System
Silane, trimethylphenoxy- (1529-17-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
26-36
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
F 
10-21
TSCA 
Yes
HazardClass 
3.2
PackingGroup 
III
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
380415
Product name
Trimethyl(phenoxy)silane
Purity
97%
Packaging
10ml
Price
$73.5
Updated
2023/06/20
TCI Chemical
Product number
T3222
Product name
Trimethyl(phenoxy)silane
Purity
>97.0%(GC)
Packaging
5mL
Price
$49
Updated
2024/03/01
TCI Chemical
Product number
T3222
Product name
Trimethyl(phenoxy)silane
Purity
>97.0%(GC)
Packaging
25mL
Price
$140
Updated
2024/03/01
Frontier Specialty Chemicals
Product number
JK494677
Product name
Phenoxytrimethylsilane
Purity
97%
Packaging
25g
Price
$143
Updated
2021/12/16
AK Scientific
Product number
9306AL
Product name
Trimethyl(phenoxy)silane
Packaging
25g
Price
$168
Updated
2021/12/16
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Trimethyl(phenoxy)silane Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid

Uses

Trimethyl(phenoxy)silane can be used as a catalyst for the Friedel-Crafts reaction, which is an organic reaction that converts alkenes into alcohols or epoxides. It can also reacts with hydrochloric acid to give phenol and chloroform. Trimethyl(phenoxy)silane has been shown to have chemical properties similar to those of phenol, such as viscosity, chemical species and resonance spectroscopy properties. It can react with oxygen in the air to form peroxides, so it should be stored in a cool, dry place away from light.

General Description

Trimethyl(phenoxy)silane is a trimethylsilyl protected alcohol. Direct lateral zincation (DlZn) of trimethyl(phenoxy)silane has been reported. Dielectric studies of phenoxysilane-phenol binary systems has been reported.

Synthesis

General procedure for trimethylsilylation of alcohols with HMDS catalyzed by P2O5/Al2O3. P2O5/Al2O3 (0.1 g) was added to a stirred solution of the alcohol (10 mmol) and HMDS (7.5 mmol) and the mixture was stirred at room temperature for the time specified in Table 2. The reaction was followed by TLC (n-hexane-EtOAc, 9:1). After completion of the reaction, ethyl acetate was added to the reaction mixture and the catalyst was isolated by filtration. It was washed well with ethyl acetate (2 9 5 ml) and then dried at 100°C for 2 h before being used again. The filtered solution was evaporated and purified by passage through a short column of silica gel with n-hexane as eluent (2 x 20 ml). Evaporation of the solvent under reduced pressure gave the pure product Trimethyl(phenoxy)silane, Yield; 89%.

Trimethyl(phenoxy)silane Preparation Products And Raw materials

Raw materials

Preparation Products

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Trimethyl(phenoxy)silane Suppliers

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View Lastest Price from Trimethyl(phenoxy)silane manufacturers

Hebei Mojin Biotechnology Co., Ltd
Product
Phenoxytrimethylsilane 1529-17-5
Price
US $50.00/KG
Min. Order
25KG
Purity
99%
Supply Ability
200ton
Release date
2021-05-11
henan kanbei chemical co.,ltd
Product
Trimethylphenoxysilane 1529-17-5
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-19
Career Henan Chemical Co
Product
PHENOXYTRIMETHYLSILANE 1529-17-5
Price
US $2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
customsie
Release date
2018-08-20

1529-17-5, Trimethyl(phenoxy)silaneRelated Search:

TRIMETHYLSILYL METHACRYLATE METHOXYTRIMETHYLSILANE ISOPROPENYLOXYTRIMETHYLSILANE (3-BROMOPHENOXY)TRIMETHYLSILANE 1-BROMO-3-(TERT-BUTYLDIMETHYLSILOXY)BENZENE Trimethyl(phenoxy)silane (4-BROMOPHENOXY)TRIMETHYLSILANE 2-(TRIMETHYLSILOXY)BENZALDEHYDE P-TRIMETHYLSILOXYNITROBENZENE 4-(TRIMETHYLSILOXY)BENZALDEHYDE 3-(TERT-BUTYLDIMETHYLSILOXY)THIOPHENOL CHLOROMETHYL(2-CHLOROPHENOXY)DIMETHYLSILANE (4-BROMOPHENOXY)-TERT-BUTYLDIMETHYLSILANE 1,3-BIS(CHLOROMETHYLDIMETHYLSILOXY)BENZENE 3,5-BIS(TERT-BUTYLDIPHENYLSILYLOXY)BENZOIC ACID METHYL ESTER 3-(T-BUTYLDIMETHYLSILOXY)IODOBENZENE CHLOROMETHYL(4-CHLOROPHENOXY)DIMETHYLSILANE BIS(TRIMETHYLSILYL)BISPHENOL A

  • Phenoxy(trimethyl)silane, Phenyl trimethylsilyl ether
  • trimethylphenoxy-silan
  • Trimethylphenoxysilane
  • trimethyl-phenoxy-silane
  • trimethylphenoxy-Silane
  • Trimethylsilyl phenyl ether
  • PHENOXYTRIMETHYLSILANE, 97+%
  • (Trimethylsilyl)oxybenzene
  • PHENYL TRIMETHYLSILYL ETHER
  • PHENOXYTRIMETHYLSILANE
  • TRIMETHYLSILYLPHENOXIDE
  • (Trimethylsiloxy)benzene
  • O-(Trimethylsilyl)phenol
  • Phenol trimethylsilyl ether
  • Phenol, TMS ether
  • Silane, trimethylphenoxy-
  • Trimethyl(Phenoxy)Silane,>94%
  • Benzene, [(trimethylsilyl)oxy]-
  • DK553
  • DKSI224
  • 1529-17-5
  • C6H5OSiCH33
  • Building Blocks
  • Protected Alcohols/Phenols
  • Oxygen Compounds
  • Organic Building Blocks
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
  • Oxygen Compounds
  • Protected Alcohols/Phenols