2-(2-Aminoethylamino)ethanol Property

Melting point:

-28 °C

Boiling point:

238-240 °C/752 mmHg (lit.)

Density 

1.03 g/mL at 25 °C (lit.)

vapor density 

3.6 (vs air)

vapor pressure 

<0.01 hPa (20 °C)

refractive index 

n20/D 1.485(lit.)

Flash point:

>230 °F

storage temp. 

Store below +30°C.

solubility 

soluble

pka

pK1:7.21(＋2);pK2:10.12(＋1) (25°C)

form 

Liquid

color 

Clear Colorless

Odor

mild ammoniacal odor

PH

11.8 (111g/l, H2O, 20℃)

explosive limit

3.3-10.1%(V)

Water Solubility 

soluble

Sensitive 

Hygroscopic

BRN 

506012

Exposure limits

NIOSH: TWA 0.1 mg/m3

Dielectric constant

18.989999999999998

InChIKey

LHIJANUOQQMGNT-UHFFFAOYSA-N

LogP

-2.2--1.46 at 20-25℃ and pH7-11

Surface tension

67.11mN/m at 1g/L and 20℃

Dissociation constant

6.83-9.82 at 25℃

CAS DataBase Reference

111-41-1(CAS DataBase Reference)

NIST Chemistry Reference

Ethanol, 2-[(2-aminoethyl)amino]-(111-41-1)

EPA Substance Registry System

N-Hydroxyethylethylenediamine (111-41-1)

Safety

Hazard Codes 

C,T

Risk Statements 

34-43-61-62

Safety Statements 

26-36/37/39-45-53-28A

RIDADR 

UN 2735 8/PG 2

WGK Germany 

1

RTECS 

KJ6300000

Autoignition Temperature

345 °C

TSCA 

Yes

HazardClass 

8

PackingGroup 

II

HS Code 

29221980

Hazardous Substances Data

111-41-1(Hazardous Substances Data)

Toxicity

LD50 orally in Rabbit: 3000 mg/kg LD50 dermal Rabbit > 2000 mg/kg

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H335May cause respiratory irritation

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

2-(2-Aminoethylamino)ethanol Chemical Properties,Usage,Production

Description

Aminoethylethanolamine is a component of colophony in soldering flux, which may cause contact and airborne contact dermatitis in workers in the electronic industry or in cable jointers.

Chemical Properties

Aminoethylethanolamine is combustible, colorless, liquid with an ammonia-like odor.

Chemical Properties

CLEAR VISCOUS LIQUID

Uses

Textile finishing compounds (antifuming agents, dyestuffs, cationic surfactants), resins, rubber products, insecticides, and certain medicinals.

Uses

It is used as an important intermediate in the manufacture of lube oil additives, fuel additives, chelating agents, surfactants and fabric softeners among other applications. N-(2-Hydroxyethyl)ethylenediamine [N-(2-Aminoethyl)ethanolamine] is used to study the aerobic biodecomposition of amines in hypersaline wastewaters.

Uses

N-(2-hydroxyethyl)ethylenediamine (hydeten) or [N-(2-aminoethyl)ethanolamine] can be used as:

• A precursor in the synthesis of room-temperature ionic liquids, acetate and formate ammonium salts of N-(2-hydroxyethyl)-ethylenediamine.
• A ligand in the preparation of polymeric cyano-bridged platinum(II)complexes, ligand-copper(II)carbohydrate complexes and cyano-bridged Ni-Pt and Cu-Pt coordination polymers.

General Description

A clear colorless liquid with an ammonia-like odor. Corrosive to tissue. Combustible, but may be difficult to ignite. Less dense than water. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion. Used to make other chemicals.

Air & Water Reactions

Water soluble. Hygroscopic.

Reactivity Profile

2-(2-Aminoethylamino)ethanol is an amine and alcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. 2-(2-Aminoethylamino)ethanol is hygroscopic.

Health Hazard

Skin contact will cause mild irritation; eye contact will cause more severe irritation.

Fire Hazard

2-(2-Aminoethylamino)ethanol is combustible.

Contact allergens

Aminoethylethanolamine is a component of colophony in soldering flux, which may cause contact and airborne contact dermatitis in workers in the electronic industry or cable jointers.

Potential Exposure

Used to make textile finishing compounds, dyes, resins, rubber, insecticides, medicines, and oth

Shipping

UN2735 Amines, liquid, corrosive, n.o.s, or Polyamines, liquid, corrosive, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.

Purification Methods

Distil the amine twice through a Vigreux column (p 11). Redistil it from solid NaOH, then from CaH2. Alternatively, it can be converted to the dihydrochloride and recrystallised from water. It is then dried, mixed with excess of solid NaOH and the free base is distilled from the mixture. It is finally redistilled from CaH2. [Drinkard et al. J Am Chem Soc 82 2992 1960, Beilstein 4 IV 1558.]

Incompatibilities

Contact with cellulose nitrate may cause fires upon contact. Reacts with Oxidizers, strong acids.