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1-Naphthylacetonitrile

Product Name
1-Naphthylacetonitrile
CAS No.
132-75-2
Chemical Name
1-Naphthylacetonitrile
Synonyms
ANNAFOMINA;1-NAPHTHALENEACETO;1-Naphthyl acetonitr;1-Naphtylacetonitrile;1-phthyl acetonitrile;LABOTEST-BB LTBB001326;a-naphthylacetonitrile;1-NAPHTHYLACETONITRILE;Naphazoline Impurity C;1-NAPHTHYLMETHYLCYANIDE
CBNumber
CB4416463
Molecular Formula
C12H9N
Formula Weight
167.21
MOL File
132-75-2.mol
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1-Naphthylacetonitrile Property

Melting point:
33-35 °C(lit.)
Boiling point:
191-194 °C18 mm Hg(lit.)
Density 
1.1110 (rough estimate)
refractive index 
n20/D 1.6192(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Sparingly), Dichloromethane (Slightly), Methanol (Slightly)
form 
Liquid After Melting
color 
Clear yellow to brown
BRN 
1101012
CAS DataBase Reference
132-75-2(CAS DataBase Reference)
NIST Chemistry Reference
1-Naphthaleneacetonitrile(132-75-2)
EPA Substance Registry System
1-Naphthaleneacetonitrile (132-75-2)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-22
Safety Statements 
26-37/39-24/25-37-36
RIDADR 
3276
WGK Germany 
3
RTECS 
AM1240000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29269090
Toxicity
mouse,LD50,intravenous,180mg/kg (180mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03835,
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
N0366
Product name
1-Naphthylacetonitrile
Purity
>98.0%(GC)
Packaging
25g
Price
$70
Updated
2024/03/01
TCI Chemical
Product number
N0366
Product name
1-Naphthylacetonitrile
Purity
>98.0%(GC)
Packaging
500g
Price
$556
Updated
2024/03/01
Alfa Aesar
Product number
L06696
Product name
1-Naphthylacetonitrile, 97%
Packaging
5g
Price
$20.65
Updated
2024/03/01
Alfa Aesar
Product number
L06696
Product name
1-Naphthylacetonitrile, 97%
Packaging
25g
Price
$48.65
Updated
2024/03/01
Alfa Aesar
Product number
L06696
Product name
1-Naphthylacetonitrile, 97%
Packaging
100g
Price
$111.65
Updated
2024/03/01
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1-Naphthylacetonitrile Chemical Properties,Usage,Production

Chemical Properties

White to yellow solid or melt. Insoluble in water.

Uses

2-(Naphthalen-1-yl)acetonitrile is useful for the preparation of tert-Bu benzoates.

Preparation

Synthesis of 1-naphthylacetonitrile: 695g of 1-chloromethyl naphthalene, 1500ml of methanol and 475ml of water, 350g of sodium cyanide mixture boiling reflux, stirring the reaction for 2h. 1300ml of methanol was evaporated, cooled, and the reactants were washed with water to neutral to obtain 670-680g of 1-naphthylacetonitrile.

Application

1-Naphthylacetonitrile is an organic synthesis intermediate. It is used in the synthesis of 1-naphthylacetate.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 39, p. 3030, 1991 DOI: 10.1248/cpb.39.3030

1-Naphthylacetonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Naphthylacetonitrile Suppliers

TCI Chemicals (India) Pvt. Ltd.
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View Lastest Price from 1-Naphthylacetonitrile manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
1-Naphthylacetonitrile 132-75-2
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-25
Hebei Weibang Biotechnology Co., Ltd
Product
1-Naphthylacetonitrile 132-75-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-29
Hebei Mojin Biotechnology Co., Ltd
Product
1-Naphthylacetonitrile 132-75-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99.7%
Supply Ability
50000KG/month
Release date
2024-10-23

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