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ChemicalBook > CAS DataBase List > BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE

BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE

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Product Name
BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE
CAS No.
219770-99-7
Chemical Name
BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE
Synonyms
thio)methyL;ene]ruthenium(II) dichL;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II);dichloro-(phenylsulfanylmethylene)ruthenium, tricyclohexylph...;Dichloro[(phenylthio)methylene]bis(tricyclohexylphosphine)ruthenium;dichloro(phenylsulfanylmethylidene)ruthenium,tricyclohexylphosphane;dichloro-(phenylsulfanylmethylene)ruthenium, tricyclohexylphosphane;BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium (II) dichloride;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(IV) dichloride,97%
CBNumber
CB4418472
Molecular Formula
C43H72Cl2P2RuS
Formula Weight
855.02
MOL File
219770-99-7.mol
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BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Property

form 
Powder
color 
purple
EPA Substance Registry System
Ruthenium, dichloro[(phenylthio)methylene]bis(tricyclohexylphosphine)- (219770-99-7)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H228Flammable solid

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P370+P378In case of fire: Use … for extinction.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Strem Chemicals
Product number
44-0073
Product name
Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%
Packaging
1g
Price
$93
Updated
2021/12/16
Strem Chemicals
Product number
44-0073
Product name
Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%
Packaging
5g
Price
$371
Updated
2021/12/16
Crysdot
Product number
CD52000479
Product name
Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)dichloride
Purity
97%
Packaging
1g
Price
$772
Updated
2021/12/16
Chemenu
Product number
CM102929
Product name
Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)dichloride
Purity
97%
Packaging
5g
Price
$880
Updated
2021/12/16
Chemenu
Product number
CM102929
Product name
Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)dichloride
Purity
97%
Packaging
1g
Price
$220
Updated
2021/12/16
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BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Chemical Properties,Usage,Production

Reactions

  1. Metathesis catalyst, stable in air and can be used in aqueous media.
  2. Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins.
  3. Catalyst concentration 2-3 times lower than comparable phenyl and vinyl substituted ruthenium carbenes.
  4. Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times.
  5. Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives.

BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Suppliers

Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
Alfa Chemistry
Tel
--
Fax
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Email
info@Alfa-Chemistry.com
Country
United States
ProdList
6814
Advantage
0
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87

219770-99-7, BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDERelated Search:


  • Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)dichloride,min.97%
  • Bis(tricyclohexylphosphine)[(phenylthio)Methylene]rutheniuM (II) dichloride,97%
  • Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%
  • Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(IV) dichloride,97%
  • Dichloro[(phenylthio)methylene]bis(tricyclohexylphosphine)ruthenium
  • Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium (II) dichloride
  • BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE
  • Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)
  • dichloro(phenylsulfanylmethylidene)ruthenium,tricyclohexylphosphane
  • ene]ruthenium(II) dichL
  • thio)methyL
  • dichloro-(phenylsulfanylmethylene)ruthenium, tricyclohexylphosphane
  • dichloro-(phenylsulfanylmethylene)ruthenium, tricyclohexylph...
  • 219770-99-7
  • RuCl2CHSC6H5PC6H1132
  • C43H72Cl2P2RuS
  • metal-phosphine complexes
  • Ru