2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE

Product Name: 2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE
CAS No.: 3292-77-1
Chemical Name: 2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE
Synonyms: 2-(Bromoacetyl)-1,3-thiazole;2-Bromo-1-thiazol-2-yl-ethanone;2-BroMo-1-(2-thiazolyl)-ethanone;2-(Bromoacetyl)-1,3-thiazole 97+%;2-(Bromoacetyl)-1,3-thiazole 95+%;Ethanone, 2-bromo-1-(2-thiazolyl)-;2-bromo-1-(thiazol-2-yl)ethan-1-one;2-bromo-2-(2-thiazolyl)acetaldehyde;2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE;2-Bromo-1-(1,3-thiazol-2-yl)ethan-1-one
CBNumber: CB4427605
Molecular Formula: C5H4BrNOS
Formula Weight: 206.06
MOL File: 3292-77-1.mol

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2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE Property

Melting point:: 54-55
Boiling point:: 266.7±42.0 °C(Predicted)
Density: 1.763±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Acetonitrile (Slightly), Chloroform (Sparingly)
form: Solid
pka: -0.40±0.10(Predicted)
color: Orange to Dark Orange
Stability:: Light Sensitive, Moisture Sensitive

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Safety

Hazard Codes: C,Xn
Risk Statements: 34-22
Safety Statements: 22-26-36/37/39-45
Hazard Note: Corrosive
HazardClass: IRRITANT
HS Code: 2934100090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B688408
Product name: 2-Bromo-1-(1,3-thiazol-2-yl)ethanone
Packaging: 250mg
Price: $45
Updated: 2021/12/16

Ark Pharm

Product number: P000665065
Product name: 2-Bromo-1-(thiazol-2-yl)ethanone
Purity: 95%
Packaging: 100mg
Price: $18
Updated: 2021/12/16

Ark Pharm

Product number: P000665065
Product name: 2-Bromo-1-(thiazol-2-yl)ethanone
Purity: 95%
Packaging: 250mg
Price: $27
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: B13372
Product name: 2-Bromo-1-(thiazol-2-yl)ethanone
Purity: 95%
Packaging: 1g
Price: $30
Updated: 2021/12/16

ChemScene

Product number: CS-D0891
Product name: 2-(Bromoacetyl)-1,3-thiazole
Purity: ≥98.0%
Packaging: 1g
Price: $50
Updated: 2021/12/16

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2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE Chemical Properties,Usage,Production

Synthesis

24295-03-2

3292-77-1

Step A: A solution of 1-thiazol-2-ylacetophenone (2.00 g, 15.7 mmol) in anhydrous THF (8 mL) was slowly added dropwise to a solution of 97% tribromophenyltrimethylammonium (6.08 g, 15.7 mmol) in anhydrous THF (32 mL). The reaction mixture was heated at 35 °C with stirring for 3 h, followed by standing overnight. After completion of the reaction, the solid was removed by filtration and the filtrate was concentrated under reduced pressure to give the crude product. The crude product was dissolved in dichloromethane (CH2Cl2) and purified by silica gel column chromatography (eluent: 20/80 ethyl acetate/petroleum ether) to afford 2-bromo-1-thiazol-2-ylacetophenone (2.85 g, 88% yield) as a solidified oil.1H-NMR (CDCl3) δ: 8.03 (d, 1H, J = 2.8 Hz, -S-CH=CH-N=); 7.75 (d, 1H, J = 2.8 Hz, -S-CH=CH-N=); 7.75 (d, 1H, J = 2.8 Hz, -S-CH=CH-N=). ); 7.75 (d, 1H, J = 2.8 Hz, -S-CH=CH*-N=); 4.70 (s, 2H, CH2).

References

[1] Patent: US6468979, 2002, B1
[2] Bioorganic and Medicinal Chemistry, 2010, vol. 18, # 3, p. 1093 - 1102
[3] Patent: CN107629022, 2018, A. Location in patent: Paragraph 0534; 0535; 0536; 0537
[4] Helvetica Chimica Acta, 1948, vol. 31, p. 1142,1156
[5] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 15, p. 4374 - 4377

2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE Suppliers

Belgium 1 China 80 Europe 1 Germany 1 India 1 United Kingdom 5 United States 17 Global 106

J & K SCIENTIFIC LTD.

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View Lastest Price from 2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE 3292-77-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20T
Release date: 2024-07-11

Career Henan Chemical Co

Product: 2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE 3292-77-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-07-04

3292-77-1, 2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONERelated Search:

2-BROMO-1-(2-(TRIFLUOROMETHYL)THIAZOL-5-YL)ETHANONE 1-(1,3-Benzothiazol-2-yl)-2-bromo-1-ethanone 2-BROMO-1-(1,3-THIAZOL-2-YL)-1-ETHANONE HYDROBROMIDE 2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE

2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE

2-(Bromoacetyl)-1,3-thiazole

2-Bromo-1-(1,3-thiazol-2-yl)ethan-1-one

Ethanone, 2-bromo-1-(2-thiazolyl)- (9CI)

2-(Bromoacetyl)-1,3-thiazole 97+%

2-bromo-1-(1,3-thiazol-2-yl)-1-ethanone

2-Bromo-1-thiazol-2-yl-ethanone

2-BroMo-1-(2-thiazolyl)-ethanone

2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE HBr salt

2-Bromo-1-(1,3-thiazol-2-yl)ethan-1-one, 2-(1-Bromoethanoyl)-1,3-thiazole

2-bromo-1-(thiazol-2-yl)ethan-1-one

2-bromo-2-(2-thiazolyl)acetaldehyde

2-(Bromoacetyl)-1,3-thiazole 95+%

Ethanone, 2-bromo-1-(2-thiazolyl)-

3292-77-1

Acetyl Halides

Thiazoles, Isothiazoles & Benzothiazoles

ACETYLHALIDE

Acetyl Halides

Thiazoles, Isothiazoles &Benzothiazoles