CYCLOPENTADIENYLVANADIUM TETRACARBONYL

CYCLOPENTADIENYLVANADIUM TETRACARBONYL Property

Melting point:

138°C

Boiling point:

80-110°C 0,1mm

Flash point:

80-100°C/0.1mm subl.

solubility 

sol benzene, 1,2-dichloroethane, THF; slightly sol hexane.

form 

crystal

color 

orange to red

Water Solubility 

Insoluble in water.

Sensitive 

Air Sensitive

Exposure limits

NIOSH: Ceiling 0.05 mg/m3

Safety

Risk Statements 

23/24/25

Safety Statements 

26-28-36/37/39-45

RIDADR 

3285

HazardClass 

6.1

PackingGroup 

II

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Hazard statements

H300Fatal if swallowed

H310Fatal in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H330Fatal if inhaled

H335May cause respiratory irritation

Precautionary statements

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P320Specific treatment is urgent (see … on this label).

P330Rinse mouth.

P405Store locked up.

CYCLOPENTADIENYLVANADIUM TETRACARBONYL Chemical Properties,Usage,Production

Uses

Employed as pharmaceutical intermediates.

Uses

Tetracarbonylcyclopentadienylvanadium is used as a catalyst for stereoselective alkene oxidation; forms an anionic hydride complex which reduces dibromides; reacts with alkynes to form cyclic ketones.

storage

CYCLOPENTADIENYLVANADIUM TETRACARBONYL is stored and handled in an inert atmosphere.