Reaction
ChemicalBook > CAS DataBase List > (R)-VAPOL

(R)-VAPOL

Reaction
Product Name
(R)-VAPOL
CAS No.
147702-16-7
Chemical Name
(R)-VAPOL
Synonyms
(S)-VAPOL;(R)-VAPOL;(R)-VAPOL 97%;(R)-VAPOL,99%e.e.;(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL);(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL);(R) -2,2'--diphenyl-3,3 '- (4-phenanthrenol;(3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol;(3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol;(3R)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
CBNumber
CB4450751
Molecular Formula
C40H26O2
Formula Weight
538.63
MOL File
147702-16-7.mol
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(R)-VAPOL Property

Melting point:
225-229 °C
alpha 
-123.4° (c 1.0, THF)
Boiling point:
712.2±60.0 °C(Predicted)
Density 
1.286±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
8.37±0.30(Predicted)
form 
Powder
color 
white to pale yellow
optical activity
[α]20/D -144°, c = 1 in chloroform
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Safety

Hazard Codes 
Xn
Risk Statements 
37/38-40-41
Safety Statements 
26-36/37/39
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
675210
Product name
(R)-VAPOL
Purity
97%
Packaging
100mg
Price
$55.6
Updated
2024/03/01
Sigma-Aldrich
Product number
675210
Product name
(R)-VAPOL
Purity
97%
Packaging
500mg
Price
$264.8
Updated
2024/03/01
Strem Chemicals
Product number
08-1704
Product name
(3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (R)-VAPOL
Packaging
100mg
Price
$255
Updated
2024/03/01
Strem Chemicals
Product number
08-1704
Product name
(3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (R)-VAPOL
Packaging
500mg
Price
$1021
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
HCH0009280
Product name
(3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
Purity
95.00%
Packaging
500MG
Price
$1109.06
Updated
2021/12/16
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(R)-VAPOL Chemical Properties,Usage,Production

Reaction

  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric imino aldol reaction.
  3. Chiral ligand used in catalytic asymmetric Petasis reaction. 

Uses

VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(R)-VAPOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-VAPOL Suppliers

ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75

147702-16-7, (R)-VAPOLRelated Search:


  • (R)-VAPOL 97%
  • (R)-VAPOL,99%e.e.
  • (S)-2,2'-DIPHENYL-(4-BIPHENANTHROL)
  • (R)-VAPOL
  • (S)-VAPOL
  • (R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL)
  • (3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
  • (3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
  • (3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-dioldichloromethaneadduct,min.98%(R)-VAPOL
  • (3R)-(-)-2,2''-DIPHENYL-[3,3''-BIPHENANTHRENE]-4,4''-DIOL DICHLOROMETHANE ADDUCT (R)-VAPOL
  • (R) -2,2'--diphenyl-3,3 '- (4-phenanthrenol
  • (3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol
  • 3,3'-Biphenanthrene]-4,4'-diol, 2,2'-diphenyl-, (3R)-
  • (3R)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
  • (3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol
  • (3R)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
  • 147702-16-7
  • C40H26O212CH2Cl2
  • BINOL Series
  • Chiral Oxygen