di(4-t-butylphenyl)iodonium camphorsulfonate
- Product Name
- di(4-t-butylphenyl)iodonium camphorsulfonate
- CAS No.
- 193345-23-2
- Chemical Name
- di(4-t-butylphenyl)iodonium camphorsulfonate
- Synonyms
- DTBPI-CS;di(4-t-butylphenyl)iodonium camphorsulfonate;Bis(tert-butylphenyl)iodonium 10-camphorsulfonate;Bis-(4-tert-butylphenyl)-iodonium 10-camphorsulfonate;Iodonium, bis[4-(1,1-dimethylethyl)phenyl]-, 7,7-dimethyl-2-...;Iodonium, bis[4-(1,1-dimethylethyl)phenyl]-, 7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonate C;Iodonium, bis[4-(1,1-dimethyl- ethyl)phenyl]-, 7,7-dimethyl- 2-oxobicyclo[2.2.1]heptane-1-methanesulfonate (1:1)
- CBNumber
- CB44775643
- Molecular Formula
- C30H41IO4S
- Formula Weight
- 624.62
- MOL File
- 193345-23-2.mol
di(4-t-butylphenyl)iodonium camphorsulfonate Property
- InChI
- InChI=1S/C20H26I.C10H16O4S/c1-19(2,3)15-7-11-17(12-8-15)21-18-13-9-16(10-14-18)20(4,5)6;1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7-14H,1-6H3;7H,3-6H2,1-2H3,(H,12,13,14)/q+1;/p-1
- InChIKey
- MDUKBVGQQFOMPC-UHFFFAOYSA-M
- SMILES
- [I+](C1=CC=C(C(C)(C)C)C=C1)C1=CC=C(C(C)(C)C)C=C1.C(S([O-])(=O)=O)C12C(C)(C)C(CC1)CC2=O
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H318Causes serious eye damage
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P330Rinse mouth.
P501Dispose of contents/container to..…
di(4-t-butylphenyl)iodonium camphorsulfonate Chemical Properties,Usage,Production
Synthesis
Ethyl acetate (50 ml) was added to bis(p-tert-butylphenyl)iodonium acetate (467 mg, 1 mmol) and methyl camphorsulfonate (259 mg, 1.05 mmol). The resultant mixture was refluxed for 24 hours while being stirred. The reaction mixture was cooled, and formed solid was removed through filtration. The solid was recrystallized from acetone, and dried under vacuum, to thereby yield 518 mg of bis(p-tert-butylphenyl)iodonium camphorsulfonate (di(4-t-butylphenyl)iodonium camphorsulfonate) (yield: 83%).
di(4-t-butylphenyl)iodonium camphorsulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
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