TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)GADO& Property

Melting point:

67-90 °C(lit.)

Flash point:

36 °F

form 

solid

Water Solubility 

Soluble in water.

Sensitive 

Moisture Sensitive

Hydrolytic Sensitivity

8: reacts rapidly with moisture, water, protic solvents

Safety

Hazard Codes 

F,C

Risk Statements 

11-14/15-34

Safety Statements 

16-26-36/37/39-43-45-7/8

RIDADR 

UN 3396 4.3/PG 2

WGK Germany 

3

HazardClass 

4.1

PackingGroup 

III

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

H261In contact with water releases flammable gas

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)GADO& Chemical Properties,Usage,Production

Uses

Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) is used in many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome.

General Description

Atomic number of base material: 64 Gadolinium