4-BROMO-4'-(DIPHENYLAMINO)BIPHENYL
- Product Name
- 4-BROMO-4'-(DIPHENYLAMINO)BIPHENYL
- CAS No.
- 202831-65-0
- Chemical Name
- 4-BROMO-4'-(DIPHENYLAMINO)BIPHENYL
- Synonyms
- K0063;CAS:202831-65-0;4-Bromo-4'-(diphenylamino)biphenyl;4-Bromo-4'-(diphenylamino)biphenyl;4-BROMO-4`-(DIPHENYLLAMINO)BIPHENYL;(4'-BROMOBIPHENYL-4-YL)DIPHENYLAMINE;4-(4-bromophenyl)-N,N-diphenylaniline;4'-broMo-N,N-diphenylbiphenyl-4-aMine;4'-Bromo-N,N-diphenyl-4-biphenylamine;(4'-bromobiphenyl-4-yl)-diphenylamine
- CBNumber
- CB4500715
- Molecular Formula
- C24H18BrN
- Formula Weight
- 400.31
- MOL File
- 202831-65-0.mol
4-BROMO-4'-(DIPHENYLAMINO)BIPHENYL Property
- Melting point:
- 127.0 to 131.0 °C
- Boiling point:
- 518.2±33.0 °C(Predicted)
- Density
- 1.325
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- powder to crystal
- pka
- -3.34±0.60(Predicted)
- color
- White to Orange to Green
Safety
- HS Code
- 29214990
N-Bromosuccinimide Price
- Product number
- B2844
- Product name
- 4-Bromo-4'-(diphenylamino)biphenyl
- Purity
- >93.0%(GC)
- Packaging
- 1g
- Price
- $440
- Updated
- 2025/07/31
- Product number
- B2844
- Product name
- 4-Bromo-4'-(diphenylamino)biphenyl
- Purity
- >93.0%(GC)
- Packaging
- 250mg
- Price
- $160
- Updated
- 2025/07/31
- Product number
- B506040
- Product name
- 4''-Bromo-N,N-diphenyl-[1,1''-biphenyl]-4-amine
- Packaging
- 2.5mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- FB62273
- Product name
- 4-Bromo-4'-(diphenylamino)biphenyl
- Packaging
- 25mg
- Price
- $43
- Updated
- 2021/12/16
- Product number
- FB62273
- Product name
- 4-Bromo-4'-(diphenylamino)biphenyl
- Packaging
- 50mg
- Price
- $74
- Updated
- 2021/12/16
4-BROMO-4'-(DIPHENYLAMINO)BIPHENYL Chemical Properties,Usage,Production
Synthesis
589-87-7
201802-67-7
202831-65-0
Example 1.13.1 Synthesis of 4'-bromo-N,N-diphenyl-[1,1'-biphenyl]-4-amine (35): (4-(diphenylamino)phenyl)boronic acid (1.5 g, 5.19 mmol), 4-iodo-1-bromobenzene (1.33 g, 4.71 mmol), Na2CO3 (1.78 g, 16.8 mmol) and Pd(PPh3 )4 (0.163 g, 0.141 mmol) were dissolved in THF/H2O (28 mL/17 mL) mixed solvent. The reaction mixture was degassed and heated to reflux under argon protection overnight. After completion of the reaction, it was cooled to room temperature and the mixture was poured into dichloromethane (150 mL) and washed sequentially with water (2 x 150 mL) and brine (100 mL). The organic phase was dried with Na2SO4, filtered and purified by fast column chromatography (silica gel, hexane/ethyl acetate 50:1), and finally recrystallized in a solvent mixture of dichloromethane/methanol to give a white solid product (compound 35) (1.64 g, 87% yield).
References
[1] Journal of Organic Chemistry, 2017, vol. 82, # 18, p. 9435 - 9451
[2] Patent: US2010/326526, 2010, A1
[3] Patent: WO2011/8560, 2011, A1. Location in patent: Page/Page column 47-48
[4] RSC Advances, 2015, vol. 5, # 41, p. 32298 - 32306
[5] Patent: US9172051, 2015, B2. Location in patent: Page/Page column 67; 68; 69; 70; 71; 72; 75; 76
4-BROMO-4'-(DIPHENYLAMINO)BIPHENYL Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-BROMO-4'-(DIPHENYLAMINO)BIPHENYL manufacturers
- Product
- 4-Bromo-4'-(diphenylamino)biphenyl 202831-65-0
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-16
- Product
- 4'-Bromo-N,N-diphenyl-4-biphenylamine 202831-65-0
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-30
- Product
- 4-BROMO-4'-(DIPHENYLAMINO)BIPHENYL 202831-65-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98.0% min
- Supply Ability
- 1000kg
- Release date
- 2023-04-05