GERMANIUM(IV) ETHOXIDE

Product Name: GERMANIUM(IV) ETHOXIDE
CAS No.: 14165-55-0
Chemical Name: GERMANIUM(IV) ETHOXIDE
Synonyms: GERMANIUM ETHYLATE;GERMANIUM ETHOXIDE;TETRAETHOXYGERMANE;TETRAETHYOXYGERMANE;Ethyl germanate(IV);Ethyl orthogermanate;TETRAETHOXYGERMANIUM;GermaniumEthylsulfate;Germanium(IV)-ethylat;TETRAMETHOXYGERMANIUM
CBNumber: CB4683885
Molecular Formula: C8H20GeO4
Formula Weight: 252.88
MOL File: 14165-55-0.mol

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GERMANIUM(IV) ETHOXIDE Property

Melting point:: -72°C
Boiling point:: 185-6°C
Density: 1.14 g/mL at 25 °C(lit.)
refractive index: n20/D 1.407(lit.)
Flash point:: 121 °F
form: Liquid
color: Colorless
Specific Gravity: 1.134
Water Solubility: Soluble in anhydrous alcohol and benzene. Hydrolyzes in water
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
BRN: 3661173
CAS DataBase Reference: 14165-55-0(CAS DataBase Reference)
EPA Substance Registry System: Ethanol, germanium(4+) salt (14165-55-0)

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Safety

Hazard Codes: T,Xi
Risk Statements: 10-36/37/38-23/24/25
Safety Statements: 26-36-45-36/37/39-27-16
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
F: 10-21
TSCA: Yes
HazardClass: 3
PackingGroup: III
HS Code: 2905190019

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 339180
Product name: Germanium(IV) ethoxide
Purity: ≥99.95% trace metals basis
Packaging: 5g
Price: $184
Updated: 2024/03/01

Sigma-Aldrich

Product number: 339180
Product name: Germanium(IV) ethoxide
Purity: ≥99.95% trace metals basis
Packaging: 25g
Price: $614
Updated: 2024/03/01

Alfa Aesar

Product number: 014679
Product name: Germanium(IV) ethoxide, 97%
Packaging: 5g
Price: $132
Updated: 2024/03/01

Alfa Aesar

Product number: 014679
Product name: Germanium(IV) ethoxide, 97%
Packaging: 1g
Price: $38.6
Updated: 2023/06/20

Strem Chemicals

Product number: 93-3206
Product name: Germanium(IV) ethoxide (99.99+%-Ge) PURATREM
Packaging: 1g
Price: $45
Updated: 2024/03/01

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GERMANIUM(IV) ETHOXIDE Chemical Properties,Usage,Production

Chemical Properties

Water-clear liquid. B.p. 186°C. Hydrolyzes easily, yielding GeO2.

Uses

It is a sol-gel intermediate for optical fibers and photosensitive.

Preparation

A solution of 9.8 g. of metallic sodium in a considerable excess of absolute alcohol is prepared. A solution of 20 g. of GeCl4 in absolute ether is added with stirring and exclusion of moisture. The mixture is refluxed for several hours and then decanted from the NaCl which separates. The solid is washed with absolute ether. The washings are combined with the main solution and the solvent is then driven off in vacuum. Finally, the tetraethoxygermane is distilled. It is redistilled at atmospheric pressure.

Purification Methods

Distil it through a 10cm Vigreux column (p 11) under reduced pressure. Alternatively distil it through a Fenske glass helices (p 11) column fitted with a total condensation variable take-off stillhead. Fractionate it under reduced pressure using a reflux ratio of 10:1. [Johnson & Fritz J Am Chem Soc 75 718 1953, Bradley J Chem Soc 4916 1956, Beilstein 1 IV 1308.]

GERMANIUM(IV) ETHOXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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GERMANIUM(IV) ETHOXIDE Suppliers

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14165-55-0, GERMANIUM(IV) ETHOXIDERelated Search:

ANTIMONY(III) ETHOXIDE TETRAETHYLGERMANE GERMANIUM TETRAIODIDE GERMANIUM (II) SULFIDE TRIETHYLGERMANIUM CHLORIDE DIMETHYLGERMANIUM DICHLORIDE TRIMETHYLGERMANIUM CHLORIDE Tetramethylgermane TRIPHENYLGERMANIUM CHLORIDE TETRA-N-BUTYLGERMANE GERMANIUM TETRABROMIDE Yttria stabilized zirconia Germanium GERMANIUM(IV) ETHOXIDE GERMANIUM(IV) ISOPROPOXIDE TETRA-N-BUTOXYGERMANE GERMANIUM TETRA-SEC-BUTOXIDE GERMANIUM TETRA-I-BUTOXIDE

GERMANIUM ETHOXIDE

GERMANIUM ETHYLATE

GERMANIUM(IV) ETHOXIDE

GERMANIUM TETRAETHOXIDE

Germanium(IV)ethoxide, 99.95+%

TETRAETHYOXYGERMANE

Germanium(IV) ethoxide, 99.995% (metals basis)

Orthogermanic acid tetraethyl ester

Tetraethoxygermanium(IV)

germanium(Ⅳ) ethoxide

GermaniumEthylsulfate

ethanol,germanium(4+)salt

Germanium(IV) Ethoxide 98%

Ethyl alcohol germanium(4+) salt

Ethyl germanate(IV)

Ethyl orthogermanate

Germanium(IV) ethoxide/ 99.995%

TETRAETHOXYGERMANE, 99.999%

Germanium(IV) ethoxide >=99.95% trace metals basis

Germanium(IV) ethoxide, 99.9995% trace metals basis

germanicacidtetraethylester

Germanium(IV)-ethylat

tetraethylorthogermanate

TETRAETHOXYGERMANE

TETRAETHOXYGERMANIUM

TETRAMETHOXYGERMANIUM

Germanium (IV) ethoxide (99.99+%-Ge) PURATREM

Germanium(IV) ethylate~Tetraethoxygermanium

Germaniumethoxidemetalsbasiscolorlessliq

GermaniumethoxideTetraethoxygermane

germanium(4+) ethanolate

Germanium(IV) ethoxide, 99.95+% metals basis

Germanium(Ⅳ) Ethoxide, 99.9%

GERMANIUM(IV) ETHOXIDE ISO 9001：2015 REACH

Germanium(IV) ethoxide, 97%,

14165-55-0

4C2H5OGe

C8H20GeO4

C8H20O4Ge

GeOC2H54

C2H6O14Ge

Catalysis and Inorganic Chemistry

metal alkoxide