Classification Applications Reactions
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Bathophenanthroline

Classification Applications Reactions
Product Name
Bathophenanthroline
CAS No.
1662-01-7
Chemical Name
Bathophenanthroline
Synonyms
BPHEN;4,7-DIPHENYL-1,10-PHENANTHROLINE;Bathophen;1,10-Phenanthroline, 4,7-diphenyl-;bathophenanthrolin;Bathophenantroline;1,10-bathophenanthroline;4,7-Diphenyl-1,1-phenanthroline;BathophenanthroL;TIMTEC-BB SBB008862
CBNumber
CB4707550
Molecular Formula
C24H16N2
Formula Weight
332.4
MOL File
1662-01-7.mol
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Bathophenanthroline Property

Melting point:
218-220 °C(lit.)
Boiling point:
459.52°C (rough estimate)
Density 
1.2047 (rough estimate)
refractive index 
1.7620 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in organic solvents. Slightly soluble in acidic aqueous solutions. Insoluble in neutral or alkaline solutions.
pka
4.83±0.10(Predicted)
form 
Crystalline Powder, Crystals or Crystalline Mass
color 
White to yellow to pinkish
BRN 
261048
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
DHDHJYNTEFLIHY-UHFFFAOYSA-N
CAS DataBase Reference
1662-01-7(CAS DataBase Reference)
NIST Chemistry Reference
1,10-Phenanthroline, 4,7-diphenyl-(1662-01-7)
EPA Substance Registry System
1,10-Phenanthroline, 4,7-diphenyl- (1662-01-7)
Absorption
λmax?272 nm (in THF)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
22-24/25-36-26
WGK Germany 
3
RTECS 
SF8427000
F 
8
TSCA 
Yes
HS Code 
29339990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
11880
Product name
Bathophenanthroline
Purity
for spectrophotometric det. of Fe in serum, ≥99.0%
Packaging
1g
Price
$61.6
Updated
2024/03/01
Sigma-Aldrich
Product number
11880
Product name
Bathophenanthroline
Purity
for spectrophotometric det. of Fe in serum, ≥99.0%
Packaging
5G
Price
$618
Updated
2024/03/01
Sigma-Aldrich
Product number
1.24513
Product name
Bathophenanthroline
Purity
GR for analysis
Packaging
1g
Price
$341
Updated
2022/05/15
TCI Chemical
Product number
B2695
Product name
Bathophenanthroline (purified by sublimation)
Purity
>99.0%(HPLC)(T)
Packaging
1g
Price
$195
Updated
2024/03/01
TCI Chemical
Product number
D0905
Product name
Bathophenanthroline
Purity
>99.0%(T)
Packaging
1g
Price
$91
Updated
2024/03/01
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Bathophenanthroline Chemical Properties,Usage,Production

Classification

Hole-blocking layer (HBL) materials , Electron injection layer (EIL) materials, OLEDS, Organic photovoltaics, Perovskite solar cells.

Applications

BPhen is widely used as a hole-blocking or exciton-blocking layer due to its wide energy gap and high ionisation potential.
The phenanthroline unit is small, rigid, and planar, with extended π-electrons and short hopping lengths that facilitate electron mobility. The electron mobility of BPhen is about 5 × 10-4 cm2 V-1 s-1, which is about two orders of magnitude higher than that of Alq3.
When doped with lithium, BPhen:Li is an excellent electron-transport material, and is often used as an electron-injection layer to enable ohmic contact to any electrode -- without the need to consider the work function alignments.

Reactions

  1. Bidentate ligand and reagent for determination of iron.
  2. Ligand used in the copper-catalyzed protodecarboxylation of aromatic carboxylic acids. 

Description

BPhen is widely used as a hole-blocking or exciton-blocking layer due to its wide energy gap and high ionisation potential.

Chemical Properties

white to faintly yellow crystalline powder

Uses

Bathophenanthroline is widely used for determination of iron in serum and urine by colorimtetry. It acts as buffer layer to improve the efficiency of organic photovoltaic cells. It is very useful as a scavenger reagent, for the removal of traces of iron and copper from reagent solutions, which is used in the trace metal determination. Iron bathophenanthroline complex is involved as a redox mediating agent for imaging surface immobilized deoxyribonucleic acid (DNA) by using Scanning Electrochemical Microscopy (SECM).

Uses

Bathophenanthroline was used in an ultra-sensitive and selective nonextractive quenchofluorimetric method, in order to determine palladium (II) at μg/l Levels. It may also be used as the buffer layer to improve the performance of organic photovoltaic cells.

Definition

ChEBI: A member of the class of phenanthrolines that is 1,10-phenanthroline bearing two phenyl substituents at positions 4 and 7.

General Description

This product has been enhanced for catalysis.

Bathophenanthroline Preparation Products And Raw materials

Raw materials

Ethanol ARSENIC ACID,HEMIHYDRATE Stannous chloride 2-Nitroaniline Benzene Methanol Sodium hydroxide PETROLEUM ETHER 3-Chloropropiophenone Sulfuric acid

Preparation Products

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View Lastest Price from Bathophenanthroline manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
Bphen 1662-01-7
Price
US $0.00/g
Min. Order
1g
Purity
99.90%
Supply Ability
100KGS
Release date
2021-09-15
Shanghai UCHEM Inc.
Product
4,7-Diphenyl-1,10-phenanthroline 1662-01-7
Price
US $13.00-240.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2024-04-12
Hebei Xinsheng New Material Technology Co., LTD.
Product
Bathophenanthroline 1662-01-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
30000 Kg
Release date
2023-11-13

1662-01-7, BathophenanthrolineRelated Search:

1,5-Diphenylcarbazide 1,3-Diphenyl-2-thiourea 3,4'-DIAMINODIPHENYLMETHANE Diphenylmethane tert-Butylchlorodiphenylsilane 1,7-PHENANTHROLINE Biphenyl Chlorodiphenylphosphine Bathophenanthroline: (Use 1,10-o-Phenanthroline) Diphenylsilane Bathocuproine BATHOCUPROINEDISULFONIC ACID DISODIUM SALT BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE TRIS-(BATHOPHENANTHROLINE-DISULFONATE)-RUTHENIUM(II) NA-SOLUTION BATHOPHENANTHROLINE RUTHENIUM CHLORIDE,BATHOPHENANTHROLINE RUTHENIUM DICHLORIDE,TRIS-(BATHOPHENANTHROLINE) RUTHENIUM (II) CHLORIDE TRIS(4 7-DIPHENYL-1 10-PHENANTHROLINE)RU BUFFER SOLUTION TRIS(4 7-DIPHENYL-1 10-PHENANTHROLINE)

  • BATHOPHENANTHROLINE
  • TIMTEC-BB SBB008862
  • 4,7-Diphenyl-1,1-phenanthroline
  • 4,7-DIPHENYL-1,10-PHENANTHROLINE
  • 1,10-bathophenanthroline
  • bathophenanthrolin
  • 4,7-DIPHENYL-1,10-PHENANTHRO-
  • BATHOPHENANTHROLINE R. G.
  • BathophenanthrolineGr
  • Bathophenanthroline, 98+%
  • 1,4,7-Diphenyl-1,10-phenanthroline
  • 4,7-Diphenyl-[1,10] phenanthroline (Bathophenanthroline)
  • BATHOPHENANTHROLINE, REAG.
  • 4,7-Diphenyl-1,10-phanthroline
  • 4,7-Diphenyl-1,10-phenanthroline,min.97%(Bathophenanthroline)
  • 1,10-Phenanthroline, 4,7-diphenyl-
  • BATHOPHENANTHROLINE extrapure AR
  • 4,7-Diphenyl-1,10-phenanthroline, Indicator Grade
  • 4,7-Diphenyl-1,10-phenanthroline, BPhen
  • 1,8-Diphenyl-4,5-diazaphenanthrene
  • Bathophen
  • Bathophenantroline
  • 4,7-DIPHENYL-1,10-PHENANTHROLINE SUBLIMED HOLE BLOCKING MATERIAL
  • Bathophenanthroline (refined product of D0905)
  • BPHEN
  • 4,7-Diphenyl-1,10-phenanthroline,99%
  • 10-Phenanthroline,4,7-diphenyl-1
  • 4,7-Diphenyl-1,10-diazaphenanthrene
  • 4,7-Diphenyl-1,10-phenanthroli
  • 4,7-diphenyl-10-phenanthroline
  • Bathophenanthroline,4,7-Diphenyl-1,10-phenanthroline, BPhen
  • 4,7-Diphenyl-1,10-phenanthroline ,98.5%
  • Bathophenanthroline (purified by subliMation)
  • (purified by subliMation)
  • Bathophenanthroline&nbsp
  • 4,7-Diphenyl-1,10-phenanthroline, 99% 1GR
  • BATHOPHENANTHROLINE GR FOR ANALYSIS
  • 4,7-Diphenyl-1,10-phenanthroline, 99% (Bathophenanthroline)
  • 4,7-Diphenyl-o-phenanthroline
  • BathophenanthroL
  • BATHOPHENANTHROLINE, 99%BATHOPHENANTHROLINE, 99%BATHOPHENANTHROLINE, 99%BATHOPHENANTHROLINE, 99%
  • 4,7-diphenyl-1,10-phenanthroline4,7-
  • Bathophenanthroline &gt
  • 4,7-Diphenyl-1,10-phenanthroline, 98.5%, reagent grade
  • Bathophenanthroline (purified by sublimation)&gt
  • 4,7-Diphenyl-1,10-phenanthroline, purified by sublimation
  • 4,7-diphenyl-1,10-phenathroline
  • BPhen (Bathophenanthroline)
  • Bathophenanthroline, GR 99%+
  • CAS 1662-01-7 Bathophenanthroline
  • Bathophenthroline 99% AR
  • 1662-01-7
  • C24H16N2
  • C6H52C12H6N2
  • N-Containing
  • Others
  • IR/UV/ VIS
  • Spectroscopy Reagents